Human exposure and mass balance distribution during procymidone application in horticultural greenhouses

Autores
Fitó Friedrichs, Gretel Alejandra; Berenstein, Giselle Anahí; Nasello, María Soledad; Dutra Alcoba, Yohana Yisel; Hughes, Enrique Alejandro; Basack, Silvana Beatriz; Montserrat, Javier Marcelo
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The purpose of this study was to analyze the impact of procymidone application in periurban horticultural greenhouses, especially on workers (applicators and assistants) and soil and plastic mulching, when mechanically pressurized application systems were employed. The mean Potential Dermal Exposure (PDE) was measured using the Whole Body Dosimetry technique. The PDE for the applicators was 188 mL h−1 ± 103 mL h−1, and 14.7 mL h−1 ± 6.3 mL h−1 for the assistants. In the first case, the most exposed body sections were the upper right and left (46.8 mL h−1 ± 23.4 mL h−1; 47.0 mL h−1 ± 23.5 mL h−1) and lower (20.8 mL h−1 ± 10.4 mL h−1; 17.3 mL h−1 ± 8.7 mL h−1) legs, while in the case of assistants, hands and legs were the most impacted limbs. Regarding the Margin of Safety (MOS) during the mix and load stage, two of three pesticide preparations resulted unsafe, while for the applicators, six of six spraying operations were unsafe. For the assistants, five of five operations were safe, but three of them were close to the safety limit. Procymidone distribution between drift (0.03% ± 0.07 %), applicator (0.20% ± 0.15 %), polyethylene mulching (8.5% ± 4.5 %) and soil (3.0% ± 1.1 %) was determined with respect to the total pesticide applied. Procymidone soil impact was also evaluated using Eisenia andrei behavioral tests, finding positive correlations between procymidone application and avoidance and reproduction tests.
Fil: Fitó Friedrichs, Gretel Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Berenstein, Giselle Anahí. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Nasello, María Soledad. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Dutra Alcoba, Yohana Yisel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Hughes, Enrique Alejandro. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Basack, Silvana Beatriz. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Materia
EISENIA ANDREI
ENVIRONMENTAL CHEMISTRY
ENVIRONMENTAL POLLUTION
ENVIRONMENTAL RISK ASSESSMENT
EXPOSURE
HORTICULTURE
MOS
PDE
PESTICIDE
PROCYMIDONE
SOIL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/172260

id CONICETDig_27c2a5dcab43aa2797f1d4dec3eafc7d
oai_identifier_str oai:ri.conicet.gov.ar:11336/172260
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Human exposure and mass balance distribution during procymidone application in horticultural greenhousesFitó Friedrichs, Gretel AlejandraBerenstein, Giselle AnahíNasello, María SoledadDutra Alcoba, Yohana YiselHughes, Enrique AlejandroBasack, Silvana BeatrizMontserrat, Javier MarceloEISENIA ANDREIENVIRONMENTAL CHEMISTRYENVIRONMENTAL POLLUTIONENVIRONMENTAL RISK ASSESSMENTEXPOSUREHORTICULTUREMOSPDEPESTICIDEPROCYMIDONESOILhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The purpose of this study was to analyze the impact of procymidone application in periurban horticultural greenhouses, especially on workers (applicators and assistants) and soil and plastic mulching, when mechanically pressurized application systems were employed. The mean Potential Dermal Exposure (PDE) was measured using the Whole Body Dosimetry technique. The PDE for the applicators was 188 mL h−1 ± 103 mL h−1, and 14.7 mL h−1 ± 6.3 mL h−1 for the assistants. In the first case, the most exposed body sections were the upper right and left (46.8 mL h−1 ± 23.4 mL h−1; 47.0 mL h−1 ± 23.5 mL h−1) and lower (20.8 mL h−1 ± 10.4 mL h−1; 17.3 mL h−1 ± 8.7 mL h−1) legs, while in the case of assistants, hands and legs were the most impacted limbs. Regarding the Margin of Safety (MOS) during the mix and load stage, two of three pesticide preparations resulted unsafe, while for the applicators, six of six spraying operations were unsafe. For the assistants, five of five operations were safe, but three of them were close to the safety limit. Procymidone distribution between drift (0.03% ± 0.07 %), applicator (0.20% ± 0.15 %), polyethylene mulching (8.5% ± 4.5 %) and soil (3.0% ± 1.1 %) was determined with respect to the total pesticide applied. Procymidone soil impact was also evaluated using Eisenia andrei behavioral tests, finding positive correlations between procymidone application and avoidance and reproduction tests.Fil: Fitó Friedrichs, Gretel Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Berenstein, Giselle Anahí. