Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application

Autores
Fernandez Brizuela, Anabel Alejandra; Mazza, German Delfor; Rodriguez, Rosa Ana
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Combustion of six lignocellulosic wastes was studied using thermogravimetric analysis. Experimental data were analyzed using different kinetic methods Kissinger, FWO, DAEM linear multiple regression methods and Coast Redfern method. Also, their thermodynamic parameters (ΔG, ΔH, ΔS) were obtained. The activation energy (E) and the pre-exponential factor (A) values calculated by the DAEM, FWO and Kissinger methods were higher than those obtained by the linear multiple regression and Coast Redfern methods. The E values obtained from the Kissinger method are consistent with the range of values obtained by the FWO and DAEM methods and are very near to their average values (between 52.75 and 116.92 kJ/mol for all studied agro-industrial wastes). DAEM and FWO methods provides E and A distributions, detecting multi-step kinetics. However, Kissinger method provides only one E and A values for all heating rates, similar to obtained values applying DAEM and FWO methods. The linear multiple regression method provides the knowledge of kinetic triplets for each studied heating rate, presenting a slower fit than the other methods. On the other hand, Coast Redfern method supplies these triplets and the reaction mechanisms. However, using this method, the obtained E values are very different to the calculated values applying isoconversional methods. Using the last mentioned methods, the models of volume contraction and first order describe the devolatilization and char combustion stages, respectively. The obtained thermodynamic parameters values show that the lignocellulosic wastes combustion has a low reaction favorability.
Fil: Fernandez Brizuela, Anabel Alejandra. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Juan; Argentina
Fil: Mazza, German Delfor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Rodriguez, Rosa Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Juan; Argentina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina
Materia
COMBUSTION
ISOCONVERSIONAL AND NON-ISOCONVERSIONAL METHODS
KINETIC BEHAVIOUR
LIGNOCELLULOSIC WASTES
THERMODYNAMIC PARAMETERS
THERMOGRAVIMETRIC ANALYSIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/93312
Acceder
id CONICETDig_73336d7e773195843c143c3c615e0de6
oai_identifier_str oai:ri.conicet.gov.ar:11336/93312
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods applicationFernandez Brizuela, Anabel AlejandraMazza, German DelforRodriguez, Rosa AnaCOMBUSTIONISOCONVERSIONAL AND NON-ISOCONVERSIONAL METHODSKINETIC BEHAVIOURLIGNOCELLULOSIC WASTESTHERMODYNAMIC PARAMETERSTHERMOGRAVIMETRIC ANALYSIShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Combustion of six lignocellulosic wastes was studied using thermogravimetric analysis. Experimental data were analyzed using different kinetic methods Kissinger, FWO, DAEM linear multiple regression methods and Coast Redfern method. Also, their thermodynamic parameters (ΔG, ΔH, ΔS) were obtained. The activation energy (E) and the pre-exponential factor (A) values calculated by the DAEM, FWO and Kissinger methods were higher than those obtained by the linear multiple regression and Coast Redfern methods. The E values obtained from the Kissinger method are consistent with the range of values obtained by the FWO and DAEM methods and are very near to their average values (between 52.75 and 116.92 kJ/mol for all studied agro-industrial wastes). DAEM and FWO methods provides E and A distributions, detecting multi-step kinetics. However, Kissinger method provides only one E and A values for all heating rates, similar to obtained values applying DAEM and FWO methods. The linear multiple regression method provides the knowledge of kinetic triplets for each studied heating rate, presenting a slower fit than the other methods. On the other hand, Coast Redfern method supplies these triplets and the reaction mechanisms. However, using this method, the obtained E values are very different to the calculated values applying isoconversional methods. Using the last mentioned methods, the models of volume contraction and first order describe the devolatilization and char combustion stages, respectively. The obtained thermodynamic parameters values show that the lignocellulosic wastes combustion has a low reaction favorability.Fil: Fernandez Brizuela, Anabel Alejandra. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Juan; ArgentinaFil: Mazza, German Delfor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Rodriguez, Rosa Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Juan; Argentina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; ArgentinaElsevier2018-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/93312Fernandez Brizuela, Anabel Alejandra; Mazza, German Delfor; Rodriguez, Rosa Ana; Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application; Elsevier; Journal of Environmental Chemical Engineering; 6; 1; 2-2018; 404-4152213-3437CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2213343717306528info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2017.12.013info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:07:41Zoai:ri.conicet.gov.ar:11336/93312instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:07:41.742CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application
title Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application
spellingShingle Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application
Fernandez Brizuela, Anabel Alejandra
COMBUSTION
ISOCONVERSIONAL AND NON-ISOCONVERSIONAL METHODS
