Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy

Autores
D'amico, David Alberto; Iglesias Montes, Magdalena Luz; Manfredi, Liliana Beatriz; Cyras, Viviana Paola
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Biodegradable polymeric blends based on poly(3-hydroxybutyrate) (PHB) and polylactic acid (PLA) were prepared by melt mixing. Trybutyrin, a bio-based plasticizer, was added at a fixed proportion in all blends. Crystal structure, percent crystallinity, miscibility, mechanical properties and permeation of fully biodegradable PHB/PLA blends were investigated in detail by Differential Scanning Calorimetry (DSC), Fourier Transformed Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), tensile tests and water vapor permeation tests. From the thermal test, two glass transition temperatures were found for the whole range of compositions, which reveals the immiscibility between PHB and PLA. Moreover, the biphasic melt further confirms this fact. Tensile tests showed an increase in the elongation at break with the PLA content. SEM images reveal debonding between the interfacial surfaces, which justifies the increase in the elongation at break. Water vapor permeation values for blends were slightly higher than that of the plasticized pristine polymer. The plasticized polymer blends showed valuable properties to extend the applications of PHB and PLA.
Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Iglesias Montes, Magdalena Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Bio-Based Polymers
Blends
Poly(3-Hydroxybutyrate) (Phb)
Polylactic Acid (Pla)
Processing
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/40040
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategyD'amico, David AlbertoIglesias Montes, Magdalena LuzManfredi, Liliana BeatrizCyras, Viviana PaolaBio-Based PolymersBlendsPoly(3-Hydroxybutyrate) (Phb)Polylactic Acid (Pla)Processinghttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Biodegradable polymeric blends based on poly(3-hydroxybutyrate) (PHB) and polylactic acid (PLA) were prepared by melt mixing. Trybutyrin, a bio-based plasticizer, was added at a fixed proportion in all blends. Crystal structure, percent crystallinity, miscibility, mechanical properties and permeation of fully biodegradable PHB/PLA blends were investigated in detail by Differential Scanning Calorimetry (DSC), Fourier Transformed Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), tensile tests and water vapor permeation tests. From the thermal test, two glass transition temperatures were found for the whole range of compositions, which reveals the immiscibility between PHB and PLA. Moreover, the biphasic melt further confirms this fact. Tensile tests showed an increase in the elongation at break with the PLA content. SEM images reveal debonding between the interfacial surfaces, which justifies the increase in the elongation at break. Water vapor permeation values for blends were slightly higher than that of the plasticized pristine polymer. The plasticized polymer blends showed valuable properties to extend the applications of PHB and PLA.Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Iglesias Montes, Magdalena Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier2016-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/40040D'amico, David Alberto; Iglesias Montes, Magdalena Luz; Manfredi, Liliana Beatriz; Cyras, Viviana Paola; Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy; Elsevier; Polymer Testing; 49; 2-2016; 22-280142-9418CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymertesting.2015.11.004info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0142941815300222info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:42Zoai:ri.conicet.gov.ar:11336/40040instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:43.115CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy
title Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy
spellingShingle Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy
D'amico, David Alberto
Bio-Based Polymers
Blends
Poly(3-Hydroxybutyrate) (Phb)
Polylactic Acid (Pla)
Processing
title_short Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy
title_full Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy
title_fullStr Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy
title_full_unstemmed Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy
title_sort Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy
dc.creator.none.fl_str_mv D'amico, David Alberto
Iglesias Montes, Magdalena Luz
Manfredi, Liliana Beatriz
Cyras, Viviana Paola
author D'amico, David Alberto
author_facet D'amico, David Alberto
Iglesias Montes, Magdalena Luz
Manfredi, Liliana Beatriz
Cyras, Viviana Paola
author_role author
author2 Iglesias Montes, Magdalena Luz
Manfredi, Liliana Beatriz
Cyras, Viviana Paola
author2_role author
author
author
dc.subject.none.fl_str_mv Bio-Based Polymers
Blends
Poly(3-Hydroxybutyrate) (Phb)
Polylactic Acid (Pla)
Processing
topic Bio-Based Polymers
Blends
Poly(3-Hydroxybutyrate) (Phb)
Polylactic Acid (Pla)
Processing
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Biodegradable polymeric blends based on poly(3-hydroxybutyrate) (PHB) and polylactic acid (PLA) were prepared by melt mixing. Trybutyrin, a bio-based plasticizer, was added at a fixed proportion in all blends. Crystal structure, percent crystallinity, miscibility, mechanical properties and permeation of fully biodegradable PHB/PLA blends were investigated in detail by Differential Scanning Calorimetry (DSC), Fourier Transformed Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), tensile tests and water vapor permeation tests. From the thermal test, two glass transition temperatures were found for the whole range of compositions, which reveals the immiscibility between PHB and PLA. Moreover, the biphasic melt further confirms this fact. Tensile tests showed an increase in the elongation at break with the PLA content. SEM images reveal debonding between the interfacial surfaces, which justifies the increase in the elongation at break. Water vapor permeation values for blends were slightly higher than that of the plasticized pristine polymer. The plasticized polymer blends showed valuable properties to extend the applications of PHB and PLA.
Fil: D'amico, David Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Iglesias Montes, Magdalena Luz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Biodegradable polymeric blends based on poly(3-hydroxybutyrate) (PHB) and polylactic acid (PLA) were prepared by melt mixing. Trybutyrin, a bio-based plasticizer, was added at a fixed proportion in all blends. Crystal structure, percent crystallinity, miscibility, mechanical properties and permeation of fully biodegradable PHB/PLA blends were investigated in detail by Differential Scanning Calorimetry (DSC), Fourier Transformed Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), tensile tests and water vapor permeation tests. From the thermal test, two glass transition temperatures were found for the whole range of compositions, which reveals the immiscibility between PHB and PLA. Moreover, the biphasic melt further confirms this fact. Tensile tests showed an increase in the elongation at break with the PLA content. SEM images reveal debonding between the interfacial surfaces, which justifies the increase in the elongation at break. Water vapor permeation values for blends were slightly higher than that of the plasticized pristine polymer. The plasticized polymer blends showed valuable properties to extend the applications of PHB and PLA.
publishDate 2016
dc.date.none.fl_str_mv 2016-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/40040
D'amico, David Alberto; Iglesias Montes, Magdalena Luz; Manfredi, Liliana Beatriz; Cyras, Viviana Paola; Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy; Elsevier; Polymer Testing; 49; 2-2016; 22-28
0142-9418
CONICET Digital
CONICET
url http://hdl.handle.net/11336/40040
identifier_str_mv D'amico, David Alberto; Iglesias Montes, Magdalena Luz; Manfredi, Liliana Beatriz; Cyras, Viviana Paola; Fully bio-based and biodegradable polylactic acid/poly(3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy; Elsevier; Polymer Testing; 49; 2-2016; 22-28
0142-9418
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymertesting.2015.11.004
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0142941815300222
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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