Demixing of polypropylene/polystyrene blends by near-critical selective solubilization
- Autores
- Martini, Raquel Evangelina; Barbosa, Silvia Elena; Brignole, Esteban Alberto
- Año de publicación
- 2006
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Blend phase characterization is a fundamental step in a polymer blend study. To analyze the blend composition and morphology, the separation of thermoplastic polymer blends into its components is the method used. This separation by traditional techniques, such as Soxhlet, is very difficult because of the high molecular weight molecules of the polymer blend components. The use of a high-temperature-high-pressure near-critical solvent is an interesting alternative that results in a complete and fast separation. In this work, a systematic study of the demixing of polypropylene (PP)/polystyrene (PS) blends is presented. First, the selectivity of n-alkanes was explored at high pressure and over a wide range of temperatures on pure polymers. From this study the processing window for blend separation was obtained. Second, the influence of the blend morphology and composition on the separation efficiency was analyzed. The method was applied to analyze and quantify the copolymer formed in a PP/PS in situ compatibilized blend. It is concluded that the method proppsed for blend separation is simple, fast, and accurate for the systems analyzed.
Fil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/37605
Ver los metadatos del registro completo
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Demixing of polypropylene/polystyrene blends by near-critical selective solubilizationMartini, Raquel EvangelinaBarbosa, Silvia ElenaBrignole, Esteban Albertohttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Blend phase characterization is a fundamental step in a polymer blend study. To analyze the blend composition and morphology, the separation of thermoplastic polymer blends into its components is the method used. This separation by traditional techniques, such as Soxhlet, is very difficult because of the high molecular weight molecules of the polymer blend components. The use of a high-temperature-high-pressure near-critical solvent is an interesting alternative that results in a complete and fast separation. In this work, a systematic study of the demixing of polypropylene (PP)/polystyrene (PS) blends is presented. First, the selectivity of n-alkanes was explored at high pressure and over a wide range of temperatures on pure polymers. From this study the processing window for blend separation was obtained. Second, the influence of the blend morphology and composition on the separation efficiency was analyzed. The method was applied to analyze and quantify the copolymer formed in a PP/PS in situ compatibilized blend. It is concluded that the method proppsed for blend separation is simple, fast, and accurate for the systems analyzed.Fil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaAmerican Chemical Society2006-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37605Martini, Raquel Evangelina; Barbosa, Silvia Elena; Brignole, Esteban Alberto; Demixing of polypropylene/polystyrene blends by near-critical selective solubilization; American Chemical Society; Industrial & Engineering Chemical Research; 45; 10; 5-2006; 3393-33990888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie050715ginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ie050715ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:08Zoai:ri.conicet.gov.ar:11336/37605instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:09.061CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Demixing of polypropylene/polystyrene blends by near-critical selective solubilization |
title |
Demixing of polypropylene/polystyrene blends by near-critical selective solubilization |
spellingShingle |
Demixing of polypropylene/polystyrene blends by near-critical selective solubilization Martini, Raquel Evangelina |
title_short |
Demixing of polypropylene/polystyrene blends by near-critical selective solubilization |
title_full |
Demixing of polypropylene/polystyrene blends by near-critical selective solubilization |
title_fullStr |
Demixing of polypropylene/polystyrene blends by near-critical selective solubilization |
title_full_unstemmed |
Demixing of polypropylene/polystyrene blends by near-critical selective solubilization |
title_sort |
Demixing of polypropylene/polystyrene blends by near-critical selective solubilization |
dc.creator.none.fl_str_mv |
Martini, Raquel Evangelina Barbosa, Silvia Elena Brignole, Esteban Alberto |
author |
Martini, Raquel Evangelina |
author_facet |
Martini, Raquel Evangelina Barbosa, Silvia Elena Brignole, Esteban Alberto |
author_role |
author |
author2 |
Barbosa, Silvia Elena Brignole, Esteban Alberto |
author2_role |
author author |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Blend phase characterization is a fundamental step in a polymer blend study. To analyze the blend composition and morphology, the separation of thermoplastic polymer blends into its components is the method used. This separation by traditional techniques, such as Soxhlet, is very difficult because of the high molecular weight molecules of the polymer blend components. The use of a high-temperature-high-pressure near-critical solvent is an interesting alternative that results in a complete and fast separation. In this work, a systematic study of the demixing of polypropylene (PP)/polystyrene (PS) blends is presented. First, the selectivity of n-alkanes was explored at high pressure and over a wide range of temperatures on pure polymers. From this study the processing window for blend separation was obtained. Second, the influence of the blend morphology and composition on the separation efficiency was analyzed. The method was applied to analyze and quantify the copolymer formed in a PP/PS in situ compatibilized blend. It is concluded that the method proppsed for blend separation is simple, fast, and accurate for the systems analyzed. Fil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Brignole, Esteban Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina |
description |
Blend phase characterization is a fundamental step in a polymer blend study. To analyze the blend composition and morphology, the separation of thermoplastic polymer blends into its components is the method used. This separation by traditional techniques, such as Soxhlet, is very difficult because of the high molecular weight molecules of the polymer blend components. The use of a high-temperature-high-pressure near-critical solvent is an interesting alternative that results in a complete and fast separation. In this work, a systematic study of the demixing of polypropylene (PP)/polystyrene (PS) blends is presented. First, the selectivity of n-alkanes was explored at high pressure and over a wide range of temperatures on pure polymers. From this study the processing window for blend separation was obtained. Second, the influence of the blend morphology and composition on the separation efficiency was analyzed. The method was applied to analyze and quantify the copolymer formed in a PP/PS in situ compatibilized blend. It is concluded that the method proppsed for blend separation is simple, fast, and accurate for the systems analyzed. |
publishDate |
2006 |
dc.date.none.fl_str_mv |
2006-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/37605 Martini, Raquel Evangelina; Barbosa, Silvia Elena; Brignole, Esteban Alberto; Demixing of polypropylene/polystyrene blends by near-critical selective solubilization; American Chemical Society; Industrial & Engineering Chemical Research; 45; 10; 5-2006; 3393-3399 0888-5885 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/37605 |
identifier_str_mv |
Martini, Raquel Evangelina; Barbosa, Silvia Elena; Brignole, Esteban Alberto; Demixing of polypropylene/polystyrene blends by near-critical selective solubilization; American Chemical Society; Industrial & Engineering Chemical Research; 45; 10; 5-2006; 3393-3399 0888-5885 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/ie050715g info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ie050715g |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613055786254336 |
score |
13.070432 |