Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational...

Autores: Jios, Jorge Luis; Romanelli, Gustavo Pablo; Autino, Juan Carlos; Giaccio, Hector E.; Duddeck, Helmut; Wiebcke, Michael
Año de publicación: 2005
Idioma: inglés
Tipo de recurso: artículo
Estado: versión publicada
Descripción: The complete and unambiguous assignment of the 1H NMR and 13C NMR spectra of 26 N-aralkylsulfonamides, N-sulfonyl-1,2,3,4-tetrahydroisoquinolines and N-sulfonylbenz[c]azepines was performed on the basis of APT, DEPT, homonuclear (gs-COSY) and 1H-detected heteronuclear one-bond (gs-HMQC) and long-range (gsHMBC) correlation experiments. The methylated 2,3,4,5- tetrahydro-1H-2-benzazepine derivative 26 adopts a chair conformation as determined by 1H- 1H coupling analysis and g-gauche effects. This is supported by a single-crystal X-ray structure analysis.
Fil: Jios, Jorge Luis. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Servicios a la Industria y al Sistema Científico; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Autino, Juan Carlos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Giaccio, Hector E.. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Fil: Duddeck, Helmut. Universitat Hannover. Institut fur Anorganische Chemie; Alemania
Fil: Wiebcke, Michael. Universitat Hannover. Institut fur Anorganische Chemie; Alemania
Materia: 1h Nmr
13c Nmr
N-Aralkylsulfonamides
N-Sulfonyl-1,2,3,4-Tetrahydroisoquinolines
N-Sulfonyl-2,3,4,5-Tetrahydro-1h-2-Benzazepines
Conformational Analysis
X-Ray Diffraction
Nivel de accesibilidad: acceso abierto
Condiciones de uso: https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
Institución: Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador: oai:ri.conicet.gov.ar:11336/55688

