Human exposure and mass balance distribution during procymidone application in horticultural greenhouses
- Autores
- Fitó Friedrichs, Gretel Alejandra; Berenstein, Giselle Anahí; Nasello, María Soledad; Dutra Alcoba, Yohana Yisel; Hughes, Enrique Alejandro; Basack, Silvana Beatriz; Montserrat, Javier Marcelo
- Año de publicación
- 2020
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The purpose of this study was to analyze the impact of procymidone application in periurban horticultural greenhouses, especially on workers (applicators and assistants) and soil and plastic mulching, when mechanically pressurized application systems were employed. The mean Potential Dermal Exposure (PDE) was measured using the Whole Body Dosimetry technique. The PDE for the applicators was 188 mL h−1 ± 103 mL h−1, and 14.7 mL h−1 ± 6.3 mL h−1 for the assistants. In the first case, the most exposed body sections were the upper right and left (46.8 mL h−1 ± 23.4 mL h−1; 47.0 mL h−1 ± 23.5 mL h−1) and lower (20.8 mL h−1 ± 10.4 mL h−1; 17.3 mL h−1 ± 8.7 mL h−1) legs, while in the case of assistants, hands and legs were the most impacted limbs. Regarding the Margin of Safety (MOS) during the mix and load stage, two of three pesticide preparations resulted unsafe, while for the applicators, six of six spraying operations were unsafe. For the assistants, five of five operations were safe, but three of them were close to the safety limit. Procymidone distribution between drift (0.03% ± 0.07 %), applicator (0.20% ± 0.15 %), polyethylene mulching (8.5% ± 4.5 %) and soil (3.0% ± 1.1 %) was determined with respect to the total pesticide applied. Procymidone soil impact was also evaluated using Eisenia andrei behavioral tests, finding positive correlations between procymidone application and avoidance and reproduction tests.
Fil: Fitó Friedrichs, Gretel Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Berenstein, Giselle Anahí. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Nasello, María Soledad. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Dutra Alcoba, Yohana Yisel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Hughes, Enrique Alejandro. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Basack, Silvana Beatriz. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina
Fil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina - Materia
-
EISENIA ANDREI
ENVIRONMENTAL CHEMISTRY
ENVIRONMENTAL POLLUTION
ENVIRONMENTAL RISK ASSESSMENT
EXPOSURE
HORTICULTURE
MOS
PDE
PESTICIDE
PROCYMIDONE
SOIL - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/172260
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Human exposure and mass balance distribution during procymidone application in horticultural greenhousesFitó Friedrichs, Gretel AlejandraBerenstein, Giselle AnahíNasello, María SoledadDutra Alcoba, Yohana YiselHughes, Enrique AlejandroBasack, Silvana BeatrizMontserrat, Javier MarceloEISENIA ANDREIENVIRONMENTAL CHEMISTRYENVIRONMENTAL POLLUTIONENVIRONMENTAL RISK ASSESSMENTEXPOSUREHORTICULTUREMOSPDEPESTICIDEPROCYMIDONESOILhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The purpose of this study was to analyze the impact of procymidone application in periurban horticultural greenhouses, especially on workers (applicators and assistants) and soil and plastic mulching, when mechanically pressurized application systems were employed. The mean Potential Dermal Exposure (PDE) was measured using the Whole Body Dosimetry technique. The PDE for the applicators was 188 mL h−1 ± 103 mL h−1, and 14.7 mL h−1 ± 6.3 mL h−1 for the assistants. In the first case, the most exposed body sections were the upper right and left (46.8 mL h−1 ± 23.4 mL h−1; 47.0 mL h−1 ± 23.5 mL h−1) and lower (20.8 mL h−1 ± 10.4 mL h−1; 17.3 mL h−1 ± 8.7 mL h−1) legs, while in the case of assistants, hands and legs were the most impacted limbs. Regarding the Margin of Safety (MOS) during the mix and load stage, two of three pesticide preparations resulted unsafe, while for the applicators, six of six spraying operations were unsafe. For the assistants, five of five operations were safe, but three of them were close to the safety limit. Procymidone distribution between drift (0.03% ± 0.07 %), applicator (0.20% ± 0.15 %), polyethylene mulching (8.5% ± 4.5 %) and soil (3.0% ± 1.1 %) was determined with respect to the total pesticide applied. Procymidone soil impact was also evaluated using Eisenia andrei behavioral tests, finding positive correlations between procymidone application and avoidance and reproduction tests.Fil: Fitó Friedrichs, Gretel Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Berenstein, Giselle Anahí. