Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy
- Autores
- D'amico, David Alberto; Iglesias Montes, Magdalena Luz; Manfredi, Liliana Beatriz; Cyras, Viviana Paola
- Año de publicación
- 2016
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Biodegradable polymeric blends based on poly(3-hydroxybutyrate) (PHB) and polylactic acid (PLA) were prepared by melt mixing. Trybutyrin, a bio-based plasticizer, was added at a fixed proportion in all blends. Crystal structure, percent crystallinity, miscibility, mechanical properties and permeation of fully biodegradable PHB/PLA blends were investigated in detail by Differential Scanning Calorimetry (DSC), Fourier Transformed Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), tensile tests and water vapor permeation tests. From the thermal test, two glass transition temperatures were found for the whole range of compositions, which reveals the immiscibility between PHB and PLA. Moreover, the biphasic melt further confirms this fact. Tensile tests showed an increase in the elongation at break with the PLA content. SEM images reveal debonding between the interfacial surfaces, which justifies the increase in the elongation at break. Water vapor permeation values for blends were slightly higher than that of the plasticized pristine polymer. The plasticized polymer blends showed valuable properties to extend the applications of PHB and PLA.
Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Iglesias Montes, Magdalena Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
Bio-Based Polymers
Blends
Poly(3-Hydroxybutyrate) (Phb)
Polylactic Acid (Pla)
Processing - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/40040
Ver los metadatos del registro completo
id |
CONICETDig_24a2c2f4d1a003bcc41d968bc2848a7a |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/40040 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategyD'amico, David AlbertoIglesias Montes, Magdalena LuzManfredi, Liliana BeatrizCyras, Viviana PaolaBio-Based PolymersBlendsPoly(3-Hydroxybutyrate) (Phb)Polylactic Acid (Pla)Processinghttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Biodegradable polymeric blends based on poly(3-hydroxybutyrate) (PHB) and polylactic acid (PLA) were prepared by melt mixing. Trybutyrin, a bio-based plasticizer, was added at a fixed proportion in all blends. Crystal structure, percent crystallinity, miscibility, mechanical properties and permeation of fully biodegradable PHB/PLA blends were investigated in detail by Differential Scanning Calorimetry (DSC), Fourier Transformed Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), tensile tests and water vapor permeation tests. From the thermal test, two glass transition temperatures were found for the whole range of compositions, which reveals the immiscibility between PHB and PLA. Moreover, the biphasic melt further confirms this fact. Tensile tests showed an increase in the elongation at break with the PLA content. SEM images reveal debonding between the interfacial surfaces, which justifies the increase in the elongation at break. Water vapor permeation values for blends were slightly higher than that of the plasticized pristine polymer. The plasticized polymer blends showed valuable properties to extend the applications of PHB and PLA.Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Iglesias Montes, Magdalena Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier2016-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/40040D'amico, David Alberto; Iglesias Montes, Magdalena Luz; Manfredi, Liliana Beatriz; Cyras, Viviana Paola; Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy; Elsevier; Polymer Testing; 49; 2-2016; 22-280142-9418CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymertesting.2015.11.004info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0142941815300222info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:44:04Zoai:ri.conicet.gov.ar:11336/40040instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:44:04.732CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy |
title |
Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy |
spellingShingle |
Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy D'amico, David Alberto Bio-Based Polymers Blends Poly(3-Hydroxybutyrate) (Phb) Polylactic Acid (Pla) Processing |
title_short |
Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy |
title_full |
Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy |
title_fullStr |
Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy |
title_full_unstemmed |
Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy |
title_sort |
Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy |
dc.creator.none.fl_str_mv |
D'amico, David Alberto Iglesias Montes, Magdalena Luz Manfredi, Liliana Beatriz Cyras, Viviana Paola |
author |
D'amico, David Alberto |
author_facet |
D'amico, David Alberto Iglesias Montes, Magdalena Luz Manfredi, Liliana Beatriz Cyras, Viviana Paola |
author_role |
author |
author2 |
Iglesias Montes, Magdalena Luz Manfredi, Liliana Beatriz Cyras, Viviana Paola |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Bio-Based Polymers Blends Poly(3-Hydroxybutyrate) (Phb) Polylactic Acid (Pla) Processing |
topic |
Bio-Based Polymers Blends Poly(3-Hydroxybutyrate) (Phb) Polylactic Acid (Pla) Processing |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Biodegradable polymeric blends based on poly(3-hydroxybutyrate) (PHB) and polylactic acid (PLA) were prepared by melt mixing. Trybutyrin, a bio-based plasticizer, was added at a fixed proportion in all blends. Crystal structure, percent crystallinity, miscibility, mechanical properties and permeation of fully biodegradable PHB/PLA blends were investigated in detail by Differential Scanning Calorimetry (DSC), Fourier Transformed Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), tensile tests and water vapor permeation tests. From the thermal test, two glass transition temperatures were found for the whole range of compositions, which reveals the immiscibility between PHB and PLA. Moreover, the biphasic melt further confirms this fact. Tensile tests showed an increase in the elongation at break with the PLA content. SEM images reveal debonding between the interfacial surfaces, which justifies the increase in the elongation at break. Water vapor permeation values for blends were slightly higher than that of the plasticized pristine polymer. The plasticized polymer blends showed valuable properties to extend the applications of PHB and PLA. Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Iglesias Montes, Magdalena Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
Biodegradable polymeric blends based on poly(3-hydroxybutyrate) (PHB) and polylactic acid (PLA) were prepared by melt mixing. Trybutyrin, a bio-based plasticizer, was added at a fixed proportion in all blends. Crystal structure, percent crystallinity, miscibility, mechanical properties and permeation of fully biodegradable PHB/PLA blends were investigated in detail by Differential Scanning Calorimetry (DSC), Fourier Transformed Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), tensile tests and water vapor permeation tests. From the thermal test, two glass transition temperatures were found for the whole range of compositions, which reveals the immiscibility between PHB and PLA. Moreover, the biphasic melt further confirms this fact. Tensile tests showed an increase in the elongation at break with the PLA content. SEM images reveal debonding between the interfacial surfaces, which justifies the increase in the elongation at break. Water vapor permeation values for blends were slightly higher than that of the plasticized pristine polymer. The plasticized polymer blends showed valuable properties to extend the applications of PHB and PLA. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/40040 D'amico, David Alberto; Iglesias Montes, Magdalena Luz; Manfredi, Liliana Beatriz; Cyras, Viviana Paola; Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy; Elsevier; Polymer Testing; 49; 2-2016; 22-28 0142-9418 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/40040 |
identifier_str_mv |
D'amico, David Alberto; Iglesias Montes, Magdalena Luz; Manfredi, Liliana Beatriz; Cyras, Viviana Paola; Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy; Elsevier; Polymer Testing; 49; 2-2016; 22-28 0142-9418 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymertesting.2015.11.004 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0142941815300222 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1842268643524608000 |
score |
13.13397 |