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repository_id_str	3498
network_name_str	CONICET Digital (CONICET)
spelling	Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepinJios, Jorge LuisRomanelli, Gustavo PabloAutino, Juan CarlosGiaccio, Hector E.Duddeck, HelmutWiebcke, Michael1h Nmr13c NmrN-AralkylsulfonamidesN-Sulfonyl-1,2,3,4-TetrahydroisoquinolinesN-Sulfonyl-2,3,4,5-Tetrahydro-1h-2-BenzazepinesConformational AnalysisX-Ray Diffractionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The complete and unambiguous assignment of the 1H NMR and 13C NMR spectra of 26 N-aralkylsulfonamides, N-sulfonyl-1,2,3,4-tetrahydroisoquinolines and N-sulfonylbenz[c]azepines was performed on the basis of APT, DEPT, homonuclear (gs-COSY) and 1H-detected heteronuclear one-bond (gs-HMQC) and long-range (gsHMBC) correlation experiments. The methylated 2,3,4,5- tetrahydro-1H-2-benzazepine derivative 26 adopts a chair conformation as determined by 1H- 1H coupling analysis and g-gauche effects. This is supported by a single-crystal X-ray structure analysis.Fil: Jios, Jorge Luis. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Servicios a la Industria y al Sistema Científico; ArgentinaFil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaFil: Autino, Juan Carlos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; ArgentinaFil: Giaccio, Hector E.. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; ArgentinaFil: Duddeck, Helmut. Universitat Hannover. Institut fur Anorganische Chemie; AlemaniaFil: Wiebcke, Michael. Universitat Hannover. Institut fur Anorganische Chemie; AlemaniaJohn Wiley & Sons Ltd2005-09-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/55688Jios, Jorge Luis; Romanelli, Gustavo Pablo; Autino, Juan Carlos; Giaccio, Hector E.; Duddeck, Helmut; et al.; Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin; John Wiley & Sons Ltd; Magnetic Resonance in Chemistry; 43; 12; 12-9-2005; 1057-10620749-1581CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/mrc.1657info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/mrc.1657info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:50:58Zoai:ri.conicet.gov.ar:11336/55688instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:50:59.038CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv	Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin
title	Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin
spellingShingle	Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin Jios, Jorge Luis 1h Nmr 13c Nmr N-Aralkylsulfonamides N-Sulfonyl-1,2,3,4-Tetrahydroisoquinolines N-Sulfonyl-2,3,4,5-Tetrahydro-1h-2-Benzazepines Conformational Analysis X-Ray Diffraction
title_short	Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin
title_full	Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin
title_fullStr	Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin
title_full_unstemmed	Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin
title_sort	Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin
dc.creator.none.fl_str_mv	Jios, Jorge Luis Romanelli, Gustavo Pablo Autino, Juan Carlos Giaccio, Hector E. Duddeck, Helmut Wiebcke, Michael
author	Jios, Jorge Luis
author_facet	Jios, Jorge Luis Romanelli, Gustavo Pablo Autino, Juan Carlos Giaccio, Hector E. Duddeck, Helmut Wiebcke, Michael
author_role	author
author2	Romanelli, Gustavo Pablo Autino, Juan Carlos Giaccio, Hector E. Duddeck, Helmut Wiebcke, Michael
author2_role	author author author author author
dc.subject.none.fl_str_mv	1h Nmr 13c Nmr N-Aralkylsulfonamides N-Sulfonyl-1,2,3,4-Tetrahydroisoquinolines N-Sulfonyl-2,3,4,5-Tetrahydro-1h-2-Benzazepines Conformational Analysis X-Ray Diffraction
topic	1h Nmr 13c Nmr N-Aralkylsulfonamides N-Sulfonyl-1,2,3,4-Tetrahydroisoquinolines N-Sulfonyl-2,3,4,5-Tetrahydro-1h-2-Benzazepines Conformational Analysis X-Ray Diffraction
purl_subject.fl_str_mv	https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv	The complete and unambiguous assignment of the 1H NMR and 13C NMR spectra of 26 N-aralkylsulfonamides, N-sulfonyl-1,2,3,4-tetrahydroisoquinolines and N-sulfonylbenz[c]azepines was performed on the basis of APT, DEPT, homonuclear (gs-COSY) and 1H-detected heteronuclear one-bond (gs-HMQC) and long-range (gsHMBC) correlation experiments. The methylated 2,3,4,5- tetrahydro-1H-2-benzazepine derivative 26 adopts a chair conformation as determined by 1H- 1H coupling analysis and g-gauche effects. This is supported by a single-crystal X-ray structure analysis. Fil: Jios, Jorge Luis. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Servicios a la Industria y al Sistema Científico; Argentina Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina Fil: Autino, Juan Carlos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina Fil: Giaccio, Hector E.. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina Fil: Duddeck, Helmut. Universitat Hannover. Institut fur Anorganische Chemie; Alemania Fil: Wiebcke, Michael. Universitat Hannover. Institut fur Anorganische Chemie; Alemania
description	The complete and unambiguous assignment of the 1H NMR and 13C NMR spectra of 26 N-aralkylsulfonamides, N-sulfonyl-1,2,3,4-tetrahydroisoquinolines and N-sulfonylbenz[c]azepines was performed on the basis of APT, DEPT, homonuclear (gs-COSY) and 1H-detected heteronuclear one-bond (gs-HMQC) and long-range (gsHMBC) correlation experiments. The methylated 2,3,4,5- tetrahydro-1H-2-benzazepine derivative 26 adopts a chair conformation as determined by 1H- 1H coupling analysis and g-gauche effects. This is supported by a single-crystal X-ray structure analysis.
publishDate	2005
dc.date.none.fl_str_mv	2005-09-12
dc.type.none.fl_str_mv	info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo
format	article
status_str	publishedVersion
dc.identifier.none.fl_str_mv	http://hdl.handle.net/11336/55688 Jios, Jorge Luis; Romanelli, Gustavo Pablo; Autino, Juan Carlos; Giaccio, Hector E.; Duddeck, Helmut; et al.; Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin; John Wiley & Sons Ltd; Magnetic Resonance in Chemistry; 43; 12; 12-9-2005; 1057-1062 0749-1581 CONICET Digital CONICET
url	http://hdl.handle.net/11336/55688
identifier_str_mv	Jios, Jorge Luis; Romanelli, Gustavo Pablo; Autino, Juan Carlos; Giaccio, Hector E.; Duddeck, Helmut; et al.; Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational analysis of N‐[((3′,4′‐dichlorophenyl)methyl)sulfonyl]‐3‐methyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepin; John Wiley & Sons Ltd; Magnetic Resonance in Chemistry; 43; 12; 12-9-2005; 1057-1062 0749-1581 CONICET Digital CONICET
dc.language.none.fl_str_mv	eng
language	eng
dc.relation.none.fl_str_mv	info:eu-repo/semantics/altIdentifier/doi/10.1002/mrc.1657 info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/mrc.1657
dc.rights.none.fl_str_mv	info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv	openAccess
rights_invalid_str_mv	https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv	application/pdf application/pdf
dc.publisher.none.fl_str_mv	John Wiley & Sons Ltd
publisher.none.fl_str_mv	John Wiley & Sons Ltd
dc.source.none.fl_str_mv	reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str	CONICET Digital (CONICET)
collection	CONICET Digital (CONICET)
instname_str	Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv	CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv	dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score	13.22299

Complete 1H and 13C NMR spectral assignment of N‐aralkylsulfonamides, N‐sulfonyl‐1,2,3,4‐tetrahydroisoquinolines and N‐sulfonyl‐2,3,4,5‐tetrahydro‐1H‐2‐benzazepines. Conformational...

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