Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study

Autores
Troncoso, Loreto; Mariño, Carlos; Arce, Mauricio Damián; Alonso, José Antonio
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compounds exhibit a K2NiF4-type layered perovskite structure; they are based on the La1.2Sr0.8InO4+δ oxide, which was found to exhibit excellent features as fast oxide-ion conductor via an interstitial oxygen mechanism. These new Ba-containing materials were designed to present a more open framework to enhance oxygen conduction. The citrate-nitrate soft-chemistry technique was used to synthesize such structural perovskite-type materials, followed by annealing in air at moderate temperatures (1150 °C). The subtleties of their crystal structures were investigated from neutron powder diffraction (NPD) data. They crystallize in the orthorhombic Pbca space group. Interstitial O3 oxygen atoms were identified by difference Fourier maps in the NaCl layer of the K2NiF4 structure. At variance with the parent compound, conspicuous oxygen vacancies were found at the O2-type oxygen atoms for x = 0.2, corresponding to the axial positions of the InO6 octahedra. The short O2-O3 distances and the absence of steric impediments suggest a dual oxygen-interstitial mechanism for oxide-ion conduction in these materials. Conductivity measurements show that the activation energy values are comparable to those typical of ionic conductors working by simple vacancy mechanisms (~1 eV). The increment of the total conductivity for x = 0.2 can be due to the mixed mechanism driving both oxygen vacancies and interstitials, which is original for these potential electrolytes for solid-oxide fuel cells.
Fil: Troncoso, Loreto. Consejo Superior de Investigaciones Científicas; España. Universidad Austral de Chile; Chile
Fil: Mariño, Carlos. Universidad Austral de Chile; Chile. Universidad de Santiago de Chile; Chile
Fil: Arce, Mauricio Damián. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina
Fil: Alonso, José Antonio. Consejo Superior de Investigaciones Científicas; España
Materia
ACTIVATION ENERGY
LAYERED PEROVSKITE
NEUTRON POWDER DIFFRACTION
OXYGEN INTERSTITIALS
OXYGEN VACANCIES
OXYGEN-ION CONDUCTOR
SOLID ELECTROLYTE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/123267
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/123267
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction studyTroncoso, LoretoMariño, CarlosArce, Mauricio DamiánAlonso, José AntonioACTIVATION ENERGYLAYERED PEROVSKITENEUTRON POWDER DIFFRACTIONOXYGEN INTERSTITIALSOXYGEN VACANCIESOXYGEN-ION CONDUCTORSOLID ELECTROLYTEhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The title compounds exhibit a K2NiF4-type layered perovskite structure; they are based on the La1.2Sr0.8InO4+δ oxide, which was found to exhibit excellent features as fast oxide-ion conductor via an interstitial oxygen mechanism. These new Ba-containing materials were designed to present a more open framework to enhance oxygen conduction. The citrate-nitrate soft-chemistry technique was used to synthesize such structural perovskite-type materials, followed by annealing in air at moderate temperatures (1150 °C). The subtleties of their crystal structures were investigated from neutron powder diffraction (NPD) data. They crystallize in the orthorhombic Pbca space group. Interstitial O3 oxygen atoms were identified by difference Fourier maps in the NaCl layer of the K2NiF4 structure. At variance with the parent compound, conspicuous oxygen vacancies were found at the O2-type oxygen atoms for x = 0.2, corresponding to the axial positions of the InO6 octahedra. The short O2-O3 distances and the absence of steric impediments suggest a dual oxygen-interstitial mechanism for oxide-ion conduction in these materials. Conductivity measurements show that the activation energy values are comparable to those typical of ionic conductors working by simple vacancy mechanisms (~1 eV). The increment of the total conductivity for x = 0.2 can be due to the mixed mechanism driving both oxygen vacancies and interstitials, which is original for these potential electrolytes for solid-oxide fuel cells.Fil: Troncoso, Loreto. Consejo Superior de Investigaciones Científicas; España. Universidad Austral de Chile; ChileFil: Mariño, Carlos. Universidad Austral de Chile; Chile. Universidad de Santiago de Chile; ChileFil: Arce, Mauricio Damián. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; ArgentinaFil: Alonso, José Antonio. Consejo Superior de Investigaciones Científicas; EspañaMolecular Diversity Preservation International2019-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/123267Troncoso, Loreto; Mariño, Carlos; Arce, Mauricio Damián; Alonso, José Antonio; Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study; Molecular Diversity Preservation International; Materials; 12; 10; 5-2019; 1-101996-1944CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.3390/ma12101624info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:53:00Zoai:ri.conicet.gov.ar:11336/123267instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:53:00.98CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study
title Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study
spellingShingle Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study
Troncoso, Loreto
ACTIVATION ENERGY
LAYERED PEROVSKITE
NEUTRON POWDER DIFFRACTION
OXYGEN INTERSTITIALS
OXYGEN VACANCIES
OXYGEN-ION CONDUCTOR
SOLID ELECTROLYTE
