Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies

Autores
Parthasarathy, Prakash; Fernandez Brizuela, Anabel Alejandra; Kumar Singh, Deepak; Al Ansari, Tareq; Mackey, Hamish R.; Rodriguez, Rosa Ana; Mazza, German Delfor; Vachan Tirkey, Jeewan; McKay, Gordon
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Cameldung (CM) and date stone (DS) are biomass resources that are abundant acrossthe Gulf region and have the potential to produce sustainable renewable fuelsand specialty products. Copyrolysis of camel dung with DS is an intriguingresearch approach to boosting both the production and quality of pyrolysisproducts, particularly biochar. The current study investigated the bio-energypotential of CM, DS, and CD-DS blend by assessing their physicochemical attributes,pyrolysis characteristics, and kinetic behaviour using thermodynamic analysis.To investigate the pyrolysis behaviour, the materials were thermally decomposedusing a thermogravimetric analyser under non-isothermal conditions at differentheating rates in a nitrogen environment. The findings of the physicochemicalanalysis established the bio-energy potential of the feedstocks for long-termenergy generation. Thermal degradation profiles of the samples revealedmultistage degradation due to the various components in their structure. Whilea positive synergistic effect between DS and CD was observed in the thermalprofile of the blend. The average apparent activation energy of CD from theFriedman method, Flynn-Wall-Ozawa (FWO) model, Kissinger-Akahira-Sunose (KAS)method, and Starink model was 324, 167, 157, and 158 kJ/mol, respectively.Friedman, FWO, KAS, and Starink methods yielded average activation energies of621, 315, 276, and 279 kJ/mol for DS, respectively. The mean activation energyof the blend estimated using the Friedman, FWO, KAS, and Starink methods was210, 216, 206, and 207 kJ/mol, respectively. The thermodynamic outcomes revealthat slow pyrolysis of the specified feedstocks is a nonspontaneous processrequiring external energy for their degradation. The findings of this study mayaid in a better understanding of reaction processes and the expansion of pyrolysisapplications of DS, CD, and their mix.
Fil: Parthasarathy, Prakash. Hamad Bin Khalifa University; Qatar
Fil: Fernandez Brizuela, Anabel Alejandra. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Conicet - Patagonia Confluencia. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica | Universidad Nacional del Comahue. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica.; Argentina
Fil: Kumar Singh, Deepak. Indian Institute of Technology; India
Fil: Al Ansari, Tareq. Hamad Bin Khalifa University; Qatar
Fil: Mackey, Hamish R.. Hamad Bin Khalifa University; Qatar
Fil: Rodriguez, Rosa Ana. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Conicet - Patagonia Confluencia. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica | Universidad Nacional del Comahue. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica.; Argentina
Fil: Mazza, German Delfor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Vachan Tirkey, Jeewan. Indian Institute Of Technology. Mechanical & Industrial Engineering Departament; India
Fil: McKay, Gordon. Hamad Bin Khalifa University; Qatar
Materia
CAMEL DUNG
DATE STONE
PYROLYSIS
THERMOGRAVIMETRIC ANALYSIS
KINETIC ANALYSIS
THERMODYNAMIC PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/217854
Acceder
id CONICETDig_12d146740b65f8d9cc8385bcb7bf6247
oai_identifier_str oai:ri.conicet.gov.ar:11336/217854
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studiesParthasarathy, PrakashFernandez Brizuela, Anabel AlejandraKumar Singh, DeepakAl Ansari, TareqMackey, Hamish R.Rodriguez, Rosa AnaMazza, German DelforVachan Tirkey, JeewanMcKay, GordonCAMEL DUNGDATE STONEPYROLYSISTHERMOGRAVIMETRIC ANALYSISKINETIC ANALYSISTHERMODYNAMIC PROPERTIEShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Cameldung (CM) and date stone (DS) are biomass resources that are abundant acrossthe Gulf region and have the potential to produce sustainable renewable fuelsand specialty products. Copyrolysis of camel dung with DS is an intriguingresearch approach to boosting both the production and quality of pyrolysisproducts, particularly biochar. The current study investigated the bio-energypotential of CM, DS, and CD-DS blend by assessing their physicochemical attributes,pyrolysis characteristics, and kinetic behaviour using thermodynamic analysis.To investigate the pyrolysis behaviour, the materials were thermally decomposedusing a thermogravimetric analyser under non-isothermal conditions at differentheating rates in a nitrogen environment. The findings of the physicochemicalanalysis established the bio-energy potential of the feedstocks for long-termenergy generation. Thermal degradation profiles of the samples revealedmultistage degradation due to the various components in their structure. Whilea positive synergistic effect between DS and CD was observed in the thermalprofile of the blend. The average apparent activation energy of CD from theFriedman method, Flynn-Wall-Ozawa (FWO) model, Kissinger-Akahira-Sunose (KAS)method, and Starink model was 324, 167, 157, and 158 kJ/mol, respectively.Friedman, FWO, KAS, and Starink methods yielded average activation energies of621, 315, 276, and 279 kJ/mol for DS, respectively. The mean activation energyof the blend estimated using the Friedman, FWO, KAS, and Starink methods was210, 216, 206, and 207 kJ/mol, respectively. The thermodynamic outcomes revealthat slow pyrolysis of the specified feedstocks is a nonspontaneous processrequiring external energy for their degradation. The findings of this study mayaid in a better understanding of reaction processes and the expansion of pyrolysisapplications of DS, CD, and their mix.Fil: Parthasarathy, Prakash. Hamad Bin Khalifa University; QatarFil: Fernandez Brizuela, Anabel Alejandra. