Starch/polyvinyl alcohol blends containing polyurethane as plasticizer

Autores
González Forte, Lucía del Sol; Pardini, Oscar Ricardo; Amalvy, Javier I.
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Starch-based films containing 70wt% of starch and a combination of poly(vinyl alcohol) and a low glass transition temperature polyurethane as plasticizer were prepared. The effect of PVA/PU ratio content on the morphology and physical properties was investigated by infrared spectroscopy (FTIR), X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy and measurements of mechanical properties and water vapor permeability. A relative small amount of PU (less than 15 wt%), significantly changes the properties of the blend due to intermolecular hydrogen bonding interactions between the three components. FTIR and XRD results indicate that blends containing PU are more amorphous than the pure starch/PVA blend and SEM images show a homogeneous matrix due to the good compatibility between starch and PU. Incorporation of PU to the starch/PVA blend shifts the glass transition temperature to lower values and reduce the elastic modulus, indicating a successful plasticization effect. The resulting blends produce films with improved physical properties.
Fil: González Forte, Lucía del Sol. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Pardini, Oscar Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Amalvy, Javier I.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Materia
COATING
HYDROGEN BONDING
BARRIER PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/62571
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Starch/polyvinyl alcohol blends containing polyurethane as plasticizerGonzález Forte, Lucía del SolPardini, Oscar RicardoAmalvy, Javier I.COATINGHYDROGEN BONDINGBARRIER PROPERTIEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Starch-based films containing 70wt% of starch and a combination of poly(vinyl alcohol) and a low glass transition temperature polyurethane as plasticizer were prepared. The effect of PVA/PU ratio content on the morphology and physical properties was investigated by infrared spectroscopy (FTIR), X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy and measurements of mechanical properties and water vapor permeability. A relative small amount of PU (less than 15 wt%), significantly changes the properties of the blend due to intermolecular hydrogen bonding interactions between the three components. FTIR and XRD results indicate that blends containing PU are more amorphous than the pure starch/PVA blend and SEM images show a homogeneous matrix due to the good compatibility between starch and PU. Incorporation of PU to the starch/PVA blend shifts the glass transition temperature to lower values and reduce the elastic modulus, indicating a successful plasticization effect. The resulting blends produce films with improved physical properties.Fil: González Forte, Lucía del Sol. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Pardini, Oscar Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Amalvy, Javier I.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaSavvy2016-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/62571González Forte, Lucía del Sol; Pardini, Oscar Ricardo; Amalvy, Javier I.; Starch/polyvinyl alcohol blends containing polyurethane as plasticizer; Savvy; Journal of Composites and Biodegradable Polymers; 4; 6-2016; 2-102311-8717CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.12974/2311-8717.2016.04.01.1info:eu-repo/semantics/altIdentifier/url/http://savvysciencepublisher.com/downloads/jcbpv4n1a1/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:15:03Zoai:ri.conicet.gov.ar:11336/62571instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:15:03.946CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Starch/polyvinyl alcohol blends containing polyurethane as plasticizer
title Starch/polyvinyl alcohol blends containing polyurethane as plasticizer
spellingShingle Starch/polyvinyl alcohol blends containing polyurethane as plasticizer
González Forte, Lucía del Sol
COATING
HYDROGEN BONDING
BARRIER PROPERTIES
title_short Starch/polyvinyl alcohol blends containing polyurethane as plasticizer
title_full Starch/polyvinyl alcohol blends containing polyurethane as plasticizer
title_fullStr Starch/polyvinyl alcohol blends containing polyurethane as plasticizer
title_full_unstemmed Starch/polyvinyl alcohol blends containing polyurethane as plasticizer
title_sort Starch/polyvinyl alcohol blends containing polyurethane as plasticizer
dc.creator.none.fl_str_mv González Forte, Lucía del Sol
Pardini, Oscar Ricardo
Amalvy, Javier I.
author González Forte, Lucía del Sol
author_facet González Forte, Lucía del Sol
Pardini, Oscar Ricardo
Amalvy, Javier I.
author_role author
author2 Pardini, Oscar Ricardo
Amalvy, Javier I.
author2_role author
author
dc.subject.none.fl_str_mv COATING
HYDROGEN BONDING
BARRIER PROPERTIES
topic COATING
HYDROGEN BONDING
BARRIER PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Starch-based films containing 70wt% of starch and a combination of poly(vinyl alcohol) and a low glass transition temperature polyurethane as plasticizer were prepared. The effect of PVA/PU ratio content on the morphology and physical properties was investigated by infrared spectroscopy (FTIR), X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy and measurements of mechanical properties and water vapor permeability. A relative small amount of PU (less than 15 wt%), significantly changes the properties of the blend due to intermolecular hydrogen bonding interactions between the three components. FTIR and XRD results indicate that blends containing PU are more amorphous than the pure starch/PVA blend and SEM images show a homogeneous matrix due to the good compatibility between starch and PU. Incorporation of PU to the starch/PVA blend shifts the glass transition temperature to lower values and reduce the elastic modulus, indicating a successful plasticization effect. The resulting blends produce films with improved physical properties.
Fil: González Forte, Lucía del Sol. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Pardini, Oscar Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Amalvy, Javier I.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
description Starch-based films containing 70wt% of starch and a combination of poly(vinyl alcohol) and a low glass transition temperature polyurethane as plasticizer were prepared. The effect of PVA/PU ratio content on the morphology and physical properties was investigated by infrared spectroscopy (FTIR), X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy and measurements of mechanical properties and water vapor permeability. A relative small amount of PU (less than 15 wt%), significantly changes the properties of the blend due to intermolecular hydrogen bonding interactions between the three components. FTIR and XRD results indicate that blends containing PU are more amorphous than the pure starch/PVA blend and SEM images show a homogeneous matrix due to the good compatibility between starch and PU. Incorporation of PU to the starch/PVA blend shifts the glass transition temperature to lower values and reduce the elastic modulus, indicating a successful plasticization effect. The resulting blends produce films with improved physical properties.
publishDate 2016
dc.date.none.fl_str_mv 2016-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/62571
González Forte, Lucía del Sol; Pardini, Oscar Ricardo; Amalvy, Javier I.; Starch/polyvinyl alcohol blends containing polyurethane as plasticizer; Savvy; Journal of Composites and Biodegradable Polymers; 4; 6-2016; 2-10
2311-8717
CONICET Digital
CONICET
url http://hdl.handle.net/11336/62571
identifier_str_mv González Forte, Lucía del Sol; Pardini, Oscar Ricardo; Amalvy, Javier I.; Starch/polyvinyl alcohol blends containing polyurethane as plasticizer; Savvy; Journal of Composites and Biodegradable Polymers; 4; 6-2016; 2-10
2311-8717
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.12974/2311-8717.2016.04.01.1
info:eu-repo/semantics/altIdentifier/url/http://savvysciencepublisher.com/downloads/jcbpv4n1a1/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Savvy
publisher.none.fl_str_mv Savvy
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.221938

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