Combined PFPD-FID assessment of sulfur in liquid fuels

Autores
del Rio Cuevas, José Daniel; Rey, Marilín; Sedran, Ulises Anselmo; de la Puente, Gabriela
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A pulsed flame photometric detector (PFPD) was calibrated using standard sulfur compounds present in gasoline and diesel fuels, in combination with a flame ionization detector (FID). Gasoline range standards were added to a hydrocarbon mixture simulating gasoline, with individual sulfur concentrations from 3 to 80 ppm. Diesel range standards were added to a low sulfur commercial diesel fuel, with sulfur concentrations from 10 to 100 ppm. In gasoline, both the chromatographic areas calculated with the linearized signal (data points elevated to a given power), and reported by the instrument were regressioned with the sulfur mass concentrations. In both cases the areas were normalized with the FID areas to reduce deviations. Results were better when using the linearized signal. Only the normalized areas calculated with the linearized signal can be used in the case of the diesel, due to significant peak coelution. Individual calibration coefficients were calculated for each standard, but overall coefficients can be used safely in each of the boiling ranges. The compliance of regulations about sulfur was verified in commercial fuels and the different sulfur compounds were inspected. The simultaneous combined FID-PFPD use allows adding the sulfur to the conventional
analysis of liquid fuels (e.g. composition, simulated distillation).
Fil: del Rio Cuevas, José Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rey, Marilín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: de la Puente, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Pfpd
Sulfur
Gasoline
Diesel
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/52870
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/52870
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Combined PFPD-FID assessment of sulfur in liquid fuelsdel Rio Cuevas, José DanielRey, MarilínSedran, Ulises Anselmode la Puente, GabrielaPfpdSulfurGasolineDieselhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A pulsed flame photometric detector (PFPD) was calibrated using standard sulfur compounds present in gasoline and diesel fuels, in combination with a flame ionization detector (FID). Gasoline range standards were added to a hydrocarbon mixture simulating gasoline, with individual sulfur concentrations from 3 to 80 ppm. Diesel range standards were added to a low sulfur commercial diesel fuel, with sulfur concentrations from 10 to 100 ppm. In gasoline, both the chromatographic areas calculated with the linearized signal (data points elevated to a given power), and reported by the instrument were regressioned with the sulfur mass concentrations. In both cases the areas were normalized with the FID areas to reduce deviations. Results were better when using the linearized signal. Only the normalized areas calculated with the linearized signal can be used in the case of the diesel, due to significant peak coelution. Individual calibration coefficients were calculated for each standard, but overall coefficients can be used safely in each of the boiling ranges. The compliance of regulations about sulfur was verified in commercial fuels and the different sulfur compounds were inspected. The simultaneous combined FID-PFPD use allows adding the sulfur to the conventional<br />analysis of liquid fuels (e.g. composition, simulated distillation).Fil: del Rio Cuevas, José Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Rey, Marilín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: de la Puente, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2011-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/52870del Rio Cuevas, José Daniel; Rey, Marilín; Sedran, Ulises Anselmo; de la Puente, Gabriela; Combined PFPD-FID assessment of sulfur in liquid fuels; Elsevier Science; Fuel Processing Technology; 92; 12; 12-2011; 2278-22840378-3820CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuproc.2011.07.017info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0378382011002773info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T10:46:21Zoai:ri.conicet.gov.ar:11336/52870instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 10:46:22.086CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Combined PFPD-FID assessment of sulfur in liquid fuels
title Combined PFPD-FID assessment of sulfur in liquid fuels
spellingShingle Combined PFPD-FID assessment of sulfur in liquid fuels
del Rio Cuevas, José Daniel
Pfpd
Sulfur
Gasoline
Diesel
