Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method

Autores
Tulli, Fiorella Giovanna; Morales, Jesús Marcelo Nicolás; Salas, Esteban Eduardo; Moran Vieyra, Faustino Eduardo; Borsarelli, Claudio Darío
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A set of opaque films were prepared with Degussa P25® or Hombikat UV100® TiO2 powders by the doctor blade method on glass slides with different compositions of polyethylene glycol of 20 kDa (PEG20), and they were characterized by spectroscopy, microscopy and photochemical kinetics measurements. After annealing treatment at 450 °C, about 5–7% C atom was incorporated into the films, as a consequence of the degradation of the organic complexing agents, inducing a small reduction of the energy band gap of TiO2 (i.e. 3.02 ≤ Eg (eV) ≤ 3.08). All films were about 15 ± 2 μm thick but their micro-morphological characteristics depended on the content of PEG20, showing different patterns of cracks and aggregates that produce intense light scattering and retransmission phenomena with the result of a three-dimensional excitation of the TiO2 particles in the thick film. Back-face excitation with UVA light (365 ± 42 nm) of the opaque films in contact with an aqueous solution produced both surface-bound and free hydroxyl radicals (HO•), as detected using a coumarin solution as a radical dosimeter. The photogeneration efficiency of HO• decreased with the surface roughness of the films, which varied between 135 and 439 nm depending on the film's composition.
Fil: Tulli, Fiorella Giovanna. Universidad Nacional de Santiago del Estero; Argentina. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina
Fil: Morales, Jesús Marcelo Nicolás. Universidad Nacional de Santiago del Estero; Argentina. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina
Fil: Salas, Esteban Eduardo. Universidad Nacional de Santiago del Estero; Argentina. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina
Fil: Moran Vieyra, Faustino Eduardo. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina. Universidad Nacional de Santiago del Estero. Facultad de Agronomía y Agroindustrias; Argentina
Fil: Borsarelli, Claudio Darío. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina. Universidad Nacional de Santiago del Estero. Facultad de Agronomía y Agroindustrias; Argentina
Materia
TITANIUM DIOXIDE FILMS
DOCTOR BLADE METHOD
PHOTOCATALYSIS
SURFACE MORPHOLOGY
PHOTOCATALYTIC QUANTUM EFFICENCY
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/148298
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/148298
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade MethodTulli, Fiorella GiovannaMorales, Jesús Marcelo NicolásSalas, Esteban EduardoMoran Vieyra, Faustino EduardoBorsarelli, Claudio DaríoTITANIUM DIOXIDE FILMSDOCTOR BLADE METHODPHOTOCATALYSISSURFACE MORPHOLOGYPHOTOCATALYTIC QUANTUM EFFICENCYhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A set of opaque films were prepared with Degussa P25® or Hombikat UV100® TiO2 powders by the doctor blade method on glass slides with different compositions of polyethylene glycol of 20 kDa (PEG20), and they were characterized by spectroscopy, microscopy and photochemical kinetics measurements. After annealing treatment at 450 °C, about 5–7% C atom was incorporated into the films, as a consequence of the degradation of the organic complexing agents, inducing a small reduction of the energy band gap of TiO2 (i.e. 3.02 ≤ Eg (eV) ≤ 3.08). All films were about 15 ± 2 μm thick but their micro-morphological characteristics depended on the content of PEG20, showing different patterns of cracks and aggregates that produce intense light scattering and retransmission phenomena with the result of a three-dimensional excitation of the TiO2 particles in the thick film. Back-face excitation with UVA light (365 ± 42 nm) of the opaque films in contact with an aqueous solution produced both surface-bound and free hydroxyl radicals (HO•), as detected using a coumarin solution as a radical dosimeter. The photogeneration efficiency of HO• decreased with the surface roughness of the films, which varied between 135 and 439 nm depending on the film's composition.Fil: Tulli, Fiorella Giovanna. Universidad Nacional de Santiago del Estero; Argentina. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; ArgentinaFil: Morales, Jesús Marcelo Nicolás. Universidad Nacional de Santiago del Estero; Argentina. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; ArgentinaFil: Salas, Esteban Eduardo. Universidad Nacional de Santiago del Estero; Argentina. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; ArgentinaFil: Moran Vieyra, Faustino Eduardo. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina. Universidad Nacional de Santiago del Estero. Facultad de Agronomía y Agroindustrias; ArgentinaFil: Borsarelli, Claudio Darío. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina. Universidad Nacional de Santiago del Estero. Facultad de Agronomía y Agroindustrias; ArgentinaWiley Blackwell Publishing, Inc2021-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/148298Tulli, Fiorella Giovanna; Morales, Jesús Marcelo Nicolás; Salas, Esteban Eduardo; Moran Vieyra, Faustino Eduardo; Borsarelli, Claudio Darío; Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method; Wiley Blackwell Publishing, Inc; Photochemistry and Photobiology; 97; 1; 1-2021; 22-310031-8655CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1111/php.13320info:eu-repo/semantics/altIdentifier/doi/10.1111/php.13320info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:59:01Zoai:ri.conicet.gov.ar:11336/148298instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:59:01.605CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method
title Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method
