Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study

Autores
Mafra, Daniela L.; Olmos Asar, Jimena Anahí; Negreiros, Fabio R.; Reina, Alfonso; Kim, Ki Kang; Dresselhaus, Mildred S.; Kong, Jing; Mankey, Gary J.; Araujo, Paulo T.
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The growth of large area single-layer graphene (1-LG) is studied using ambient pressure chemical vapor deposition on single-crystal Ni(111), Ni(110), and Ni(100). By varying both the furnace temperature in the range of 800-1100 °C and the gas flow through the growth chamber, uniform, high-quality 1-LG is obtained for Ni(111) and Ni(110) single crystals and for Ni(100) thin films. Surprisingly, only multilayer graphene growth could be obtained for single-crystal Ni(100). The experimental results are analyzed to determine the optimum combination of temperature and gas flow. Characterization with optical microscopy, Raman spectroscopy, and optical transmission support our findings. Density-functional theory calculations are performed to determine the energy barriers for diffusion, segregation, and adsorption, and model the kinetic pathways for formation of different carbon structures on the low-index surfaces of Ni.
Fil: Mafra, Daniela L.. Massachusetts Institute of Technology; Estados Unidos
Fil: Olmos Asar, Jimena Anahí. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Negreiros, Fabio R.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Reina, Alfonso. Massachusetts Institute of Technology; Estados Unidos
Fil: Kim, Ki Kang. Dongguk University-seoul; Corea del Sur
Fil: Dresselhaus, Mildred S.. Massachusetts Institute of Technology; Estados Unidos
Fil: Kong, Jing. Massachusetts Institute of Technology; Estados Unidos
Fil: Mankey, Gary J.. The University Of Alabama; Estados Unidos
Fil: Araujo, Paulo T.. University of Alabama at Birmingahm; Estados Unidos
Materia
Nickel
Graphene
Ambient-pressure CVD
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/86914
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles studyMafra, Daniela L.Olmos Asar, Jimena AnahíNegreiros, Fabio R.Reina, AlfonsoKim, Ki KangDresselhaus, Mildred S.Kong, JingMankey, Gary J.Araujo, Paulo T.NickelGrapheneAmbient-pressure CVDhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The growth of large area single-layer graphene (1-LG) is studied using ambient pressure chemical vapor deposition on single-crystal Ni(111), Ni(110), and Ni(100). By varying both the furnace temperature in the range of 800-1100 °C and the gas flow through the growth chamber, uniform, high-quality 1-LG is obtained for Ni(111) and Ni(110) single crystals and for Ni(100) thin films. Surprisingly, only multilayer graphene growth could be obtained for single-crystal Ni(100). The experimental results are analyzed to determine the optimum combination of temperature and gas flow. Characterization with optical microscopy, Raman spectroscopy, and optical transmission support our findings. Density-functional theory calculations are performed to determine the energy barriers for diffusion, segregation, and adsorption, and model the kinetic pathways for formation of different carbon structures on the low-index surfaces of Ni.Fil: Mafra, Daniela L.. Massachusetts Institute of Technology; Estados UnidosFil: Olmos Asar, Jimena Anahí. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Negreiros, Fabio R.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Reina, Alfonso. Massachusetts Institute of Technology; Estados UnidosFil: Kim, Ki Kang. Dongguk University-seoul; Corea del SurFil: Dresselhaus, Mildred S.. Massachusetts Institute of Technology; Estados UnidosFil: Kong, Jing. Massachusetts Institute of Technology; Estados UnidosFil: Mankey, Gary J.. The University Of Alabama; Estados UnidosFil: Araujo, Paulo T.. University of Alabama at Birmingahm; Estados UnidosAmerican Physical Society2018-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/86914Mafra, Daniela L.; Olmos Asar, Jimena Anahí; Negreiros, Fabio R.; Reina, Alfonso; Kim, Ki Kang; et al.; Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study; American Physical Society; Physical Review Materials; 2; 7; 7-20182475-9953CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1103/PhysRevMaterials.2.073404info:eu-repo/semantics/altIdentifier/url/https://journals.aps.org/prmaterials/abstract/10.1103/PhysRevMaterials.2.073404info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:06:12Zoai:ri.conicet.gov.ar:11336/86914instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:06:12.809CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study
title Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study
spellingShingle Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study
Mafra, Daniela L.
