Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95

Autores
Setevich, Cristian F.; Mogni, Liliana Verónica; Caneiro, Alberto; Prado, Fernando Daniel
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Three different cathode configurations using porous layers of La0.4Ba0.6CoO3-d (LBC), LBCGDC composite in a 1:1 weight ratio, and GDC were prepared and tested by impedance spectroscopy measurements on symmetrical cells. The sequence of layers for the three cathode configurations is: A)porous GDC + LBC, B) porous GDC + LBCGDC composite, C) porous GDC + LBCGDC composite + LBC. The minimum polarization resistance (Rp) value was obtained with configuration C. The incorporation of both the porous GDC layer and the intermediate layer of LBC-GDC composite, allowed us to solve adherence problems caused by the total expansion mismatch between LBC (26 10-6 K-1) and GDC (12 10-6 K-1). The Rp values obtained with cell C are comparable to the performance of another cell C prepared with Ba0.5Sr0.5Co0.8Fe0.2O3-d (BSCF). For example, the Rp values at 600 ºC, in air, were 0.071 and 0.065 Ωcm2 for LBC and BSCF, respectively. These results suggest that configuration C is very promising for developing IT-SOFC cathode with low Rp values.
Fil: Setevich, Cristian F.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Fil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Caneiro, Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Materia
Perovskitas de Cobalto
Conductores Mixtos
Cátodos Sofc
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/66287
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/66287
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95Setevich, Cristian F.Mogni, Liliana VerónicaCaneiro, AlbertoPrado, Fernando DanielPerovskitas de CobaltoConductores MixtosCátodos Sofchttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Three different cathode configurations using porous layers of La0.4Ba0.6CoO3-d (LBC), LBCGDC composite in a 1:1 weight ratio, and GDC were prepared and tested by impedance spectroscopy measurements on symmetrical cells. The sequence of layers for the three cathode configurations is: A)porous GDC + LBC, B) porous GDC + LBCGDC composite, C) porous GDC + LBCGDC composite + LBC. The minimum polarization resistance (Rp) value was obtained with configuration C. The incorporation of both the porous GDC layer and the intermediate layer of LBC-GDC composite, allowed us to solve adherence problems caused by the total expansion mismatch between LBC (26 10-6 K-1) and GDC (12 10-6 K-1). The Rp values obtained with cell C are comparable to the performance of another cell C prepared with Ba0.5Sr0.5Co0.8Fe0.2O3-d (BSCF). For example, the Rp values at 600 ºC, in air, were 0.071 and 0.065 Ωcm2 for LBC and BSCF, respectively. These results suggest that configuration C is very promising for developing IT-SOFC cathode with low Rp values.Fil: Setevich, Cristian F.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaFil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Caneiro, Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaPergamon-Elsevier Science Ltd2012-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66287Setevich, Cristian F.; Mogni, Liliana Verónica; Caneiro, Alberto; Prado, Fernando Daniel; Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 37; 19; 10-2012; 14895-149010360-3199CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0360319912002960info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2012.01.155info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:37:55Zoai:ri.conicet.gov.ar:11336/66287instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:37:56.101CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95
title Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95
spellingShingle Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95
Setevich, Cristian F.
Perovskitas de Cobalto
Conductores Mixtos
Cátodos Sofc
title_short Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95
title_full Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95
title_fullStr Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95
title_full_unstemmed Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95
title_sort Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95
dc.creator.none.fl_str_mv Setevich, Cristian F.
Mogni, Liliana Verónica
Caneiro, Alberto
Prado, Fernando Daniel
author Setevich, Cristian F.
author_facet Setevich, Cristian F.
Mogni, Liliana Verónica
Caneiro, Alberto
Prado, Fernando Daniel
author_role author
author2 Mogni, Liliana Verónica
Caneiro, Alberto
Prado, Fernando Daniel
author2_role author
author
author
dc.subject.none.fl_str_mv Perovskitas de Cobalto
Conductores Mixtos
Cátodos Sofc
topic Perovskitas de Cobalto
Conductores Mixtos
Cátodos Sofc
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Three different cathode configurations using porous layers of La0.4Ba0.6CoO3-d (LBC), LBCGDC composite in a 1:1 weight ratio, and GDC were prepared and tested by impedance spectroscopy measurements on symmetrical cells. The sequence of layers for the three cathode configurations is: A)porous GDC + LBC, B) porous GDC + LBCGDC composite, C) porous GDC + LBCGDC composite + LBC. The minimum polarization resistance (Rp) value was obtained with configuration C. The incorporation of both the porous GDC layer and the intermediate layer of LBC-GDC composite, allowed us to solve adherence problems caused by the total expansion mismatch between LBC (26 10-6 K-1) and GDC (12 10-6 K-1). The Rp values obtained with cell C are comparable to the performance of another cell C prepared with Ba0.5Sr0.5Co0.8Fe0.2O3-d (BSCF). For example, the Rp values at 600 ºC, in air, were 0.071 and 0.065 Ωcm2 for LBC and BSCF, respectively. These results suggest that configuration C is very promising for developing IT-SOFC cathode with low Rp values.
Fil: Setevich, Cristian F.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Fil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Caneiro, Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
description Three different cathode configurations using porous layers of La0.4Ba0.6CoO3-d (LBC), LBCGDC composite in a 1:1 weight ratio, and GDC were prepared and tested by impedance spectroscopy measurements on symmetrical cells. The sequence of layers for the three cathode configurations is: A)porous GDC + LBC, B) porous GDC + LBCGDC composite, C) porous GDC + LBCGDC composite + LBC. The minimum polarization resistance (Rp) value was obtained with configuration C. The incorporation of both the porous GDC layer and the intermediate layer of LBC-GDC composite, allowed us to solve adherence problems caused by the total expansion mismatch between LBC (26 10-6 K-1) and GDC (12 10-6 K-1). The Rp values obtained with cell C are comparable to the performance of another cell C prepared with Ba0.5Sr0.5Co0.8Fe0.2O3-d (BSCF). For example, the Rp values at 600 ºC, in air, were 0.071 and 0.065 Ωcm2 for LBC and BSCF, respectively. These results suggest that configuration C is very promising for developing IT-SOFC cathode with low Rp values.
publishDate 2012
dc.date.none.fl_str_mv 2012-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/66287
Setevich, Cristian F.; Mogni, Liliana Verónica; Caneiro, Alberto; Prado, Fernando Daniel; Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 37; 19; 10-2012; 14895-14901
0360-3199
CONICET Digital
CONICET
url http://hdl.handle.net/11336/66287
identifier_str_mv Setevich, Cristian F.; Mogni, Liliana Verónica; Caneiro, Alberto; Prado, Fernando Daniel; Optimum cathode configuration for IT-SOFC using La0.4Ba0.6CoO3−δ and Ce0.9Gd0.1O1.95; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 37; 19; 10-2012; 14895-14901
0360-3199
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0360319912002960
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2012.01.155
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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