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Nasello, María Soledad. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Dutra Alcoba, Yohana Yisel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Hughes, Enrique Alejandro. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Basack, Silvana Beatriz. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaFil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; ArgentinaElsevier2020-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/172260Fitó Friedrichs, Gretel Alejandra; Berenstein, Giselle Anahí; Nasello, María Soledad; Dutra Alcoba, Yohana Yisel; Hughes, Enrique Alejandro; et al.; Human exposure and mass balance distribution during procymidone application in horticultural greenhouses; Elsevier; Heliyon; 6; 1; 1-2020; 1-102405-8440CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2405844019367520info:eu-repo/semantics/altIdentifier/doi/10.1016/j.heliyon.2019.e03093info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:10:42Zoai:ri.conicet.gov.ar:11336/172260instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:10:43.179CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Human exposure and mass balance distribution during procymidone application in horticultural greenhouses |
title |
Human exposure and mass balance distribution during procymidone application in horticultural greenhouses |
spellingShingle |
Human exposure and mass balance distribution during procymidone application in horticultural greenhouses Fitó Friedrichs, Gretel Alejandra EISENIA ANDREI ENVIRONMENTAL CHEMISTRY ENVIRONMENTAL POLLUTION ENVIRONMENTAL RISK ASSESSMENT EXPOSURE HORTICULTURE MOS PDE PESTICIDE PROCYMIDONE SOIL |
title_short |
Human exposure and mass balance distribution during procymidone application in horticultural greenhouses |
title_full |
Human exposure and mass balance distribution during procymidone application in horticultural greenhouses |
title_fullStr |
Human exposure and mass balance distribution during procymidone application in horticultural greenhouses |
title_full_unstemmed |
Human exposure and mass balance distribution during procymidone application in horticultural greenhouses |
title_sort |
Human exposure and mass balance distribution during procymidone application in horticultural greenhouses |
dc.creator.none.fl_str_mv |
Fitó Friedrichs, Gretel Alejandra Berenstein, Giselle Anahí Nasello, María Soledad Dutra Alcoba, Yohana Yisel Hughes, Enrique Alejandro Basack, Silvana Beatriz Montserrat, Javier Marcelo |
author |
Fitó Friedrichs, Gretel Alejandra |
author_facet |
Fitó Friedrichs, Gretel Alejandra Berenstein, Giselle Anahí Nasello, María Soledad Dutra Alcoba, Yohana Yisel Hughes, Enrique Alejandro Basack, Silvana Beatriz Montserrat, Javier Marcelo |
author_role |
author |
author2 |
Berenstein, Giselle Anahí Nasello, María Soledad Dutra Alcoba, Yohana Yisel Hughes, Enrique Alejandro Basack, Silvana Beatriz Montserrat, Javier Marcelo |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
EISENIA ANDREI ENVIRONMENTAL CHEMISTRY ENVIRONMENTAL POLLUTION ENVIRONMENTAL RISK ASSESSMENT EXPOSURE HORTICULTURE MOS PDE PESTICIDE PROCYMIDONE SOIL |
topic |
