Linear butene skeletal isomerization over boron-promoted ferrierite
- Autores
- Coronati, Iván; Font, Guillermo; Fontana, Nicolás; Querini, Carlos Alberto; Comelli, Raul Alberto
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Boron-promoted potassium-ferrierite catalysts were prepared following the wet impregnation technique. Both boron concentration and pH of impregnating solution were changed. Catalytic behavior was measured during the butene skeletal isomerization. H+ ion exchange induced by impregnation medium and presence of boron species promote catalytic activity, isobutene yield, and catalyst stability. The catalyst impregnated with 0.01 M solution at pH 0.8 showed the best performance. The effect of temperature, butene partial pressure, and contact time was evaluated. The high stability of this catalyst is an important goal. Large conversion and high isobutene yield were reached in the 400-525 °C range; the largest yield (38%) was obtained at 475 °C. Both linear butene conversion and isobutene yield increased by increasing contact time or by decreasing the butene partial pressure. Isobutene yield remained practically constant during 24 h of reaction. Carbonaceous deposit formed during reaction was characterized by temperature-programmed oxidation and by FTIR. Coke amount at different reaction conditions was lower than 0.7%. Active catalysts displayed the maximum of the combustion peak between 560 and 608 °C, shifting to higher temperature when reaction temperature increases. After 24 h of reaction at 450 °C, the carbonaceous deposit only reaches 0.9%, being it 6.0% after 120 h.
Fil: Coronati, Iván. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Font, Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Fontana, Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Comelli, Raul Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina - Materia
-
Linear Butenes
Skeletal Isomerization
Isobutene
Boron-Potassium Ferierite
Stability - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/65159
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Linear butene skeletal isomerization over boron-promoted ferrieriteCoronati, IvánFont, GuillermoFontana, NicolásQuerini, Carlos AlbertoComelli, Raul AlbertoLinear ButenesSkeletal IsomerizationIsobuteneBoron-Potassium FerieriteStabilityhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Boron-promoted potassium-ferrierite catalysts were prepared following the wet impregnation technique. Both boron concentration and pH of impregnating solution were changed. Catalytic behavior was measured during the butene skeletal isomerization. H+ ion exchange induced by impregnation medium and presence of boron species promote catalytic activity, isobutene yield, and catalyst stability. The catalyst impregnated with 0.01 M solution at pH 0.8 showed the best performance. The effect of temperature, butene partial pressure, and contact time was evaluated. The high stability of this catalyst is an important goal. Large conversion and high isobutene yield were reached in the 400-525 °C range; the largest yield (38%) was obtained at 475 °C. Both linear butene conversion and isobutene yield increased by increasing contact time or by decreasing the butene partial pressure. Isobutene yield remained practically constant during 24 h of reaction. Carbonaceous deposit formed during reaction was characterized by temperature-programmed oxidation and by FTIR. Coke amount at different reaction conditions was lower than 0.7%. Active catalysts displayed the maximum of the combustion peak between 560 and 608 °C, shifting to higher temperature when reaction temperature increases. After 24 h of reaction at 450 °C, the carbonaceous deposit only reaches 0.9%, being it 6.0% after 120 h.Fil: Coronati, Iván. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Font, Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Fontana, Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Comelli, Raul Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2008-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/65159Coronati, Iván; Font, Guillermo; Fontana, Nicolás; Querini, Carlos Alberto; Comelli, Raul Alberto; Linear butene skeletal isomerization over boron-promoted ferrierite; Elsevier Science; Catalysis Today; 133-135; 1-4; 4-2008; 63-680920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2007.12.023info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:19Zoai:ri.conicet.gov.ar:11336/65159instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:20.285CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Linear butene skeletal isomerization over boron-promoted ferrierite |
title |
Linear butene skeletal isomerization over boron-promoted ferrierite |
spellingShingle |
Linear butene skeletal isomerization over boron-promoted ferrierite Coronati, Iván Linear Butenes Skeletal Isomerization Isobutene Boron-Potassium Ferierite Stability |