spellingShingle Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method
Tulli, Fiorella Giovanna
TITANIUM DIOXIDE FILMS
DOCTOR BLADE METHOD
PHOTOCATALYSIS
SURFACE MORPHOLOGY
PHOTOCATALYTIC QUANTUM EFFICENCY
title_short Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method
title_full Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method
title_fullStr Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method
title_full_unstemmed Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method
title_sort Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method
dc.creator.none.fl_str_mv Tulli, Fiorella Giovanna
Morales, Jesús Marcelo Nicolás
Salas, Esteban Eduardo
Moran Vieyra, Faustino Eduardo
Borsarelli, Claudio Darío
author Tulli, Fiorella Giovanna
author_facet Tulli, Fiorella Giovanna
Morales, Jesús Marcelo Nicolás
Salas, Esteban Eduardo
Moran Vieyra, Faustino Eduardo
Borsarelli, Claudio Darío
author_role author
author2 Morales, Jesús Marcelo Nicolás
Salas, Esteban Eduardo
Moran Vieyra, Faustino Eduardo
Borsarelli, Claudio Darío
author2_role author
author
author
author
dc.subject.none.fl_str_mv TITANIUM DIOXIDE FILMS
DOCTOR BLADE METHOD
PHOTOCATALYSIS
SURFACE MORPHOLOGY
PHOTOCATALYTIC QUANTUM EFFICENCY
topic TITANIUM DIOXIDE FILMS
DOCTOR BLADE METHOD
PHOTOCATALYSIS
SURFACE MORPHOLOGY
PHOTOCATALYTIC QUANTUM EFFICENCY
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A set of opaque films were prepared with Degussa P25® or Hombikat UV100® TiO2 powders by the doctor blade method on glass slides with different compositions of polyethylene glycol of 20 kDa (PEG20), and they were characterized by spectroscopy, microscopy and photochemical kinetics measurements. After annealing treatment at 450 °C, about 5–7% C atom was incorporated into the films, as a consequence of the degradation of the organic complexing agents, inducing a small reduction of the energy band gap of TiO2 (i.e. 3.02 ≤ Eg (eV) ≤ 3.08). All films were about 15 ± 2 μm thick but their micro-morphological characteristics depended on the content of PEG20, showing different patterns of cracks and aggregates that produce intense light scattering and retransmission phenomena with the result of a three-dimensional excitation of the TiO2 particles in the thick film. Back-face excitation with UVA light (365 ± 42 nm) of the opaque films in contact with an aqueous solution produced both surface-bound and free hydroxyl radicals (HO•), as detected using a coumarin solution as a radical dosimeter. The photogeneration efficiency of HO• decreased with the surface roughness of the films, which varied between 135 and 439 nm depending on the film's composition.
Fil: Tulli, Fiorella Giovanna. Universidad Nacional de Santiago del Estero; Argentina. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina
Fil: Morales, Jesús Marcelo Nicolás. Universidad Nacional de Santiago del Estero; Argentina. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina
Fil: Salas, Esteban Eduardo. Universidad Nacional de Santiago del Estero; Argentina. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina
Fil: Moran Vieyra, Faustino Eduardo. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina. Universidad Nacional de Santiago del Estero. Facultad de Agronomía y Agroindustrias; Argentina
Fil: Borsarelli, Claudio Darío. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina. Universidad Nacional de Santiago del Estero. Facultad de Agronomía y Agroindustrias; Argentina
description A set of opaque films were prepared with Degussa P25® or Hombikat UV100® TiO2 powders by the doctor blade method on glass slides with different compositions of polyethylene glycol of 20 kDa (PEG20), and they were characterized by spectroscopy, microscopy and photochemical kinetics measurements. After annealing treatment at 450 °C, about 5–7% C atom was incorporated into the films, as a consequence of the degradation of the organic complexing agents, inducing a small reduction of the energy band gap of TiO2 (i.e. 3.02 ≤ Eg (eV) ≤ 3.08). All films were about 15 ± 2 μm thick but their micro-morphological characteristics depended on the content of PEG20, showing different patterns of cracks and aggregates that produce intense light scattering and retransmission phenomena with the result of a three-dimensional excitation of the TiO2 particles in the thick film. Back-face excitation with UVA light (365 ± 42 nm) of the opaque films in contact with an aqueous solution produced both surface-bound and free hydroxyl radicals (HO•), as detected using a coumarin solution as a radical dosimeter. The photogeneration efficiency of HO• decreased with the surface roughness of the films, which varied between 135 and 439 nm depending on the film's composition.
publishDate 2021
dc.date.none.fl_str_mv 2021-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/148298
Tulli, Fiorella Giovanna; Morales, Jesús Marcelo Nicolás; Salas, Esteban Eduardo; Moran Vieyra, Faustino Eduardo; Borsarelli, Claudio Darío; Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method; Wiley Blackwell Publishing, Inc; Photochemistry and Photobiology; 97; 1; 1-2021; 22-31
0031-8655
CONICET Digital
CONICET
url http://hdl.handle.net/11336/148298
identifier_str_mv Tulli, Fiorella Giovanna; Morales, Jesús Marcelo Nicolás; Salas, Esteban Eduardo; Moran Vieyra, Faustino Eduardo; Borsarelli, Claudio Darío; Photocatalytic Efficiency Tuning by the Surface Roughness of TiO2 Coatings on Glass Prepared by the Doctor Blade Method; Wiley Blackwell Publishing, Inc; Photochemistry and Photobiology; 97; 1; 1-2021; 22-31
0031-8655
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1111/php.13320
info:eu-repo/semantics/altIdentifier/doi/10.1111/php.13320
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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