Nickel
Graphene
Ambient-pressure CVD
title_short Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study
title_full Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study
title_fullStr Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study
title_full_unstemmed Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study
title_sort Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study
dc.creator.none.fl_str_mv Mafra, Daniela L.
Olmos Asar, Jimena Anahí
Negreiros, Fabio R.
Reina, Alfonso
Kim, Ki Kang
Dresselhaus, Mildred S.
Kong, Jing
Mankey, Gary J.
Araujo, Paulo T.
author Mafra, Daniela L.
author_facet Mafra, Daniela L.
Olmos Asar, Jimena Anahí
Negreiros, Fabio R.
Reina, Alfonso
Kim, Ki Kang
Dresselhaus, Mildred S.
Kong, Jing
Mankey, Gary J.
Araujo, Paulo T.
author_role author
author2 Olmos Asar, Jimena Anahí
Negreiros, Fabio R.
Reina, Alfonso
Kim, Ki Kang
Dresselhaus, Mildred S.
Kong, Jing
Mankey, Gary J.
Araujo, Paulo T.
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Nickel
Graphene
Ambient-pressure CVD
topic Nickel
Graphene
Ambient-pressure CVD
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The growth of large area single-layer graphene (1-LG) is studied using ambient pressure chemical vapor deposition on single-crystal Ni(111), Ni(110), and Ni(100). By varying both the furnace temperature in the range of 800-1100 °C and the gas flow through the growth chamber, uniform, high-quality 1-LG is obtained for Ni(111) and Ni(110) single crystals and for Ni(100) thin films. Surprisingly, only multilayer graphene growth could be obtained for single-crystal Ni(100). The experimental results are analyzed to determine the optimum combination of temperature and gas flow. Characterization with optical microscopy, Raman spectroscopy, and optical transmission support our findings. Density-functional theory calculations are performed to determine the energy barriers for diffusion, segregation, and adsorption, and model the kinetic pathways for formation of different carbon structures on the low-index surfaces of Ni.
Fil: Mafra, Daniela L.. Massachusetts Institute of Technology; Estados Unidos
Fil: Olmos Asar, Jimena Anahí. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Negreiros, Fabio R.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Reina, Alfonso. Massachusetts Institute of Technology; Estados Unidos
Fil: Kim, Ki Kang. Dongguk University-seoul; Corea del Sur
Fil: Dresselhaus, Mildred S.. Massachusetts Institute of Technology; Estados Unidos
Fil: Kong, Jing. Massachusetts Institute of Technology; Estados Unidos
Fil: Mankey, Gary J.. The University Of Alabama; Estados Unidos
Fil: Araujo, Paulo T.. University of Alabama at Birmingahm; Estados Unidos
description The growth of large area single-layer graphene (1-LG) is studied using ambient pressure chemical vapor deposition on single-crystal Ni(111), Ni(110), and Ni(100). By varying both the furnace temperature in the range of 800-1100 °C and the gas flow through the growth chamber, uniform, high-quality 1-LG is obtained for Ni(111) and Ni(110) single crystals and for Ni(100) thin films. Surprisingly, only multilayer graphene growth could be obtained for single-crystal Ni(100). The experimental results are analyzed to determine the optimum combination of temperature and gas flow. Characterization with optical microscopy, Raman spectroscopy, and optical transmission support our findings. Density-functional theory calculations are performed to determine the energy barriers for diffusion, segregation, and adsorption, and model the kinetic pathways for formation of different carbon structures on the low-index surfaces of Ni.
publishDate 2018
dc.date.none.fl_str_mv 2018-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/86914
Mafra, Daniela L.; Olmos Asar, Jimena Anahí; Negreiros, Fabio R.; Reina, Alfonso; Kim, Ki Kang; et al.; Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study; American Physical Society; Physical Review Materials; 2; 7; 7-2018
2475-9953
CONICET Digital
CONICET
url http://hdl.handle.net/11336/86914
identifier_str_mv Mafra, Daniela L.; Olmos Asar, Jimena Anahí; Negreiros, Fabio R.; Reina, Alfonso; Kim, Ki Kang; et al.; Ambient-pressure CVD of graphene on low-index Ni surfaces using methane: A combined experimental and first-principles study; American Physical Society; Physical Review Materials; 2; 7; 7-2018
2475-9953
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1103/PhysRevMaterials.2.073404
info:eu-repo/semantics/altIdentifier/url/https://journals.aps.org/prmaterials/abstract/10.1103/PhysRevMaterials.2.073404
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Physical Society
publisher.none.fl_str_mv American Physical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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