Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane

Autores
Faroldi, Betina María Cecilia; Gómez Múnera, John Anderson; Falivene, Juan Manuel; Rodríguez Ramos, Inmaculada; Gutiérrez García, Álvaro; Tejedor Fernández, Loreto; González Carrazán, Silvia; Cornaglia, Laura Maria
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Rh catalysts with low Rh content were prepared by incipient wetness impregnation using [NH4]3[RhCl6]·3H2O or RhCl3·3H2O as precursor salts, on CaO–SiO2 supports. All solids showed a high stability after 48 h on stream for the dry reforming of methane with low carbon content, which made them suitable for obtaining ultrapure hydrogen in a membrane reactor. The methane conversion and hydrogen recovery were measured increasing the sweep gas flow rates to rise the driving force for hydrogen permeation. The catalyst with 0.36 wt.% of Rh showed a slight deactivation. However, the Rh(0.6)/CaO–SiO2 solid, in which the Rh impregnation was performed using [NH4]3[RhCl6]·3H2O, exhibited an increase on CH4 conversion of 77% and a hydrogen recovery equal to 84%. Nanoparticles of about 1.4–1.7 nm surface average diameter were detected for the reduced and used solids indicating that Rh is well dispersed and sintering was not produced after the catalytic tests. Rh particle sizes calculated by CO chemisorption were coincident with those measured by Transmission Electron Microscopy. Characterization by this technique and Laser Raman Spectroscopy of the solids used in membrane reactor revealed the formation of scarce carbon filaments. However, a surface re-oxidation was detected in the low loading catalyst used in the membrane reactor suggesting that it is the main cause for the decrease in the activity of the highly dispersed catalyst.
Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Gómez Múnera, John Anderson. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Falivene, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rodríguez Ramos, Inmaculada. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; España
Fil: Gutiérrez García, Álvaro. Universidad de Salamanca; España
Fil: Tejedor Fernández, Loreto. Universidad de Salamanca; España
Fil: González Carrazán, Silvia. Universidad de Salamanca; España
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Dry Reforming
Rh Nanoparticles
Sio2 Binary Supports
Pure Hydrogen
Membrane Reactor
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/43569
Acceder
id CONICETDig_02d56d37e92b2e82c712ad811d180e83
oai_identifier_str oai:ri.conicet.gov.ar:11336/43569
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Well-dispersed Rh nanoparticles with high activity for the dry reforming of methaneFaroldi, Betina María CeciliaGómez Múnera, John AndersonFalivene, Juan ManuelRodríguez Ramos, InmaculadaGutiérrez García, ÁlvaroTejedor Fernández, LoretoGonzález Carrazán, SilviaCornaglia, Laura MariaDry ReformingRh NanoparticlesSio2 Binary SupportsPure HydrogenMembrane Reactorhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Rh catalysts with low Rh content were prepared by incipient wetness impregnation using [NH4]3[RhCl6]·3H2O or RhCl3·3H2O as precursor salts, on CaO–SiO2 supports. All solids showed a high stability after 48 h on stream for the dry reforming of methane with low carbon content, which made them suitable for obtaining ultrapure hydrogen in a membrane reactor. The methane conversion and hydrogen recovery were measured increasing the sweep gas flow rates to rise the driving force for hydrogen permeation. The catalyst with 0.36 wt.% of Rh showed a slight deactivation. However, the Rh(0.6)/CaO–SiO2 solid, in which the Rh impregnation was performed using [NH4]3[RhCl6]·3H2O, exhibited an increase on CH4 conversion of 77% and a hydrogen recovery equal to 84%. Nanoparticles of about 1.4–1.7 nm surface average diameter were detected for the reduced and used solids indicating that Rh is well dispersed and sintering was not produced after the catalytic tests. Rh particle sizes calculated by CO chemisorption were coincident with those measured by Transmission Electron Microscopy. Characterization by this technique and Laser Raman Spectroscopy of the solids used in membrane reactor revealed the formation of scarce carbon filaments. However, a surface re-oxidation was detected in the low loading catalyst used in the membrane reactor suggesting that it is the main cause for the decrease in the activity of the highly dispersed catalyst.Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Gómez Múnera, John Anderson. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Falivene, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Rodríguez Ramos, Inmaculada. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; EspañaFil: Gutiérrez García, Álvaro. Universidad de Salamanca; EspañaFil: Tejedor Fernández, Loreto. Universidad de Salamanca; EspañaFil: González Carrazán, Silvia. Universidad de Salamanca; EspañaFil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaPergamon-Elsevier Science Ltd2017-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/43569Faroldi, Betina María Cecilia; Gómez Múnera, John Anderson; Falivene, Juan Manuel; Rodríguez Ramos, Inmaculada; Gutiérrez García, Álvaro; et al.; Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 42; 25; 6-2017; 16127-161380360-3199CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0360319917314507info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2017.04.070info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:39Zoai:ri.conicet.gov.ar:11336/43569instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:39.247CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane
title Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane
spellingShingle Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane
Faroldi, Betina María Cecilia