KINETIC BEHAVIOUR
LIGNOCELLULOSIC WASTES
THERMODYNAMIC PARAMETERS
THERMOGRAVIMETRIC ANALYSIS
title_short Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application
title_full Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application
title_fullStr Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application
title_full_unstemmed Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application
title_sort Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application
dc.creator.none.fl_str_mv Fernandez Brizuela, Anabel Alejandra
Mazza, German Delfor
Rodriguez, Rosa Ana
author Fernandez Brizuela, Anabel Alejandra
author_facet Fernandez Brizuela, Anabel Alejandra
Mazza, German Delfor
Rodriguez, Rosa Ana
author_role author
author2 Mazza, German Delfor
Rodriguez, Rosa Ana
author2_role author
author
dc.subject.none.fl_str_mv COMBUSTION
ISOCONVERSIONAL AND NON-ISOCONVERSIONAL METHODS
KINETIC BEHAVIOUR
LIGNOCELLULOSIC WASTES
THERMODYNAMIC PARAMETERS
THERMOGRAVIMETRIC ANALYSIS
topic COMBUSTION
ISOCONVERSIONAL AND NON-ISOCONVERSIONAL METHODS
KINETIC BEHAVIOUR
LIGNOCELLULOSIC WASTES
THERMODYNAMIC PARAMETERS
THERMOGRAVIMETRIC ANALYSIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Combustion of six lignocellulosic wastes was studied using thermogravimetric analysis. Experimental data were analyzed using different kinetic methods Kissinger, FWO, DAEM linear multiple regression methods and Coast Redfern method. Also, their thermodynamic parameters (ΔG, ΔH, ΔS) were obtained. The activation energy (E) and the pre-exponential factor (A) values calculated by the DAEM, FWO and Kissinger methods were higher than those obtained by the linear multiple regression and Coast Redfern methods. The E values obtained from the Kissinger method are consistent with the range of values obtained by the FWO and DAEM methods and are very near to their average values (between 52.75 and 116.92 kJ/mol for all studied agro-industrial wastes). DAEM and FWO methods provides E and A distributions, detecting multi-step kinetics. However, Kissinger method provides only one E and A values for all heating rates, similar to obtained values applying DAEM and FWO methods. The linear multiple regression method provides the knowledge of kinetic triplets for each studied heating rate, presenting a slower fit than the other methods. On the other hand, Coast Redfern method supplies these triplets and the reaction mechanisms. However, using this method, the obtained E values are very different to the calculated values applying isoconversional methods. Using the last mentioned methods, the models of volume contraction and first order describe the devolatilization and char combustion stages, respectively. The obtained thermodynamic parameters values show that the lignocellulosic wastes combustion has a low reaction favorability.
Fil: Fernandez Brizuela, Anabel Alejandra. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Juan; Argentina
Fil: Mazza, German Delfor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Rodriguez, Rosa Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Juan; Argentina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina
description Combustion of six lignocellulosic wastes was studied using thermogravimetric analysis. Experimental data were analyzed using different kinetic methods Kissinger, FWO, DAEM linear multiple regression methods and Coast Redfern method. Also, their thermodynamic parameters (ΔG, ΔH, ΔS) were obtained. The activation energy (E) and the pre-exponential factor (A) values calculated by the DAEM, FWO and Kissinger methods were higher than those obtained by the linear multiple regression and Coast Redfern methods. The E values obtained from the Kissinger method are consistent with the range of values obtained by the FWO and DAEM methods and are very near to their average values (between 52.75 and 116.92 kJ/mol for all studied agro-industrial wastes). DAEM and FWO methods provides E and A distributions, detecting multi-step kinetics. However, Kissinger method provides only one E and A values for all heating rates, similar to obtained values applying DAEM and FWO methods. The linear multiple regression method provides the knowledge of kinetic triplets for each studied heating rate, presenting a slower fit than the other methods. On the other hand, Coast Redfern method supplies these triplets and the reaction mechanisms. However, using this method, the obtained E values are very different to the calculated values applying isoconversional methods. Using the last mentioned methods, the models of volume contraction and first order describe the devolatilization and char combustion stages, respectively. The obtained thermodynamic parameters values show that the lignocellulosic wastes combustion has a low reaction favorability.
publishDate 2018
dc.date.none.fl_str_mv 2018-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/93312
Fernandez Brizuela, Anabel Alejandra; Mazza, German Delfor; Rodriguez, Rosa Ana; Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application; Elsevier; Journal of Environmental Chemical Engineering; 6; 1; 2-2018; 404-415
2213-3437
CONICET Digital
CONICET
url http://hdl.handle.net/11336/93312
identifier_str_mv Fernandez Brizuela, Anabel Alejandra; Mazza, German Delfor; Rodriguez, Rosa Ana; Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application; Elsevier; Journal of Environmental Chemical Engineering; 6; 1; 2-2018; 404-415
2213-3437
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2213343717306528
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2017.12.013
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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