Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts

Autores
Faroldi, Betina María Cecilia; Carrara, Carlos Roberto; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Ru catalysts supported on lanthanum oxide with different loadings were prepared by wet impregnation. These solids were characterized by laser Raman spectroscopy (LSR), XPS, XRD and TPR. The catalytic activity toward hydrogen production through the dry reforming of methane was determined in a fixed-bed reactor and a membrane reactor. The reaction rate expressed per gram of Ru decreased when the metal loading increased. In the Pd-Ag membrane reactor, when the sweep gas flow rate (SG) increased, the conversions overcame the equilibrium values and the difference between CH4 and CO2 conversions decreased. Both Ru(0.6) and Ru(1.2) catalysts were able to restore the equilibrium for the dry reforming reaction up to values of SG = 30 ml min-1; Ru(0.6) was the most effective catalyst. By employing a CO2/CH4 = 1 and a SG of 0.05 mmol s-1, both a high H2 permeation flux of 5.68 × 10-7 mol s-1 m-2 and a hydrogen recovery of 80% were obtained. Both the TPR and the Raman spectroscopy data indicated the presence of Ru(III) strongly interacting with La. Significantly, this observation was further confirmed by the appearance of Ru(III) on the surface. When the Ru content increased, the higher Ru 3d binding energy component was proposed as arising from Ru(IV). Concerning the Ru(1.2) solid, the presence of Ru(IV) was detected by means of TPR experiments, in agreement with the high proportion of Ru(IV) on the surface. Therefore, a fraction of Ru loading was present in this solid as species with weaker metal-support interaction leading to the slight deactivation of this catalyst in the membrane reactor.
Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Carrara, Carlos Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Co2 Reforming
Hydrogen Production
Membrane Reactor
Ru/La2o3
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/73012
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/73012
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalystsFaroldi, Betina María CeciliaCarrara, Carlos RobertoLombardo, Eduardo AgustinCornaglia, Laura MariaCo2 ReformingHydrogen ProductionMembrane ReactorRu/La2o3https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Ru catalysts supported on lanthanum oxide with different loadings were prepared by wet impregnation. These solids were characterized by laser Raman spectroscopy (LSR), XPS, XRD and TPR. The catalytic activity toward hydrogen production through the dry reforming of methane was determined in a fixed-bed reactor and a membrane reactor. The reaction rate expressed per gram of Ru decreased when the metal loading increased. In the Pd-Ag membrane reactor, when the sweep gas flow rate (SG) increased, the conversions overcame the equilibrium values and the difference between CH4 and CO2 conversions decreased. Both Ru(0.6) and Ru(1.2) catalysts were able to restore the equilibrium for the dry reforming reaction up to values of SG = 30 ml min-1; Ru(0.6) was the most effective catalyst. By employing a CO2/CH4 = 1 and a SG of 0.05 mmol s-1, both a high H2 permeation flux of 5.68 × 10-7 mol s-1 m-2 and a hydrogen recovery of 80% were obtained. Both the TPR and the Raman spectroscopy data indicated the presence of Ru(III) strongly interacting with La. Significantly, this observation was further confirmed by the appearance of Ru(III) on the surface. When the Ru content increased, the higher Ru 3d binding energy component was proposed as arising from Ru(IV). Concerning the Ru(1.2) solid, the presence of Ru(IV) was detected by means of TPR experiments, in agreement with the high proportion of Ru(IV) on the surface. Therefore, a fraction of Ru loading was present in this solid as species with weaker metal-support interaction leading to the slight deactivation of this catalyst in the membrane reactor.Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Carrara, Carlos Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2007-03-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/73012Faroldi, Betina María Cecilia; Carrara, Carlos Roberto; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts; Elsevier Science; Applied Catalysis A: General; 319; 12-3-2007; 38-460926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2006.11.015info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:23:48Zoai:ri.conicet.gov.ar:11336/73012instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:23:48.761CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts
title Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts
spellingShingle Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts
Faroldi, Betina María Cecilia
Co2 Reforming
Hydrogen Production
Membrane Reactor
Ru/La2o3
title_short Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts
title_full Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts
title_fullStr Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts
title_full_unstemmed Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts
title_sort Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts
dc.creator.none.fl_str_mv Faroldi, Betina María Cecilia
Carrara, Carlos Roberto
Lombardo, Eduardo Agustin
Cornaglia, Laura Maria
author Faroldi, Betina María Cecilia
author_facet Faroldi, Betina María Cecilia
Carrara, Carlos Roberto
Lombardo, Eduardo Agustin
Cornaglia, Laura Maria
author_role author
author2 Carrara, Carlos Roberto
Lombardo, Eduardo Agustin
Cornaglia, Laura Maria
author2_role author
author
author
dc.subject.none.fl_str_mv Co2 Reforming
Hydrogen Production
Membrane Reactor
Ru/La2o3
topic Co2 Reforming
Hydrogen Production
Membrane Reactor
Ru/La2o3
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Ru catalysts supported on lanthanum oxide with different loadings were prepared by wet impregnation. These solids were characterized by laser Raman spectroscopy (LSR), XPS, XRD and TPR. The catalytic activity toward hydrogen production through the dry reforming of methane was determined in a fixed-bed reactor and a membrane reactor. The reaction rate expressed per gram of Ru decreased when the metal loading increased. In the Pd-Ag membrane reactor, when the sweep gas flow rate (SG) increased, the conversions overcame the equilibrium values and the difference between CH4 and CO2 conversions decreased. Both Ru(0.6) and Ru(1.2) catalysts were able to restore the equilibrium for the dry reforming reaction up to values of SG = 30 ml min-1; Ru(0.6) was the most effective catalyst. By employing a CO2/CH4 = 1 and a SG of 0.05 mmol s-1, both a high H2 permeation flux of 5.68 × 10-7 mol s-1 m-2 and a hydrogen recovery of 80% were obtained. Both the TPR and the Raman spectroscopy data indicated the presence of Ru(III) strongly interacting with La. Significantly, this observation was further confirmed by the appearance of Ru(III) on the surface. When the Ru content increased, the higher Ru 3d binding energy component was proposed as arising from Ru(IV). Concerning the Ru(1.2) solid, the presence of Ru(IV) was detected by means of TPR experiments, in agreement with the high proportion of Ru(IV) on the surface. Therefore, a fraction of Ru loading was present in this solid as species with weaker metal-support interaction leading to the slight deactivation of this catalyst in the membrane reactor.
Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Carrara, Carlos Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description Ru catalysts supported on lanthanum oxide with different loadings were prepared by wet impregnation. These solids were characterized by laser Raman spectroscopy (LSR), XPS, XRD and TPR. The catalytic activity toward hydrogen production through the dry reforming of methane was determined in a fixed-bed reactor and a membrane reactor. The reaction rate expressed per gram of Ru decreased when the metal loading increased. In the Pd-Ag membrane reactor, when the sweep gas flow rate (SG) increased, the conversions overcame the equilibrium values and the difference between CH4 and CO2 conversions decreased. Both Ru(0.6) and Ru(1.2) catalysts were able to restore the equilibrium for the dry reforming reaction up to values of SG = 30 ml min-1; Ru(0.6) was the most effective catalyst. By employing a CO2/CH4 = 1 and a SG of 0.05 mmol s-1, both a high H2 permeation flux of 5.68 × 10-7 mol s-1 m-2 and a hydrogen recovery of 80% were obtained. Both the TPR and the Raman spectroscopy data indicated the presence of Ru(III) strongly interacting with La. Significantly, this observation was further confirmed by the appearance of Ru(III) on the surface. When the Ru content increased, the higher Ru 3d binding energy component was proposed as arising from Ru(IV). Concerning the Ru(1.2) solid, the presence of Ru(IV) was detected by means of TPR experiments, in agreement with the high proportion of Ru(IV) on the surface. Therefore, a fraction of Ru loading was present in this solid as species with weaker metal-support interaction leading to the slight deactivation of this catalyst in the membrane reactor.
publishDate 2007
dc.date.none.fl_str_mv 2007-03-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/73012
Faroldi, Betina María Cecilia; Carrara, Carlos Roberto; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts; Elsevier Science; Applied Catalysis A: General; 319; 12-3-2007; 38-46
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/73012
identifier_str_mv Faroldi, Betina María Cecilia; Carrara, Carlos Roberto; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Production of ultrapure hydrogen in a Pd-Ag membrane reactor using Ru/La2O3 catalysts; Elsevier Science; Applied Catalysis A: General; 319; 12-3-2007; 38-46
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2006.11.015
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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