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Nasello, María Soledad. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Dutra Alcoba, Yohana Yisel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Hughes, Enrique Alejandro. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Basack, Silvana Beatriz. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaElsevier2020-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/172260Fitó Friedrichs, Gretel Alejandra; Berenstein, Giselle Anahí; Nasello, María Soledad; Dutra Alcoba, Yohana Yisel; Hughes, Enrique Alejandro; et al.; Human exposure and mass balance distribution during procymidone application in horticultural greenhouses; Elsevier; Heliyon; 6; 1; 1-2020; 1-102405-8440CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2405844019367520info:eu-repo/semantics/altIdentifier/doi/10.1016/j.heliyon.2019.e03093info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:10:42Zoai:ri.conicet.gov.ar:11336/172260instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:10:43.179CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Human exposure and mass balance distribution during procymidone application in horticultural greenhouses
title Human exposure and mass balance distribution during procymidone application in horticultural greenhouses
spellingShingle Human exposure and mass balance distribution during procymidone application in horticultural greenhouses
Fitó Friedrichs, Gretel Alejandra
EISENIA ANDREI
ENVIRONMENTAL CHEMISTRY
ENVIRONMENTAL POLLUTION
ENVIRONMENTAL RISK ASSESSMENT
EXPOSURE
HORTICULTURE
MOS
PDE
PESTICIDE
PROCYMIDONE
SOIL
title_short Human exposure and mass balance distribution during procymidone application in horticultural greenhouses
title_full Human exposure and mass balance distribution during procymidone application in horticultural greenhouses
title_fullStr Human exposure and mass balance distribution during procymidone application in horticultural greenhouses
title_full_unstemmed Human exposure and mass balance distribution during procymidone application in horticultural greenhouses
title_sort Human exposure and mass balance distribution during procymidone application in horticultural greenhouses
dc.creator.none.fl_str_mv Fitó Friedrichs, Gretel Alejandra
Berenstein, Giselle Anahí
Nasello, María Soledad
Dutra Alcoba, Yohana Yisel
Hughes, Enrique Alejandro
Basack, Silvana Beatriz
Montserrat, Javier Marcelo
author Fitó Friedrichs, Gretel Alejandra
author_facet Fitó Friedrichs, Gretel Alejandra
Berenstein, Giselle Anahí
Nasello, María Soledad
Dutra Alcoba, Yohana Yisel
Hughes, Enrique Alejandro
Basack, Silvana Beatriz
Montserrat, Javier Marcelo
author_role author
author2 Berenstein, Giselle Anahí
Nasello, María Soledad
Dutra Alcoba, Yohana Yisel
Hughes, Enrique Alejandro
Basack, Silvana Beatriz
Montserrat, Javier Marcelo
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv EISENIA ANDREI
ENVIRONMENTAL CHEMISTRY
ENVIRONMENTAL POLLUTION
ENVIRONMENTAL RISK ASSESSMENT
EXPOSURE
HORTICULTURE
MOS
PDE
PESTICIDE
PROCYMIDONE
SOIL
topic EISENIA ANDREI
ENVIRONMENTAL CHEMISTRY
ENVIRONMENTAL POLLUTION
ENVIRONMENTAL RISK ASSESSMENT
EXPOSURE
HORTICULTURE
MOS
PDE
PESTICIDE
PROCYMIDONE
SOIL
