Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis
- Autores
- Springer, Valeria Haydee; Di Anibal, Carolina Vanesa; Lista, Adriana Guillermina
- Año de publicación
- 2016
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A simple and rapid capillary electrophoretic method was developed for the simultaneous determination of two sulfonylurea herbicides in water samples: metsulfuron-methyl (MSM) and nicosulfuron (NS). These herbicides are widely used in agricultural practices and their residues represent potential environment pollutants in waters and soils. The effect of the pH of the background electrolyte solution (BGE), the percentage of methanol in the BGE and the separation voltage were studied on the resolution of MSM and NS. A 23 factorial design was used to identify the main factors which significantly influenced the separation of these compounds. Other parameters were evaluated by the univariate method. The experimental results show that using a BGE composed of 25 mmol·L−1 sodium borate and 3% (v/v) of methanol at pH 8.5 and applying 15 kV, satisfactory analysis time and resolution between peaks can be obtained. The linear range for both analytes was 0.1–2.0 µg·mL−1. The detection limits were 0.034 µg·mL−1 for MSM and 0.044 µg·mL−1 for NS. Surface water and groundwater samples were analyzed applying the new method, and the obtained results presented satisfactory recovery percentages (82%–102%).
Fil: Springer, Valeria Haydee. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Di Anibal, Carolina Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Lista, Adriana Guillermina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina - Materia
-
CAPILLARY ELECTROPHORESIS
MULTIVARIATE OPTIMIZATION
SULFONYLUREA HERBICIDES
WATER SAMPLES - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/62853
Ver los metadatos del registro completo
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spelling |
Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresisSpringer, Valeria HaydeeDi Anibal, Carolina VanesaLista, Adriana GuillerminaCAPILLARY ELECTROPHORESISMULTIVARIATE OPTIMIZATIONSULFONYLUREA HERBICIDESWATER SAMPLEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A simple and rapid capillary electrophoretic method was developed for the simultaneous determination of two sulfonylurea herbicides in water samples: metsulfuron-methyl (MSM) and nicosulfuron (NS). These herbicides are widely used in agricultural practices and their residues represent potential environment pollutants in waters and soils. The effect of the pH of the background electrolyte solution (BGE), the percentage of methanol in the BGE and the separation voltage were studied on the resolution of MSM and NS. A 23 factorial design was used to identify the main factors which significantly influenced the separation of these compounds. Other parameters were evaluated by the univariate method. The experimental results show that using a BGE composed of 25 mmol·L−1 sodium borate and 3% (v/v) of methanol at pH 8.5 and applying 15 kV, satisfactory analysis time and resolution between peaks can be obtained. The linear range for both analytes was 0.1–2.0 µg·mL−1. The detection limits were 0.034 µg·mL−1 for MSM and 0.044 µg·mL−1 for NS. Surface water and groundwater samples were analyzed applying the new method, and the obtained results presented satisfactory recovery percentages (82%–102%).Fil: Springer, Valeria Haydee. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Di Anibal, Carolina Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Lista, Adriana Guillermina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaMDPI2016-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/62853Springer, Valeria Haydee; Di Anibal, Carolina Vanesa; Lista, Adriana Guillermina; Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis; MDPI; Separations; 3; 22; 8-2016; 1-102297-8739CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2297-8739/3/3/22info:eu-repo/semantics/altIdentifier/doi/10.3390/separations3030022info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:04Zoai:ri.conicet.gov.ar:11336/62853instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:04.261CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis |
title |
Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis |
spellingShingle |
Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis Springer, Valeria Haydee CAPILLARY ELECTROPHORESIS MULTIVARIATE OPTIMIZATION SULFONYLUREA HERBICIDES WATER SAMPLES |
title_short |
Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis |
title_full |
Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis |
title_fullStr |
Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis |
title_full_unstemmed |
Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis |
title_sort |
Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis |
dc.creator.none.fl_str_mv |
Springer, Valeria Haydee Di Anibal, Carolina Vanesa Lista, Adriana Guillermina |
author |
Springer, Valeria Haydee |
author_facet |
Springer, Valeria Haydee Di Anibal, Carolina Vanesa Lista, Adriana Guillermina |
author_role |
author |
author2 |
Di Anibal, Carolina Vanesa Lista, Adriana Guillermina |
author2_role |
author author |
dc.subject.none.fl_str_mv |
CAPILLARY ELECTROPHORESIS MULTIVARIATE OPTIMIZATION SULFONYLUREA HERBICIDES WATER SAMPLES |
topic |
CAPILLARY ELECTROPHORESIS MULTIVARIATE OPTIMIZATION SULFONYLUREA HERBICIDES WATER SAMPLES |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
A simple and rapid capillary electrophoretic method was developed for the simultaneous determination of two sulfonylurea herbicides in water samples: metsulfuron-methyl (MSM) and nicosulfuron (NS). These herbicides are widely used in agricultural practices and their residues represent potential environment pollutants in waters and soils. The effect of the pH of the background electrolyte solution (BGE), the percentage of methanol in the BGE and the separation voltage were studied on the resolution of MSM and NS. A 23 factorial design was used to identify the main factors which significantly influenced the separation of these compounds. Other parameters were evaluated by the univariate method. The experimental results show that using a BGE composed of 25 mmol·L−1 sodium borate and 3% (v/v) of methanol at pH 8.5 and applying 15 kV, satisfactory analysis time and resolution between peaks can be obtained. The linear range for both analytes was 0.1–2.0 µg·mL−1. The detection limits were 0.034 µg·mL−1 for MSM and 0.044 µg·mL−1 for NS. Surface water and groundwater samples were analyzed applying the new method, and the obtained results presented satisfactory recovery percentages (82%–102%). Fil: Springer, Valeria Haydee. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Di Anibal, Carolina Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Lista, Adriana Guillermina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina |
description |
A simple and rapid capillary electrophoretic method was developed for the simultaneous determination of two sulfonylurea herbicides in water samples: metsulfuron-methyl (MSM) and nicosulfuron (NS). These herbicides are widely used in agricultural practices and their residues represent potential environment pollutants in waters and soils. The effect of the pH of the background electrolyte solution (BGE), the percentage of methanol in the BGE and the separation voltage were studied on the resolution of MSM and NS. A 23 factorial design was used to identify the main factors which significantly influenced the separation of these compounds. Other parameters were evaluated by the univariate method. The experimental results show that using a BGE composed of 25 mmol·L−1 sodium borate and 3% (v/v) of methanol at pH 8.5 and applying 15 kV, satisfactory analysis time and resolution between peaks can be obtained. The linear range for both analytes was 0.1–2.0 µg·mL−1. The detection limits were 0.034 µg·mL−1 for MSM and 0.044 µg·mL−1 for NS. Surface water and groundwater samples were analyzed applying the new method, and the obtained results presented satisfactory recovery percentages (82%–102%). |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/62853 Springer, Valeria Haydee; Di Anibal, Carolina Vanesa; Lista, Adriana Guillermina; Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis; MDPI; Separations; 3; 22; 8-2016; 1-10 2297-8739 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/62853 |
identifier_str_mv |
Springer, Valeria Haydee; Di Anibal, Carolina Vanesa; Lista, Adriana Guillermina; Screening and evaluation of variables for determination of sulfonylurea herbicides in water samples by capillary zone electrophoresis; MDPI; Separations; 3; 22; 8-2016; 1-10 2297-8739 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2297-8739/3/3/22 info:eu-repo/semantics/altIdentifier/doi/10.3390/separations3030022 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
MDPI |
publisher.none.fl_str_mv |
MDPI |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613355497586688 |
score |
13.070432 |