A stable, novel catalyst improves hydrogen production in a membrane reactor

Autores
Irusta, S.; Múnera Agudelo, John Fernando; Carrara, Carlos Roberto; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The dry reforming of methane as a source of H2 was performed using a well-known catalyst, Rh/La2O3, together with a novel one, Rh/La2O3-SiO2, in a hydrogen-permeable membrane reactor. The catalysts were characterized by XRD, TPR, FTIR, H2 and CO chemisorption. In all lanthanum-based catalysts, the activity remained constant after 100 h on stream at 823 K. The basis of their high stability could be traced back to the strong metal-support interaction (TPR) in Rh/La2O3 catalysts. The La 2O3-SiO2 solids are also stable even though a weaker rhodium-lanthanum interaction (TPR) can be observed. The incorporation of the promoter (La2O3) to the silica support induces a parallel increase in the metal dispersion (CO adsorption). The effect of the operation variables upon the performance of the membrane reactor was also studied. The novel Rh (0.6%)/La2O3 (27%)-SiO2 catalyst proved to be the best formulation. Operating the membrane reactor at 823 K, both methane and CO2 conversions were 40% higher than the equilibrium values, producing 0.5 mol H2/mol CH4. This catalyst, tested at W/F three times lower than Rh (0.6%)/La2O 3, showed a similar performance. Both the increase of the sweep gas flow rate and the decrease of the permeation area significantly affected methane conversion and H2 production. The presence of tiny amounts of graphite only detectable through LRS did not endanger membrane stability. The better performance of Rh (0.6%)/La2O3 (27%)-SiO 2 is related to the high dispersion.
Fil: Irusta, S.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Carrara, Carlos Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Co2 Reforming
Hydrogen Production
La2o 3-Sio2
Membrane Reactor
Rh Catalysts
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/74314
Acceder
id CONICETDig_168b76ef72e86ae373a76b2c183ed115
oai_identifier_str oai:ri.conicet.gov.ar:11336/74314
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A stable, novel catalyst improves hydrogen production in a membrane reactorIrusta, S.Múnera Agudelo, John FernandoCarrara, Carlos RobertoLombardo, Eduardo AgustinCornaglia, Laura MariaCo2 ReformingHydrogen ProductionLa2o 3-Sio2Membrane ReactorRh Catalystshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The dry reforming of methane as a source of H2 was performed using a well-known catalyst, Rh/La2O3, together with a novel one, Rh/La2O3-SiO2, in a hydrogen-permeable membrane reactor. The catalysts were characterized by XRD, TPR, FTIR, H2 and CO chemisorption. In all lanthanum-based catalysts, the activity remained constant after 100 h on stream at 823 K. The basis of their high stability could be traced back to the strong metal-support interaction (TPR) in Rh/La2O3 catalysts. The La 2O3-SiO2 solids are also stable even though a weaker rhodium-lanthanum interaction (TPR) can be observed. The incorporation of the promoter (La2O3) to the silica support induces a parallel increase in the metal dispersion (CO adsorption). The effect of the operation variables upon the performance of the membrane reactor was also studied. The novel Rh (0.6%)/La2O3 (27%)-SiO2 catalyst proved to be the best formulation. Operating the membrane reactor at 823 K, both methane and CO2 conversions were 40% higher than the equilibrium values, producing 0.5 mol H2/mol CH4. This catalyst, tested at W/F three times lower than Rh (0.6%)/La2O 3, showed a similar performance. Both the increase of the sweep gas flow rate and the decrease of the permeation area significantly affected methane conversion and H2 production. The presence of tiny amounts of graphite only detectable through LRS did not endanger membrane stability. The better performance of Rh (0.6%)/La2O3 (27%)-SiO 2 is related to the high dispersion.Fil: Irusta, S.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Carrara, Carlos Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2005-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/74314Irusta, S.; Múnera Agudelo, John Fernando; Carrara, Carlos Roberto; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; A stable, novel catalyst improves hydrogen production in a membrane reactor; Elsevier Science; Applied Catalysis A: General; 287; 2; 6-2005; 147-1580926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2005.03.018info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X05001894info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:03:22Zoai:ri.conicet.gov.ar:11336/74314instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:03:23.064CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A stable, novel catalyst improves hydrogen production in a membrane reactor
title A stable, novel catalyst improves hydrogen production in a membrane reactor
spellingShingle A stable, novel catalyst improves hydrogen production in a membrane reactor
Irusta, S.