title_short Combined PFPD-FID assessment of sulfur in liquid fuels
title_full Combined PFPD-FID assessment of sulfur in liquid fuels
title_fullStr Combined PFPD-FID assessment of sulfur in liquid fuels
title_full_unstemmed Combined PFPD-FID assessment of sulfur in liquid fuels
title_sort Combined PFPD-FID assessment of sulfur in liquid fuels
dc.creator.none.fl_str_mv del Rio Cuevas, José Daniel
Rey, Marilín
Sedran, Ulises Anselmo
de la Puente, Gabriela
author del Rio Cuevas, José Daniel
author_facet del Rio Cuevas, José Daniel
Rey, Marilín
Sedran, Ulises Anselmo
de la Puente, Gabriela
author_role author
author2 Rey, Marilín
Sedran, Ulises Anselmo
de la Puente, Gabriela
author2_role author
author
author
dc.subject.none.fl_str_mv Pfpd
Sulfur
Gasoline
Diesel
topic Pfpd
Sulfur
Gasoline
Diesel
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A pulsed flame photometric detector (PFPD) was calibrated using standard sulfur compounds present in gasoline and diesel fuels, in combination with a flame ionization detector (FID). Gasoline range standards were added to a hydrocarbon mixture simulating gasoline, with individual sulfur concentrations from 3 to 80 ppm. Diesel range standards were added to a low sulfur commercial diesel fuel, with sulfur concentrations from 10 to 100 ppm. In gasoline, both the chromatographic areas calculated with the linearized signal (data points elevated to a given power), and reported by the instrument were regressioned with the sulfur mass concentrations. In both cases the areas were normalized with the FID areas to reduce deviations. Results were better when using the linearized signal. Only the normalized areas calculated with the linearized signal can be used in the case of the diesel, due to significant peak coelution. Individual calibration coefficients were calculated for each standard, but overall coefficients can be used safely in each of the boiling ranges. The compliance of regulations about sulfur was verified in commercial fuels and the different sulfur compounds were inspected. The simultaneous combined FID-PFPD use allows adding the sulfur to the conventional<br />analysis of liquid fuels (e.g. composition, simulated distillation).
Fil: del Rio Cuevas, José Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rey, Marilín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: de la Puente, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description A pulsed flame photometric detector (PFPD) was calibrated using standard sulfur compounds present in gasoline and diesel fuels, in combination with a flame ionization detector (FID). Gasoline range standards were added to a hydrocarbon mixture simulating gasoline, with individual sulfur concentrations from 3 to 80 ppm. Diesel range standards were added to a low sulfur commercial diesel fuel, with sulfur concentrations from 10 to 100 ppm. In gasoline, both the chromatographic areas calculated with the linearized signal (data points elevated to a given power), and reported by the instrument were regressioned with the sulfur mass concentrations. In both cases the areas were normalized with the FID areas to reduce deviations. Results were better when using the linearized signal. Only the normalized areas calculated with the linearized signal can be used in the case of the diesel, due to significant peak coelution. Individual calibration coefficients were calculated for each standard, but overall coefficients can be used safely in each of the boiling ranges. The compliance of regulations about sulfur was verified in commercial fuels and the different sulfur compounds were inspected. The simultaneous combined FID-PFPD use allows adding the sulfur to the conventional<br />analysis of liquid fuels (e.g. composition, simulated distillation).
publishDate 2011
dc.date.none.fl_str_mv 2011-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/52870
del Rio Cuevas, José Daniel; Rey, Marilín; Sedran, Ulises Anselmo; de la Puente, Gabriela; Combined PFPD-FID assessment of sulfur in liquid fuels; Elsevier Science; Fuel Processing Technology; 92; 12; 12-2011; 2278-2284
0378-3820
CONICET Digital
CONICET
url http://hdl.handle.net/11336/52870
identifier_str_mv del Rio Cuevas, José Daniel; Rey, Marilín; Sedran, Ulises Anselmo; de la Puente, Gabriela; Combined PFPD-FID assessment of sulfur in liquid fuels; Elsevier Science; Fuel Processing Technology; 92; 12; 12-2011; 2278-2284
0378-3820
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuproc.2011.07.017
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0378382011002773
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1847978171997093888
score 13.082534

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