Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization

Autores
Astudillo, Alejandro; Fauda, Darío; Querini, Carlos Alberto; Comelli, Raul Alberto
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Ammonium and potassium ferrierites were modified with tungsten or boron species using incipient wetness and wet impregnation or ion exchange. Catalytic behavior during the linear butene skeletal isomerization was measured at 300 and 450ºC, at atmospheric pressure and 0.15 atm 1-butene partial pressure. At 3000C and a short time, catalysts having strong acid sites practically reach the same high butene conversion with a low isobutene selectivity. Those acid sites favor undesirable side reactions. At a long time, conversion decreases. At a short time, tungsten exchanged on potassium-ferrierite produces two times the ferrierite’s isobutene yield. At a long time, boron impregnated on ferrierite reaches the largest isobutene production. At 450ºC, the high conversion is maintained even at a long time. At this temperature, tungsten impregnated on potassium-ferrierite, sample without strong acid sites, practically produces the same isobutene yield of ferrierite, even though its conversion is only a half of the ferrierite one. By considering by-product distributions, it can be inferred that dimerization and oligomerization reactions take place. Carbonaceous deposits were characterized by temperature-programmed oxidation and FTIR. The acid strength of active sites influences the coke amount. Independent of temperature, carbonaceous deposit formed on samples with strong acid sites is between 6.0 and 7.4%. The smallest amount (1.0%) is formed on tungsten impregnated potassium-ferrierite, which only displays the low-temperature combustion peak after reaction at 300ºC. Reaction temperature and type of acid sites affect the nature of carbonaceous deposit. Both olefinic species and aromatic rings appear in the deposit formed at 300ºC; aromatic coke increases when reaction takes place at 450ºC. Isobutene dimeric species play a role in coke formation.
Fil: Astudillo, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Fauda, Darío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Comelli, Raul Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Butenes,
Skeletal Isomerization
Tungsten-Ferrierite,
Boron-Ferrierite, Deactivation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/78032
Acceder
id CONICETDig_2410af1454ad1a6a3087281a9f4e3801
oai_identifier_str oai:ri.conicet.gov.ar:11336/78032
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerizationAstudillo, AlejandroFauda, DaríoQuerini, Carlos AlbertoComelli, Raul AlbertoButenes,Skeletal IsomerizationTungsten-Ferrierite,Boron-Ferrierite, Deactivationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Ammonium and potassium ferrierites were modified with tungsten or boron species using incipient wetness and wet impregnation or ion exchange. Catalytic behavior during the linear butene skeletal isomerization was measured at 300 and 450ºC, at atmospheric pressure and 0.15 atm 1-butene partial pressure. At 3000C and a short time, catalysts having strong acid sites practically reach the same high butene conversion with a low isobutene selectivity. Those acid sites favor undesirable side reactions. At a long time, conversion decreases. At a short time, tungsten exchanged on potassium-ferrierite produces two times the ferrierite’s isobutene yield. At a long time, boron impregnated on ferrierite reaches the largest isobutene production. At 450ºC, the high conversion is maintained even at a long time. At this temperature, tungsten impregnated on potassium-ferrierite, sample without strong acid sites, practically produces the same isobutene yield of ferrierite, even though its conversion is only a half of the ferrierite one. By considering by-product distributions, it can be inferred that dimerization and oligomerization reactions take place. Carbonaceous deposits were characterized by temperature-programmed oxidation and FTIR. The acid strength of active sites influences the coke amount. Independent of temperature, carbonaceous deposit formed on samples with strong acid sites is between 6.0 and 7.4%. The smallest amount (1.0%) is formed on tungsten impregnated potassium-ferrierite, which only displays the low-temperature combustion peak after reaction at 300ºC. Reaction temperature and type of acid sites affect the nature of carbonaceous deposit. Both olefinic species and aromatic rings appear in the deposit formed at 300ºC; aromatic coke increases when reaction takes place at 450ºC. Isobutene dimeric species play a role in coke formation.Fil: Astudillo, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Fauda, Darío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Comelli, Raul Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaResearch Trends2006-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/78032Astudillo, Alejandro; Fauda, Darío; Querini, Carlos Alberto; Comelli, Raul Alberto; Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization; Research Trends; Current Topics in Catalysis; 5; 12-2006; 89-1020972-4508CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.researchtrends.net/tia/abstract.asp?in=0&vn=5&tid=23&aid=2220&pub=2006&type=3info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:27:49Zoai:ri.conicet.gov.ar:11336/78032instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:27:50.01CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization
title Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization
spellingShingle Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization
Astudillo, Alejandro
Butenes,
Skeletal Isomerization
Tungsten-Ferrierite,
Boron-Ferrierite, Deactivation
title_short Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization
title_full Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization
title_fullStr Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization
title_full_unstemmed Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization
title_sort Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization
dc.creator.none.fl_str_mv Astudillo, Alejandro
Fauda, Darío
Querini, Carlos Alberto
Comelli, Raul Alberto
author Astudillo, Alejandro
author_facet Astudillo, Alejandro
Fauda, Darío
Querini, Carlos Alberto
Comelli, Raul Alberto
author_role author
author2 Fauda, Darío
Querini, Carlos Alberto
Comelli, Raul Alberto
author2_role author
author
author
dc.subject.none.fl_str_mv Butenes,
Skeletal Isomerization
Tungsten-Ferrierite,
Boron-Ferrierite, Deactivation
topic Butenes,
Skeletal Isomerization
Tungsten-Ferrierite,
Boron-Ferrierite, Deactivation
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Ammonium and potassium ferrierites were modified with tungsten or boron species using incipient wetness and wet impregnation or ion exchange. Catalytic behavior during the linear butene skeletal isomerization was measured at 300 and 450ºC, at atmospheric pressure and 0.15 atm 1-butene partial pressure. At 3000C and a short time, catalysts having strong acid sites practically reach the same high butene conversion with a low isobutene selectivity. Those acid sites favor undesirable side reactions. At a long time, conversion decreases. At a short time, tungsten exchanged on potassium-ferrierite produces two times the ferrierite’s isobutene yield. At a long time, boron impregnated on ferrierite reaches the largest isobutene production. At 450ºC, the high conversion is maintained even at a long time. At this temperature, tungsten impregnated on potassium-ferrierite, sample without strong acid sites, practically produces the same isobutene yield of ferrierite, even though its conversion is only a half of the ferrierite one. By considering by-product distributions, it can be inferred that dimerization and oligomerization reactions take place. Carbonaceous deposits were characterized by temperature-programmed oxidation and FTIR. The acid strength of active sites influences the coke amount. Independent of temperature, carbonaceous deposit formed on samples with strong acid sites is between 6.0 and 7.4%. The smallest amount (1.0%) is formed on tungsten impregnated potassium-ferrierite, which only displays the low-temperature combustion peak after reaction at 300ºC. Reaction temperature and type of acid sites affect the nature of carbonaceous deposit. Both olefinic species and aromatic rings appear in the deposit formed at 300ºC; aromatic coke increases when reaction takes place at 450ºC. Isobutene dimeric species play a role in coke formation.
Fil: Astudillo, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Fauda, Darío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Comelli, Raul Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description Ammonium and potassium ferrierites were modified with tungsten or boron species using incipient wetness and wet impregnation or ion exchange. Catalytic behavior during the linear butene skeletal isomerization was measured at 300 and 450ºC, at atmospheric pressure and 0.15 atm 1-butene partial pressure. At 3000C and a short time, catalysts having strong acid sites practically reach the same high butene conversion with a low isobutene selectivity. Those acid sites favor undesirable side reactions. At a long time, conversion decreases. At a short time, tungsten exchanged on potassium-ferrierite produces two times the ferrierite’s isobutene yield. At a long time, boron impregnated on ferrierite reaches the largest isobutene production. At 450ºC, the high conversion is maintained even at a long time. At this temperature, tungsten impregnated on potassium-ferrierite, sample without strong acid sites, practically produces the same isobutene yield of ferrierite, even though its conversion is only a half of the ferrierite one. By considering by-product distributions, it can be inferred that dimerization and oligomerization reactions take place. Carbonaceous deposits were characterized by temperature-programmed oxidation and FTIR. The acid strength of active sites influences the coke amount. Independent of temperature, carbonaceous deposit formed on samples with strong acid sites is between 6.0 and 7.4%. The smallest amount (1.0%) is formed on tungsten impregnated potassium-ferrierite, which only displays the low-temperature combustion peak after reaction at 300ºC. Reaction temperature and type of acid sites affect the nature of carbonaceous deposit. Both olefinic species and aromatic rings appear in the deposit formed at 300ºC; aromatic coke increases when reaction takes place at 450ºC. Isobutene dimeric species play a role in coke formation.
publishDate 2006
dc.date.none.fl_str_mv 2006-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/78032
Astudillo, Alejandro; Fauda, Darío; Querini, Carlos Alberto; Comelli, Raul Alberto; Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization; Research Trends; Current Topics in Catalysis; 5; 12-2006; 89-102
0972-4508
CONICET Digital
CONICET
url http://hdl.handle.net/11336/78032
identifier_str_mv Astudillo, Alejandro; Fauda, Darío; Querini, Carlos Alberto; Comelli, Raul Alberto; Performance of ferrierite promoted with tungsten or boron species during the linear butene skeletal isomerization; Research Trends; Current Topics in Catalysis; 5; 12-2006; 89-102
0972-4508
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.researchtrends.net/tia/abstract.asp?in=0&vn=5&tid=23&aid=2220&pub=2006&type=3
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Research Trends
publisher.none.fl_str_mv Research Trends
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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