title_short |
Linear butene skeletal isomerization over boron-promoted ferrierite |
title_full |
Linear butene skeletal isomerization over boron-promoted ferrierite |
title_fullStr |
Linear butene skeletal isomerization over boron-promoted ferrierite |
title_full_unstemmed |
Linear butene skeletal isomerization over boron-promoted ferrierite |
title_sort |
Linear butene skeletal isomerization over boron-promoted ferrierite |
dc.creator.none.fl_str_mv |
Coronati, Iván Font, Guillermo Fontana, Nicolás Querini, Carlos Alberto Comelli, Raul Alberto |
author |
Coronati, Iván |
author_facet |
Coronati, Iván Font, Guillermo Fontana, Nicolás Querini, Carlos Alberto Comelli, Raul Alberto |
author_role |
author |
author2 |
Font, Guillermo Fontana, Nicolás Querini, Carlos Alberto Comelli, Raul Alberto |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Linear Butenes Skeletal Isomerization Isobutene Boron-Potassium Ferierite Stability |
topic |
Linear Butenes Skeletal Isomerization Isobutene Boron-Potassium Ferierite Stability |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Boron-promoted potassium-ferrierite catalysts were prepared following the wet impregnation technique. Both boron concentration and pH of impregnating solution were changed. Catalytic behavior was measured during the butene skeletal isomerization. H+ ion exchange induced by impregnation medium and presence of boron species promote catalytic activity, isobutene yield, and catalyst stability. The catalyst impregnated with 0.01 M solution at pH 0.8 showed the best performance. The effect of temperature, butene partial pressure, and contact time was evaluated. The high stability of this catalyst is an important goal. Large conversion and high isobutene yield were reached in the 400-525 °C range; the largest yield (38%) was obtained at 475 °C. Both linear butene conversion and isobutene yield increased by increasing contact time or by decreasing the butene partial pressure. Isobutene yield remained practically constant during 24 h of reaction. Carbonaceous deposit formed during reaction was characterized by temperature-programmed oxidation and by FTIR. Coke amount at different reaction conditions was lower than 0.7%. Active catalysts displayed the maximum of the combustion peak between 560 and 608 °C, shifting to higher temperature when reaction temperature increases. After 24 h of reaction at 450 °C, the carbonaceous deposit only reaches 0.9%, being it 6.0% after 120 h. Fil: Coronati, Iván. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Font, Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Fontana, Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Comelli, Raul Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina |
description |
Boron-promoted potassium-ferrierite catalysts were prepared following the wet impregnation technique. Both boron concentration and pH of impregnating solution were changed. Catalytic behavior was measured during the butene skeletal isomerization. H+ ion exchange induced by impregnation medium and presence of boron species promote catalytic activity, isobutene yield, and catalyst stability. The catalyst impregnated with 0.01 M solution at pH 0.8 showed the best performance. The effect of temperature, butene partial pressure, and contact time was evaluated. The high stability of this catalyst is an important goal. Large conversion and high isobutene yield were reached in the 400-525 °C range; the largest yield (38%) was obtained at 475 °C. Both linear butene conversion and isobutene yield increased by increasing contact time or by decreasing the butene partial pressure. Isobutene yield remained practically constant during 24 h of reaction. Carbonaceous deposit formed during reaction was characterized by temperature-programmed oxidation and by FTIR. Coke amount at different reaction conditions was lower than 0.7%. Active catalysts displayed the maximum of the combustion peak between 560 and 608 °C, shifting to higher temperature when reaction temperature increases. After 24 h of reaction at 450 °C, the carbonaceous deposit only reaches 0.9%, being it 6.0% after 120 h. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/65159 Coronati, Iván; Font, Guillermo; Fontana, Nicolás; Querini, Carlos Alberto; Comelli, Raul Alberto; Linear butene skeletal isomerization over boron-promoted ferrierite; Elsevier Science; Catalysis Today; 133-135; 1-4; 4-2008; 63-68 0920-5861 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/65159 |
identifier_str_mv |
Coronati, Iván; Font, Guillermo; Fontana, Nicolás; Querini, Carlos Alberto; Comelli, Raul Alberto; Linear butene skeletal isomerization over boron-promoted ferrierite; Elsevier Science; Catalysis Today; 133-135; 1-4; 4-2008; 63-68 0920-5861 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2007.12.023 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613061437030400 |
score |
13.070432 |