Investigation of the stability of Novozym® 435 in the production of biodiesel

Autores
José, Carla; Austic, Gregory B.; Bonetto, Rita Dominga; Burton, Rachel M.; Briand, Laura Estefania
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of the composition of the feedstock (free fatty acids and methanol), the presence or absence of moisture and the contact with biodiesel on the catalytic, enzymatic and physical stability of Novozym® 435 during enzymatic biodiesel production was studied. The continuous removal of moisture leads to the deactivation of the biocatalyst and favours the degradation of the polymethylmethacrylate (PMMA) that constitutes the support of the Candida antarctica B lipase (CALB). Nevertheless, the presence of PMMA along with the active protein was detected in the reaction media regardless of the operating conditions. Surprisingly, biodiesel (without the presence of methanol) is able to diffuse inside the biocatalyst beads producing its swelling, modifying the internal texture and also dissolving the polymeric matrix.
Fil: José, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Austic, Gregory B.. Piedmont Biofuels; Estados Unidos
Fil: Bonetto, Rita Dominga. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Burton, Rachel M.. Piedmont Biofuels; Estados Unidos
Fil: Briand, Laura Estefania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
NOVOZYM® 435
BIODIESEL
FAeSTER
Enzymatic esterification
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2395
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/2395
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Investigation of the stability of Novozym® 435 in the production of biodieselJosé, CarlaAustic, Gregory B.Bonetto, Rita DomingaBurton, Rachel M.Briand, Laura EstefaniaNOVOZYM® 435BIODIESELFAeSTEREnzymatic esterificationhttps://purl.org/becyt/ford/2.9https://purl.org/becyt/ford/2The effect of the composition of the feedstock (free fatty acids and methanol), the presence or absence of moisture and the contact with biodiesel on the catalytic, enzymatic and physical stability of Novozym® 435 during enzymatic biodiesel production was studied. The continuous removal of moisture leads to the deactivation of the biocatalyst and favours the degradation of the polymethylmethacrylate (PMMA) that constitutes the support of the Candida antarctica B lipase (CALB). Nevertheless, the presence of PMMA along with the active protein was detected in the reaction media regardless of the operating conditions. Surprisingly, biodiesel (without the presence of methanol) is able to diffuse inside the biocatalyst beads producing its swelling, modifying the internal texture and also dissolving the polymeric matrix.Fil: José, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Austic, Gregory B.. Piedmont Biofuels; Estados UnidosFil: Bonetto, Rita Dominga. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Burton, Rachel M.. Piedmont Biofuels; Estados UnidosFil: Briand, Laura Estefania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaElsevier Science2013-03-30info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2395José, Carla; Austic, Gregory B.; Bonetto, Rita Dominga; Burton, Rachel M.; Briand, Laura Estefania; Investigation of the stability of Novozym® 435 in the production of biodiesel; Elsevier Science; Catalysis Today; 213; 30-3-2013; 73-800920-5861engSelected contributions of the XXIII Iberoamerican Congress on Catalysisinfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586113000746info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2013.02.013info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:11:21Zoai:ri.conicet.gov.ar:11336/2395instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:11:22.181CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Investigation of the stability of Novozym® 435 in the production of biodiesel
title Investigation of the stability of Novozym® 435 in the production of biodiesel
spellingShingle Investigation of the stability of Novozym® 435 in the production of biodiesel
José, Carla
NOVOZYM® 435
BIODIESEL
FAeSTER
Enzymatic esterification
title_short Investigation of the stability of Novozym® 435 in the production of biodiesel
title_full Investigation of the stability of Novozym® 435 in the production of biodiesel
title_fullStr Investigation of the stability of Novozym® 435 in the production of biodiesel
title_full_unstemmed Investigation of the stability of Novozym® 435 in the production of biodiesel
title_sort Investigation of the stability of Novozym® 435 in the production of biodiesel
dc.creator.none.fl_str_mv José, Carla
Austic, Gregory B.
Bonetto, Rita Dominga
Burton, Rachel M.
Briand, Laura Estefania
author José, Carla
author_facet José, Carla
Austic, Gregory B.
Bonetto, Rita Dominga
Burton, Rachel M.
Briand, Laura Estefania
author_role author
author2 Austic, Gregory B.
Bonetto, Rita Dominga
Burton, Rachel M.
Briand, Laura Estefania
author2_role author
author
author
author
dc.subject.none.fl_str_mv NOVOZYM® 435
BIODIESEL
FAeSTER
Enzymatic esterification
topic NOVOZYM® 435
BIODIESEL
FAeSTER
Enzymatic esterification
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.9
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The effect of the composition of the feedstock (free fatty acids and methanol), the presence or absence of moisture and the contact with biodiesel on the catalytic, enzymatic and physical stability of Novozym® 435 during enzymatic biodiesel production was studied. The continuous removal of moisture leads to the deactivation of the biocatalyst and favours the degradation of the polymethylmethacrylate (PMMA) that constitutes the support of the Candida antarctica B lipase (CALB). Nevertheless, the presence of PMMA along with the active protein was detected in the reaction media regardless of the operating conditions. Surprisingly, biodiesel (without the presence of methanol) is able to diffuse inside the biocatalyst beads producing its swelling, modifying the internal texture and also dissolving the polymeric matrix.
Fil: José, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Austic, Gregory B.. Piedmont Biofuels; Estados Unidos
Fil: Bonetto, Rita Dominga. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Burton, Rachel M.. Piedmont Biofuels; Estados Unidos
Fil: Briand, Laura Estefania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description The effect of the composition of the feedstock (free fatty acids and methanol), the presence or absence of moisture and the contact with biodiesel on the catalytic, enzymatic and physical stability of Novozym® 435 during enzymatic biodiesel production was studied. The continuous removal of moisture leads to the deactivation of the biocatalyst and favours the degradation of the polymethylmethacrylate (PMMA) that constitutes the support of the Candida antarctica B lipase (CALB). Nevertheless, the presence of PMMA along with the active protein was detected in the reaction media regardless of the operating conditions. Surprisingly, biodiesel (without the presence of methanol) is able to diffuse inside the biocatalyst beads producing its swelling, modifying the internal texture and also dissolving the polymeric matrix.
publishDate 2013
dc.date.none.fl_str_mv 2013-03-30
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2395
José, Carla; Austic, Gregory B.; Bonetto, Rita Dominga; Burton, Rachel M.; Briand, Laura Estefania; Investigation of the stability of Novozym® 435 in the production of biodiesel; Elsevier Science; Catalysis Today; 213; 30-3-2013; 73-80
0920-5861
url http://hdl.handle.net/11336/2395
identifier_str_mv José, Carla; Austic, Gregory B.; Bonetto, Rita Dominga; Burton, Rachel M.; Briand, Laura Estefania; Investigation of the stability of Novozym® 435 in the production of biodiesel; Elsevier Science; Catalysis Today; 213; 30-3-2013; 73-80
0920-5861
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Selected contributions of the XXIII Iberoamerican Congress on Catalysis
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586113000746
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2013.02.013
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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