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Conicet - Patagonia Confluencia. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica | Universidad Nacional del Comahue. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica.; ArgentinaFil: Kumar Singh, Deepak. Indian Institute of Technology; IndiaFil: Al Ansari, Tareq. Hamad Bin Khalifa University; QatarFil: Mackey, Hamish R.. Hamad Bin Khalifa University; QatarFil: Rodriguez, Rosa Ana. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Conicet - Patagonia Confluencia. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica | Universidad Nacional del Comahue. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica.; ArgentinaFil: Mazza, German Delfor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Vachan Tirkey, Jeewan. Indian Institute Of Technology. Mechanical & Industrial Engineering Departament; IndiaFil: McKay, Gordon. Hamad Bin Khalifa University; QatarElsevier2022-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/217854Parthasarathy, Prakash; Fernandez Brizuela, Anabel Alejandra; Kumar Singh, Deepak; Al Ansari, Tareq; Mackey, Hamish R.; et al.; Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies; Elsevier; Cleaner Chemical Engineering; 4; 10-2022; 1-102772-7823CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/journal/cleaner-chemical-engineeringinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.clce.2022.100072info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:59:12Zoai:ri.conicet.gov.ar:11336/217854instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:59:12.638CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies
title Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies
spellingShingle Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies
Parthasarathy, Prakash
CAMEL DUNG
DATE STONE
PYROLYSIS
THERMOGRAVIMETRIC ANALYSIS
KINETIC ANALYSIS
THERMODYNAMIC PROPERTIES
title_short Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies
title_full Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies
title_fullStr Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies
title_full_unstemmed Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies
title_sort Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies
dc.creator.none.fl_str_mv Parthasarathy, Prakash
Fernandez Brizuela, Anabel Alejandra
Kumar Singh, Deepak
Al Ansari, Tareq
Mackey, Hamish R.
Rodriguez, Rosa Ana
Mazza, German Delfor
Vachan Tirkey, Jeewan
McKay, Gordon
author Parthasarathy, Prakash
author_facet Parthasarathy, Prakash
Fernandez Brizuela, Anabel Alejandra
Kumar Singh, Deepak
Al Ansari, Tareq
Mackey, Hamish R.
Rodriguez, Rosa Ana
Mazza, German Delfor
Vachan Tirkey, Jeewan
McKay, Gordon
author_role author
author2 Fernandez Brizuela, Anabel Alejandra
Kumar Singh, Deepak
Al Ansari, Tareq
Mackey, Hamish R.
Rodriguez, Rosa Ana
Mazza, German Delfor
Vachan Tirkey, Jeewan
McKay, Gordon
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv CAMEL DUNG
DATE STONE
PYROLYSIS
THERMOGRAVIMETRIC ANALYSIS
KINETIC ANALYSIS
THERMODYNAMIC PROPERTIES
topic CAMEL DUNG
DATE STONE
PYROLYSIS
THERMOGRAVIMETRIC ANALYSIS
KINETIC ANALYSIS
THERMODYNAMIC PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Cameldung (CM) and date stone (DS) are biomass resources that are abundant acrossthe Gulf region and have the potential to produce sustainable renewable fuelsand specialty products. Copyrolysis of camel dung with DS is an intriguingresearch approach to boosting both the production and quality of pyrolysisproducts, particularly biochar. The current study investigated the bio-energypotential of CM, DS, and CD-DS blend by assessing their physicochemical attributes,pyrolysis characteristics, and kinetic behaviour using thermodynamic analysis.To investigate the pyrolysis behaviour, the materials were thermally decomposedusing a thermogravimetric analyser under non-isothermal conditions at differentheating rates in a nitrogen environment. The findings of the physicochemicalanalysis established the bio-energy potential of the feedstocks for long-termenergy generation. Thermal degradation profiles of the samples revealedmultistage degradation due to the various components in their structure. Whilea positive synergistic effect between DS and CD was observed in the thermalprofile of the blend. The average apparent activation energy of CD from theFriedman method, Flynn-Wall-Ozawa (FWO) model, Kissinger-Akahira-Sunose (KAS)method, and Starink model was 324, 167, 157, and 158 kJ/mol, respectively.Friedman, FWO, KAS, and Starink methods yielded average activation energies of621, 315, 276, and 279 kJ/mol for DS, respectively. The mean activation energyof the blend estimated using the Friedman, FWO, KAS, and Starink methods was210, 216, 206, and 207 kJ/mol, respectively. The thermodynamic outcomes revealthat slow pyrolysis of the specified feedstocks is a nonspontaneous processrequiring external energy for their degradation. The findings of this study mayaid in a better understanding of reaction processes and the expansion of pyrolysisapplications of DS, CD, and their mix.