Co2 Reforming
Hydrogen Production
La2o 3-Sio2
Membrane Reactor
Rh Catalysts
title_short A stable, novel catalyst improves hydrogen production in a membrane reactor
title_full A stable, novel catalyst improves hydrogen production in a membrane reactor
title_fullStr A stable, novel catalyst improves hydrogen production in a membrane reactor
title_full_unstemmed A stable, novel catalyst improves hydrogen production in a membrane reactor
title_sort A stable, novel catalyst improves hydrogen production in a membrane reactor
dc.creator.none.fl_str_mv Irusta, S.
Múnera Agudelo, John Fernando
Carrara, Carlos Roberto
Lombardo, Eduardo Agustin
Cornaglia, Laura Maria
author Irusta, S.
author_facet Irusta, S.
Múnera Agudelo, John Fernando
Carrara, Carlos Roberto
Lombardo, Eduardo Agustin
Cornaglia, Laura Maria
author_role author
author2 Múnera Agudelo, John Fernando
Carrara, Carlos Roberto
Lombardo, Eduardo Agustin
Cornaglia, Laura Maria
author2_role author
author
author
author
dc.subject.none.fl_str_mv Co2 Reforming
Hydrogen Production
La2o 3-Sio2
Membrane Reactor
Rh Catalysts
topic Co2 Reforming
Hydrogen Production
La2o 3-Sio2
Membrane Reactor
Rh Catalysts
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The dry reforming of methane as a source of H2 was performed using a well-known catalyst, Rh/La2O3, together with a novel one, Rh/La2O3-SiO2, in a hydrogen-permeable membrane reactor. The catalysts were characterized by XRD, TPR, FTIR, H2 and CO chemisorption. In all lanthanum-based catalysts, the activity remained constant after 100 h on stream at 823 K. The basis of their high stability could be traced back to the strong metal-support interaction (TPR) in Rh/La2O3 catalysts. The La 2O3-SiO2 solids are also stable even though a weaker rhodium-lanthanum interaction (TPR) can be observed. The incorporation of the promoter (La2O3) to the silica support induces a parallel increase in the metal dispersion (CO adsorption). The effect of the operation variables upon the performance of the membrane reactor was also studied. The novel Rh (0.6%)/La2O3 (27%)-SiO2 catalyst proved to be the best formulation. Operating the membrane reactor at 823 K, both methane and CO2 conversions were 40% higher than the equilibrium values, producing 0.5 mol H2/mol CH4. This catalyst, tested at W/F three times lower than Rh (0.6%)/La2O 3, showed a similar performance. Both the increase of the sweep gas flow rate and the decrease of the permeation area significantly affected methane conversion and H2 production. The presence of tiny amounts of graphite only detectable through LRS did not endanger membrane stability. The better performance of Rh (0.6%)/La2O3 (27%)-SiO 2 is related to the high dispersion.
Fil: Irusta, S.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Carrara, Carlos Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The dry reforming of methane as a source of H2 was performed using a well-known catalyst, Rh/La2O3, together with a novel one, Rh/La2O3-SiO2, in a hydrogen-permeable membrane reactor. The catalysts were characterized by XRD, TPR, FTIR, H2 and CO chemisorption. In all lanthanum-based catalysts, the activity remained constant after 100 h on stream at 823 K. The basis of their high stability could be traced back to the strong metal-support interaction (TPR) in Rh/La2O3 catalysts. The La 2O3-SiO2 solids are also stable even though a weaker rhodium-lanthanum interaction (TPR) can be observed. The incorporation of the promoter (La2O3) to the silica support induces a parallel increase in the metal dispersion (CO adsorption). The effect of the operation variables upon the performance of the membrane reactor was also studied. The novel Rh (0.6%)/La2O3 (27%)-SiO2 catalyst proved to be the best formulation. Operating the membrane reactor at 823 K, both methane and CO2 conversions were 40% higher than the equilibrium values, producing 0.5 mol H2/mol CH4. This catalyst, tested at W/F three times lower than Rh (0.6%)/La2O 3, showed a similar performance. Both the increase of the sweep gas flow rate and the decrease of the permeation area significantly affected methane conversion and H2 production. The presence of tiny amounts of graphite only detectable through LRS did not endanger membrane stability. The better performance of Rh (0.6%)/La2O3 (27%)-SiO 2 is related to the high dispersion.
publishDate 2005
dc.date.none.fl_str_mv 2005-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/74314
Irusta, S.; Múnera Agudelo, John Fernando; Carrara, Carlos Roberto; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; A stable, novel catalyst improves hydrogen production in a membrane reactor; Elsevier Science; Applied Catalysis A: General; 287; 2; 6-2005; 147-158
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/74314
identifier_str_mv Irusta, S.; Múnera Agudelo, John Fernando; Carrara, Carlos Roberto; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; A stable, novel catalyst improves hydrogen production in a membrane reactor; Elsevier Science; Applied Catalysis A: General; 287; 2; 6-2005; 147-158
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2005.03.018
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X05001894
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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