Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4...
- Autores
- Setevich, C; Toscani, Lucía María; Larrondo, Susana Adelina; Prado, F.; Caneiro, A
- Año de publicación
- 2017
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The replacement of Co by Nb in the La1 − xBaxCo1 − yNbyO3 − δ (0.6 ≤ x ≤ 1.0) system and its effects on phase stability and high temperature properties of the cubic perovskite phase were investigated by X-ray diffraction, dilatometry, electrical conductivity, oxygen permeation and electrochemical impedance spectroscopy. The incorporation of Nb in the B site stabilizes the cubic perovskite in the as prepared samples. The Nb solubility increases from y = 0.1, for the sample with Ba content x = 0.6, to y = 0.4 for 0.8 ≤ x ≤ 1.0. However, after a heat treatment at 750 °C during 10 days small amounts of secondary phases were detected for samples with x = 0.9 and 1.0. The linear expansion of the cubic phases decreases with the Nb content as well as with the Ba content. The minimum value, α = 12.9 × 10− 6 K− 1, was obtained for La0.2Ba0.8Co0.6Nb0.4O3 − δ. The behavior of electrical conductivity and oxygen permeation data with Nb content is explained from variations in the oxygen vacancy concentration, which is controlled by Nb5 + and Ba2 + contents. The minimum polarization resistance value, Rp = 0.08 Ω cm2, was obtained at 600 °C for La0.2Ba0.8Co0.9Nb0.1O3 − δ. The low Rp value of this compound and the crystal structure stability of various compositions in the system La1 − xBaxCo1 − yNbyO3 − δ with x ≥ 0.7 and y ≥ 0.1 make these materials of interest as mixed conductors.
Fil: Setevich, C. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Física; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Toscani, Lucía María. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina
Fil: Larrondo, Susana Adelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Nacional de San Martín; Argentina
Fil: Prado, F.. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Física; Argentina
Fil: Caneiro, A. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina - Materia
-
Cobaltites
Crystal Structure Stability
Nb-Doping
Oxide Mixed Conductors
Perovskites
Thermal Expansion, Impedance Spectroscopy - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/44191
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Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4Setevich, CToscani, Lucía MaríaLarrondo, Susana AdelinaPrado, F.Caneiro, ACobaltitesCrystal Structure StabilityNb-DopingOxide Mixed ConductorsPerovskitesThermal Expansion, Impedance Spectroscopyhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The replacement of Co by Nb in the La1 − xBaxCo1 − yNbyO3 − δ (0.6 ≤ x ≤ 1.0) system and its effects on phase stability and high temperature properties of the cubic perovskite phase were investigated by X-ray diffraction, dilatometry, electrical conductivity, oxygen permeation and electrochemical impedance spectroscopy. The incorporation of Nb in the B site stabilizes the cubic perovskite in the as prepared samples. The Nb solubility increases from y = 0.1, for the sample with Ba content x = 0.6, to y = 0.4 for 0.8 ≤ x ≤ 1.0. However, after a heat treatment at 750 °C during 10 days small amounts of secondary phases were detected for samples with x = 0.9 and 1.0. The linear expansion of the cubic phases decreases with the Nb content as well as with the Ba content. The minimum value, α = 12.9 × 10− 6 K− 1, was obtained for La0.2Ba0.8Co0.6Nb0.4O3 − δ. The behavior of electrical conductivity and oxygen permeation data with Nb content is explained from variations in the oxygen vacancy concentration, which is controlled by Nb5 + and Ba2 + contents. The minimum polarization resistance value, Rp = 0.08 Ω cm2, was obtained at 600 °C for La0.2Ba0.8Co0.9Nb0.1O3 − δ. The low Rp value of this compound and the crystal structure stability of various compositions in the system La1 − xBaxCo1 − yNbyO3 − δ with x ≥ 0.7 and y ≥ 0.1 make these materials of interest as mixed conductors.Fil: Setevich, C. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Física; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Toscani, Lucía María. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; ArgentinaFil: Larrondo, Susana Adelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Nacional de San Martín; ArgentinaFil: Prado, F.. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Física; ArgentinaFil: Caneiro, A. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaElsevier Science2017-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44191Setevich, C; Toscani, Lucía María; Larrondo, Susana Adelina; Prado, F.; Caneiro, A; Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4; Elsevier Science; Solid State Ionics; 300; 2-2017; 140-1480167-2738CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ssi.2016.12.016info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0167273816306919info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:17Zoai:ri.conicet.gov.ar:11336/44191instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:17.343CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4 |
title |
Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4 |
spellingShingle |
Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4 Setevich, C Cobaltites Crystal Structure Stability Nb-Doping Oxide Mixed Conductors Perovskites Thermal Expansion, Impedance Spectroscopy |
title_short |
Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4 |
title_full |
Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4 |
title_fullStr |
Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4 |
title_full_unstemmed |
Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4 |
title_sort |
Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4 |
dc.creator.none.fl_str_mv |
Setevich, C Toscani, Lucía María Larrondo, Susana Adelina Prado, F. Caneiro, A |
author |
Setevich, C |
author_facet |
Setevich, C Toscani, Lucía María Larrondo, Susana Adelina Prado, F. Caneiro, A |
author_role |
author |
author2 |
Toscani, Lucía María Larrondo, Susana Adelina Prado, F. Caneiro, A |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Cobaltites Crystal Structure Stability Nb-Doping Oxide Mixed Conductors Perovskites Thermal Expansion, Impedance Spectroscopy |
topic |
Cobaltites Crystal Structure Stability Nb-Doping Oxide Mixed Conductors Perovskites Thermal Expansion, Impedance Spectroscopy |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The replacement of Co by Nb in the La1 − xBaxCo1 − yNbyO3 − δ (0.6 ≤ x ≤ 1.0) system and its effects on phase stability and high temperature properties of the cubic perovskite phase were investigated by X-ray diffraction, dilatometry, electrical conductivity, oxygen permeation and electrochemical impedance spectroscopy. The incorporation of Nb in the B site stabilizes the cubic perovskite in the as prepared samples. The Nb solubility increases from y = 0.1, for the sample with Ba content x = 0.6, to y = 0.4 for 0.8 ≤ x ≤ 1.0. However, after a heat treatment at 750 °C during 10 days small amounts of secondary phases were detected for samples with x = 0.9 and 1.0. The linear expansion of the cubic phases decreases with the Nb content as well as with the Ba content. The minimum value, α = 12.9 × 10− 6 K− 1, was obtained for La0.2Ba0.8Co0.6Nb0.4O3 − δ. The behavior of electrical conductivity and oxygen permeation data with Nb content is explained from variations in the oxygen vacancy concentration, which is controlled by Nb5 + and Ba2 + contents. The minimum polarization resistance value, Rp = 0.08 Ω cm2, was obtained at 600 °C for La0.2Ba0.8Co0.9Nb0.1O3 − δ. The low Rp value of this compound and the crystal structure stability of various compositions in the system La1 − xBaxCo1 − yNbyO3 − δ with x ≥ 0.7 and y ≥ 0.1 make these materials of interest as mixed conductors. Fil: Setevich, C. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Física; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina Fil: Toscani, Lucía María. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina Fil: Larrondo, Susana Adelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Nacional de San Martín; Argentina Fil: Prado, F.. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur. Departamento de Física; Argentina Fil: Caneiro, A. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina |
description |
The replacement of Co by Nb in the La1 − xBaxCo1 − yNbyO3 − δ (0.6 ≤ x ≤ 1.0) system and its effects on phase stability and high temperature properties of the cubic perovskite phase were investigated by X-ray diffraction, dilatometry, electrical conductivity, oxygen permeation and electrochemical impedance spectroscopy. The incorporation of Nb in the B site stabilizes the cubic perovskite in the as prepared samples. The Nb solubility increases from y = 0.1, for the sample with Ba content x = 0.6, to y = 0.4 for 0.8 ≤ x ≤ 1.0. However, after a heat treatment at 750 °C during 10 days small amounts of secondary phases were detected for samples with x = 0.9 and 1.0. The linear expansion of the cubic phases decreases with the Nb content as well as with the Ba content. The minimum value, α = 12.9 × 10− 6 K− 1, was obtained for La0.2Ba0.8Co0.6Nb0.4O3 − δ. The behavior of electrical conductivity and oxygen permeation data with Nb content is explained from variations in the oxygen vacancy concentration, which is controlled by Nb5 + and Ba2 + contents. The minimum polarization resistance value, Rp = 0.08 Ω cm2, was obtained at 600 °C for La0.2Ba0.8Co0.9Nb0.1O3 − δ. The low Rp value of this compound and the crystal structure stability of various compositions in the system La1 − xBaxCo1 − yNbyO3 − δ with x ≥ 0.7 and y ≥ 0.1 make these materials of interest as mixed conductors. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/44191 Setevich, C; Toscani, Lucía María; Larrondo, Susana Adelina; Prado, F.; Caneiro, A; Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4; Elsevier Science; Solid State Ionics; 300; 2-2017; 140-148 0167-2738 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/44191 |
identifier_str_mv |
Setevich, C; Toscani, Lucía María; Larrondo, Susana Adelina; Prado, F.; Caneiro, A; Effect of Nb5 + content on the high temperature properties of the mixed conductors system La1 − xBaxCo1 − yNbyO3 − δ with 0.6 ≤ x ≤ 1.0 and 0 ≤ y ≤ 0.4; Elsevier Science; Solid State Ionics; 300; 2-2017; 140-148 0167-2738 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ssi.2016.12.016 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0167273816306919 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613209970966528 |
score |
13.070432 |