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The purpose of this study was to analyze the impact of procymidone application in periurban horticultural greenhouses, especially on workers (applicators and assistants) and soil and plastic mulching, when mechanically pressurized application systems were employed. The mean Potential Dermal Exposure (PDE) was measured using the Whole Body Dosimetry technique. The PDE for the applicators was 188 mL h−1 ± 103 mL h−1, and 14.7 mL h−1 ± 6.3 mL h−1 for the assistants. In the first case, the most exposed body sections were the upper right and left (46.8 mL h−1 ± 23.4 mL h−1; 47.0 mL h−1 ± 23.5 mL h−1) and lower (20.8 mL h−1 ± 10.4 mL h−1; 17.3 mL h−1 ± 8.7 mL h−1) legs, while in the case of assistants, hands and legs were the most impacted limbs. Regarding the Margin of Safety (MOS) during the mix and load stage, two of three pesticide preparations resulted unsafe, while for the applicators, six of six spraying operations were unsafe. For the assistants, five of five operations were safe, but three of them were close to the safety limit. Procymidone distribution between drift (0.03% ± 0.07 %), applicator (0.20% ± 0.15 %), polyethylene mulching (8.5% ± 4.5 %) and soil (3.0% ± 1.1 %) was determined with respect to the total pesticide applied. Procymidone soil impact was also evaluated using Eisenia andrei behavioral tests, finding positive correlations between procymidone application and avoidance and reproduction tests.
Fil: Fitó Friedrichs, Gretel Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Berenstein, Giselle Anahí. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Nasello, María Soledad. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Dutra Alcoba, Yohana Yisel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Hughes, Enrique Alejandro. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Basack, Silvana Beatriz. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
description The purpose of this study was to analyze the impact of procymidone application in periurban horticultural greenhouses, especially on workers (applicators and assistants) and soil and plastic mulching, when mechanically pressurized application systems were employed. The mean Potential Dermal Exposure (PDE) was measured using the Whole Body Dosimetry technique. The PDE for the applicators was 188 mL h−1 ± 103 mL h−1, and 14.7 mL h−1 ± 6.3 mL h−1 for the assistants. In the first case, the most exposed body sections were the upper right and left (46.8 mL h−1 ± 23.4 mL h−1; 47.0 mL h−1 ± 23.5 mL h−1) and lower (20.8 mL h−1 ± 10.4 mL h−1; 17.3 mL h−1 ± 8.7 mL h−1) legs, while in the case of assistants, hands and legs were the most impacted limbs. Regarding the Margin of Safety (MOS) during the mix and load stage, two of three pesticide preparations resulted unsafe, while for the applicators, six of six spraying operations were unsafe. For the assistants, five of five operations were safe, but three of them were close to the safety limit. Procymidone distribution between drift (0.03% ± 0.07 %), applicator (0.20% ± 0.15 %), polyethylene mulching (8.5% ± 4.5 %) and soil (3.0% ± 1.1 %) was determined with respect to the total pesticide applied. Procymidone soil impact was also evaluated using Eisenia andrei behavioral tests, finding positive correlations between procymidone application and avoidance and reproduction tests.
publishDate 2020
dc.date.none.fl_str_mv 2020-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/172260
Fitó Friedrichs, Gretel Alejandra; Berenstein, Giselle Anahí; Nasello, María Soledad; Dutra Alcoba, Yohana Yisel; Hughes, Enrique Alejandro; et al.; Human exposure and mass balance distribution during procymidone application in horticultural greenhouses; Elsevier; Heliyon; 6; 1; 1-2020; 1-10
2405-8440
CONICET Digital
CONICET
url http://hdl.handle.net/11336/172260
identifier_str_mv Fitó Friedrichs, Gretel Alejandra; Berenstein, Giselle Anahí; Nasello, María Soledad; Dutra Alcoba, Yohana Yisel; Hughes, Enrique Alejandro; et al.; Human exposure and mass balance distribution during procymidone application in horticultural greenhouses; Elsevier; Heliyon; 6; 1; 1-2020; 1-10
2405-8440
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2405844019367520
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.heliyon.2019.e03093
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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