Dry Reforming
Rh Nanoparticles
Sio2 Binary Supports
Pure Hydrogen
Membrane Reactor
title_short Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane
title_full Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane
title_fullStr Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane
title_full_unstemmed Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane
title_sort Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane
dc.creator.none.fl_str_mv Faroldi, Betina María Cecilia
Gómez Múnera, John Anderson
Falivene, Juan Manuel
Rodríguez Ramos, Inmaculada
Gutiérrez García, Álvaro
Tejedor Fernández, Loreto
González Carrazán, Silvia
Cornaglia, Laura Maria
author Faroldi, Betina María Cecilia
author_facet Faroldi, Betina María Cecilia
Gómez Múnera, John Anderson
Falivene, Juan Manuel
Rodríguez Ramos, Inmaculada
Gutiérrez García, Álvaro
Tejedor Fernández, Loreto
González Carrazán, Silvia
Cornaglia, Laura Maria
author_role author
author2 Gómez Múnera, John Anderson
Falivene, Juan Manuel
Rodríguez Ramos, Inmaculada
Gutiérrez García, Álvaro
Tejedor Fernández, Loreto
González Carrazán, Silvia
Cornaglia, Laura Maria
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Dry Reforming
Rh Nanoparticles
Sio2 Binary Supports
Pure Hydrogen
Membrane Reactor
topic Dry Reforming
Rh Nanoparticles
Sio2 Binary Supports
Pure Hydrogen
Membrane Reactor
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Rh catalysts with low Rh content were prepared by incipient wetness impregnation using [NH4]3[RhCl6]·3H2O or RhCl3·3H2O as precursor salts, on CaO–SiO2 supports. All solids showed a high stability after 48 h on stream for the dry reforming of methane with low carbon content, which made them suitable for obtaining ultrapure hydrogen in a membrane reactor. The methane conversion and hydrogen recovery were measured increasing the sweep gas flow rates to rise the driving force for hydrogen permeation. The catalyst with 0.36 wt.% of Rh showed a slight deactivation. However, the Rh(0.6)/CaO–SiO2 solid, in which the Rh impregnation was performed using [NH4]3[RhCl6]·3H2O, exhibited an increase on CH4 conversion of 77% and a hydrogen recovery equal to 84%. Nanoparticles of about 1.4–1.7 nm surface average diameter were detected for the reduced and used solids indicating that Rh is well dispersed and sintering was not produced after the catalytic tests. Rh particle sizes calculated by CO chemisorption were coincident with those measured by Transmission Electron Microscopy. Characterization by this technique and Laser Raman Spectroscopy of the solids used in membrane reactor revealed the formation of scarce carbon filaments. However, a surface re-oxidation was detected in the low loading catalyst used in the membrane reactor suggesting that it is the main cause for the decrease in the activity of the highly dispersed catalyst.
Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Gómez Múnera, John Anderson. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Falivene, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rodríguez Ramos, Inmaculada. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; España
Fil: Gutiérrez García, Álvaro. Universidad de Salamanca; España
Fil: Tejedor Fernández, Loreto. Universidad de Salamanca; España
Fil: González Carrazán, Silvia. Universidad de Salamanca; España
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description Rh catalysts with low Rh content were prepared by incipient wetness impregnation using [NH4]3[RhCl6]·3H2O or RhCl3·3H2O as precursor salts, on CaO–SiO2 supports. All solids showed a high stability after 48 h on stream for the dry reforming of methane with low carbon content, which made them suitable for obtaining ultrapure hydrogen in a membrane reactor. The methane conversion and hydrogen recovery were measured increasing the sweep gas flow rates to rise the driving force for hydrogen permeation. The catalyst with 0.36 wt.% of Rh showed a slight deactivation. However, the Rh(0.6)/CaO–SiO2 solid, in which the Rh impregnation was performed using [NH4]3[RhCl6]·3H2O, exhibited an increase on CH4 conversion of 77% and a hydrogen recovery equal to 84%. Nanoparticles of about 1.4–1.7 nm surface average diameter were detected for the reduced and used solids indicating that Rh is well dispersed and sintering was not produced after the catalytic tests. Rh particle sizes calculated by CO chemisorption were coincident with those measured by Transmission Electron Microscopy. Characterization by this technique and Laser Raman Spectroscopy of the solids used in membrane reactor revealed the formation of scarce carbon filaments. However, a surface re-oxidation was detected in the low loading catalyst used in the membrane reactor suggesting that it is the main cause for the decrease in the activity of the highly dispersed catalyst.
publishDate 2017
dc.date.none.fl_str_mv 2017-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/43569
Faroldi, Betina María Cecilia; Gómez Múnera, John Anderson; Falivene, Juan Manuel; Rodríguez Ramos, Inmaculada; Gutiérrez García, Álvaro; et al.; Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 42; 25; 6-2017; 16127-16138
0360-3199
CONICET Digital
CONICET
url http://hdl.handle.net/11336/43569
identifier_str_mv Faroldi, Betina María Cecilia; Gómez Múnera, John Anderson; Falivene, Juan Manuel; Rodríguez Ramos, Inmaculada; Gutiérrez García, Álvaro; et al.; Well-dispersed Rh nanoparticles with high activity for the dry reforming of methane; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 42; 25; 6-2017; 16127-16138
0360-3199
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0360319917314507
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2017.04.070
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613111882973184
score 13.070432

Publicaciones similares