EISENIA ANDREI ENVIRONMENTAL CHEMISTRY ENVIRONMENTAL POLLUTION ENVIRONMENTAL RISK ASSESSMENT EXPOSURE HORTICULTURE MOS PDE PESTICIDE PROCYMIDONE SOIL |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The purpose of this study was to analyze the impact of procymidone application in periurban horticultural greenhouses, especially on workers (applicators and assistants) and soil and plastic mulching, when mechanically pressurized application systems were employed. The mean Potential Dermal Exposure (PDE) was measured using the Whole Body Dosimetry technique. The PDE for the applicators was 188 mL h−1 ± 103 mL h−1, and 14.7 mL h−1 ± 6.3 mL h−1 for the assistants. In the first case, the most exposed body sections were the upper right and left (46.8 mL h−1 ± 23.4 mL h−1; 47.0 mL h−1 ± 23.5 mL h−1) and lower (20.8 mL h−1 ± 10.4 mL h−1; 17.3 mL h−1 ± 8.7 mL h−1) legs, while in the case of assistants, hands and legs were the most impacted limbs. Regarding the Margin of Safety (MOS) during the mix and load stage, two of three pesticide preparations resulted unsafe, while for the applicators, six of six spraying operations were unsafe. For the assistants, five of five operations were safe, but three of them were close to the safety limit. Procymidone distribution between drift (0.03% ± 0.07 %), applicator (0.20% ± 0.15 %), polyethylene mulching (8.5% ± 4.5 %) and soil (3.0% ± 1.1 %) was determined with respect to the total pesticide applied. Procymidone soil impact was also evaluated using Eisenia andrei behavioral tests, finding positive correlations between procymidone application and avoidance and reproduction tests. Fil: Fitó Friedrichs, Gretel Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina Fil: Berenstein, Giselle Anahí. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina Fil: Nasello, María Soledad. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina Fil: Dutra Alcoba, Yohana Yisel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina Fil: Hughes, Enrique Alejandro. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina Fil: Basack, Silvana Beatriz. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina Fil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Área de Química; Argentina |
description |
The purpose of this study was to analyze the impact of procymidone application in periurban horticultural greenhouses, especially on workers (applicators and assistants) and soil and plastic mulching, when mechanically pressurized application systems were employed. The mean Potential Dermal Exposure (PDE) was measured using the Whole Body Dosimetry technique. The PDE for the applicators was 188 mL h−1 ± 103 mL h−1, and 14.7 mL h−1 ± 6.3 mL h−1 for the assistants. In the first case, the most exposed body sections were the upper right and left (46.8 mL h−1 ± 23.4 mL h−1; 47.0 mL h−1 ± 23.5 mL h−1) and lower (20.8 mL h−1 ± 10.4 mL h−1; 17.3 mL h−1 ± 8.7 mL h−1) legs, while in the case of assistants, hands and legs were the most impacted limbs. Regarding the Margin of Safety (MOS) during the mix and load stage, two of three pesticide preparations resulted unsafe, while for the applicators, six of six spraying operations were unsafe. For the assistants, five of five operations were safe, but three of them were close to the safety limit. Procymidone distribution between drift (0.03% ± 0.07 %), applicator (0.20% ± 0.15 %), polyethylene mulching (8.5% ± 4.5 %) and soil (3.0% ± 1.1 %) was determined with respect to the total pesticide applied. Procymidone soil impact was also evaluated using Eisenia andrei behavioral tests, finding positive correlations between procymidone application and avoidance and reproduction tests. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/172260 Fitó Friedrichs, Gretel Alejandra; Berenstein, Giselle Anahí; Nasello, María Soledad; Dutra Alcoba, Yohana Yisel; Hughes, Enrique Alejandro; et al.; Human exposure and mass balance distribution during procymidone application in horticultural greenhouses; Elsevier; Heliyon; 6; 1; 1-2020; 1-10 2405-8440 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/172260 |
identifier_str_mv |
Fitó Friedrichs, Gretel Alejandra; Berenstein, Giselle Anahí; Nasello, María Soledad; Dutra Alcoba, Yohana Yisel; Hughes, Enrique Alejandro; et al.; Human exposure and mass balance distribution during procymidone application in horticultural greenhouses; Elsevier; Heliyon; 6; 1; 1-2020; 1-10 2405-8440 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2405844019367520 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.heliyon.2019.e03093 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1842270131253673984 |
score |
13.13397 |