title_short Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study
title_full Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study
title_fullStr Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study
title_full_unstemmed Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study
title_sort Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study
dc.creator.none.fl_str_mv Troncoso, Loreto
Mariño, Carlos
Arce, Mauricio Damián
Alonso, José Antonio
author Troncoso, Loreto
author_facet Troncoso, Loreto
Mariño, Carlos
Arce, Mauricio Damián
Alonso, José Antonio
author_role author
author2 Mariño, Carlos
Arce, Mauricio Damián
Alonso, José Antonio
author2_role author
author
author
dc.subject.none.fl_str_mv ACTIVATION ENERGY
LAYERED PEROVSKITE
NEUTRON POWDER DIFFRACTION
OXYGEN INTERSTITIALS
OXYGEN VACANCIES
OXYGEN-ION CONDUCTOR
SOLID ELECTROLYTE
topic ACTIVATION ENERGY
LAYERED PEROVSKITE
NEUTRON POWDER DIFFRACTION
OXYGEN INTERSTITIALS
OXYGEN VACANCIES
OXYGEN-ION CONDUCTOR
SOLID ELECTROLYTE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The title compounds exhibit a K2NiF4-type layered perovskite structure; they are based on the La1.2Sr0.8InO4+δ oxide, which was found to exhibit excellent features as fast oxide-ion conductor via an interstitial oxygen mechanism. These new Ba-containing materials were designed to present a more open framework to enhance oxygen conduction. The citrate-nitrate soft-chemistry technique was used to synthesize such structural perovskite-type materials, followed by annealing in air at moderate temperatures (1150 °C). The subtleties of their crystal structures were investigated from neutron powder diffraction (NPD) data. They crystallize in the orthorhombic Pbca space group. Interstitial O3 oxygen atoms were identified by difference Fourier maps in the NaCl layer of the K2NiF4 structure. At variance with the parent compound, conspicuous oxygen vacancies were found at the O2-type oxygen atoms for x = 0.2, corresponding to the axial positions of the InO6 octahedra. The short O2-O3 distances and the absence of steric impediments suggest a dual oxygen-interstitial mechanism for oxide-ion conduction in these materials. Conductivity measurements show that the activation energy values are comparable to those typical of ionic conductors working by simple vacancy mechanisms (~1 eV). The increment of the total conductivity for x = 0.2 can be due to the mixed mechanism driving both oxygen vacancies and interstitials, which is original for these potential electrolytes for solid-oxide fuel cells.
Fil: Troncoso, Loreto. Consejo Superior de Investigaciones Científicas; España. Universidad Austral de Chile; Chile
Fil: Mariño, Carlos. Universidad Austral de Chile; Chile. Universidad de Santiago de Chile; Chile
Fil: Arce, Mauricio Damián. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología; Argentina
Fil: Alonso, José Antonio. Consejo Superior de Investigaciones Científicas; España
description The title compounds exhibit a K2NiF4-type layered perovskite structure; they are based on the La1.2Sr0.8InO4+δ oxide, which was found to exhibit excellent features as fast oxide-ion conductor via an interstitial oxygen mechanism. These new Ba-containing materials were designed to present a more open framework to enhance oxygen conduction. The citrate-nitrate soft-chemistry technique was used to synthesize such structural perovskite-type materials, followed by annealing in air at moderate temperatures (1150 °C). The subtleties of their crystal structures were investigated from neutron powder diffraction (NPD) data. They crystallize in the orthorhombic Pbca space group. Interstitial O3 oxygen atoms were identified by difference Fourier maps in the NaCl layer of the K2NiF4 structure. At variance with the parent compound, conspicuous oxygen vacancies were found at the O2-type oxygen atoms for x = 0.2, corresponding to the axial positions of the InO6 octahedra. The short O2-O3 distances and the absence of steric impediments suggest a dual oxygen-interstitial mechanism for oxide-ion conduction in these materials. Conductivity measurements show that the activation energy values are comparable to those typical of ionic conductors working by simple vacancy mechanisms (~1 eV). The increment of the total conductivity for x = 0.2 can be due to the mixed mechanism driving both oxygen vacancies and interstitials, which is original for these potential electrolytes for solid-oxide fuel cells.
publishDate 2019
dc.date.none.fl_str_mv 2019-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/123267
Troncoso, Loreto; Mariño, Carlos; Arce, Mauricio Damián; Alonso, José Antonio; Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study; Molecular Diversity Preservation International; Materials; 12; 10; 5-2019; 1-10
1996-1944
CONICET Digital
CONICET
url http://hdl.handle.net/11336/123267
identifier_str_mv Troncoso, Loreto; Mariño, Carlos; Arce, Mauricio Damián; Alonso, José Antonio; Dual oxygen defects in layered La1.2Sr0.8-xBaxInO4+δ (x = 0.2, 0.3) oxide-Ion conductors: A neutron diffraction study; Molecular Diversity Preservation International; Materials; 12; 10; 5-2019; 1-10
1996-1944
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.3390/ma12101624
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Molecular Diversity Preservation International
publisher.none.fl_str_mv Molecular Diversity Preservation International
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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