Fil: Parthasarathy, Prakash. Hamad Bin Khalifa University; Qatar
Fil: Fernandez Brizuela, Anabel Alejandra. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Conicet - Patagonia Confluencia. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica | Universidad Nacional del Comahue. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica.; Argentina
Fil: Kumar Singh, Deepak. Indian Institute of Technology; India
Fil: Al Ansari, Tareq. Hamad Bin Khalifa University; Qatar
Fil: Mackey, Hamish R.. Hamad Bin Khalifa University; Qatar
Fil: Rodriguez, Rosa Ana. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Conicet - Patagonia Confluencia. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica | Universidad Nacional del Comahue. Instituto de Investigacion y Desarrollo En Ingenieria de Procesos, Biotecnologia y Energias Alternativas. Grupo Vinculado Instituto de Ingenieria Quimica.; Argentina
Fil: Mazza, German Delfor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Vachan Tirkey, Jeewan. Indian Institute Of Technology. Mechanical & Industrial Engineering Departament; India
Fil: McKay, Gordon. Hamad Bin Khalifa University; Qatar
description Cameldung (CM) and date stone (DS) are biomass resources that are abundant acrossthe Gulf region and have the potential to produce sustainable renewable fuelsand specialty products. Copyrolysis of camel dung with DS is an intriguingresearch approach to boosting both the production and quality of pyrolysisproducts, particularly biochar. The current study investigated the bio-energypotential of CM, DS, and CD-DS blend by assessing their physicochemical attributes,pyrolysis characteristics, and kinetic behaviour using thermodynamic analysis.To investigate the pyrolysis behaviour, the materials were thermally decomposedusing a thermogravimetric analyser under non-isothermal conditions at differentheating rates in a nitrogen environment. The findings of the physicochemicalanalysis established the bio-energy potential of the feedstocks for long-termenergy generation. Thermal degradation profiles of the samples revealedmultistage degradation due to the various components in their structure. Whilea positive synergistic effect between DS and CD was observed in the thermalprofile of the blend. The average apparent activation energy of CD from theFriedman method, Flynn-Wall-Ozawa (FWO) model, Kissinger-Akahira-Sunose (KAS)method, and Starink model was 324, 167, 157, and 158 kJ/mol, respectively.Friedman, FWO, KAS, and Starink methods yielded average activation energies of621, 315, 276, and 279 kJ/mol for DS, respectively. The mean activation energyof the blend estimated using the Friedman, FWO, KAS, and Starink methods was210, 216, 206, and 207 kJ/mol, respectively. The thermodynamic outcomes revealthat slow pyrolysis of the specified feedstocks is a nonspontaneous processrequiring external energy for their degradation. The findings of this study mayaid in a better understanding of reaction processes and the expansion of pyrolysisapplications of DS, CD, and their mix.
publishDate 2022
dc.date.none.fl_str_mv 2022-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/217854
Parthasarathy, Prakash; Fernandez Brizuela, Anabel Alejandra; Kumar Singh, Deepak; Al Ansari, Tareq; Mackey, Hamish R.; et al.; Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies; Elsevier; Cleaner Chemical Engineering; 4; 10-2022; 1-10
2772-7823
CONICET Digital
CONICET
url http://hdl.handle.net/11336/217854
identifier_str_mv Parthasarathy, Prakash; Fernandez Brizuela, Anabel Alejandra; Kumar Singh, Deepak; Al Ansari, Tareq; Mackey, Hamish R.; et al.; Thermogravimetric analysis of camel dung, date stone, and their blend for pyrolytic kinetic, and thermodynamic studies; Elsevier; Cleaner Chemical Engineering; 4; 10-2022; 1-10
2772-7823
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/journal/cleaner-chemical-engineering
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.clce.2022.100072
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.6313505

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