Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate

Autores
Sánchez, María Amparo; Mazzieri, Vanina Alejandra; Vicerich, Maria Ana; Vera, Carlos Roman; Pieck, Carlos Luis
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The influence of the kind of support (Al2O3, SiO2, and TiO2) on the catalytic activity and selectivity of Ru−Sn−Bcatalysts for the hydrogenation of methyl oleate to oleyl alcohol was studied. The results show that the most active and selectivecatalyst for producing oleyl alcohol is Ru(1%)−Sn(2%)−B/Al2O3. This was attributed to the catalyst having a favorable surfaceSn/Ru ratio (∼2). The SiO2-supported Ru−Sn−B catalyst had a good activity and hydrogenated both C═C double bonds andthe C═O group, thus producing stearyl alcohol with a high yield. It however deactivated, to a great extent, its final conversionbeing lower than that of the bimetallic catalysts supported on Al2O3 and TiO2. The TiO2-supported catalyst had a high selectivityto saturated methyl esters because it hydrogenated C═C double bonds but had little activity for hydrogenation of the C═Ogroup
Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Activity
Selectivity
Hydrogenation
Methyl Oleate
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/34992
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/34992
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleateSánchez, María AmparoMazzieri, Vanina AlejandraVicerich, Maria AnaVera, Carlos RomanPieck, Carlos LuisActivitySelectivityHydrogenationMethyl Oleatehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of the kind of support (Al2O3, SiO2, and TiO2) on the catalytic activity and selectivity of Ru−Sn−Bcatalysts for the hydrogenation of methyl oleate to oleyl alcohol was studied. The results show that the most active and selectivecatalyst for producing oleyl alcohol is Ru(1%)−Sn(2%)−B/Al2O3. This was attributed to the catalyst having a favorable surfaceSn/Ru ratio (∼2). The SiO2-supported Ru−Sn−B catalyst had a good activity and hydrogenated both C═C double bonds andthe C═O group, thus producing stearyl alcohol with a high yield. It however deactivated, to a great extent, its final conversionbeing lower than that of the bimetallic catalysts supported on Al2O3 and TiO2. The TiO2-supported catalyst had a high selectivityto saturated methyl esters because it hydrogenated C═C double bonds but had little activity for hydrogenation of the C═OgroupFil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaAmerican Chemical Society2015-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/34992Sánchez, María Amparo; Mazzieri, Vanina Alejandra; Vicerich, Maria Ana; Vera, Carlos Roman; Pieck, Carlos Luis; Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate; American Chemical Society; Industrial & Engineering Chemical Research; 54; 27; 4-2015; 6845-68540888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.iecr.5b01038info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acs.iecr.5b01038info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:50:52Zoai:ri.conicet.gov.ar:11336/34992instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:50:52.694CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate
title Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate
spellingShingle Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate
Sánchez, María Amparo
Activity
Selectivity
Hydrogenation
Methyl Oleate
title_short Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate
title_full Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate
title_fullStr Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate
title_full_unstemmed Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate
title_sort Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate
dc.creator.none.fl_str_mv Sánchez, María Amparo
Mazzieri, Vanina Alejandra
Vicerich, Maria Ana
Vera, Carlos Roman
Pieck, Carlos Luis
author Sánchez, María Amparo
author_facet Sánchez, María Amparo
Mazzieri, Vanina Alejandra
Vicerich, Maria Ana
Vera, Carlos Roman
Pieck, Carlos Luis
author_role author
author2 Mazzieri, Vanina Alejandra
Vicerich, Maria Ana
Vera, Carlos Roman
Pieck, Carlos Luis
author2_role author
author
author
author
dc.subject.none.fl_str_mv Activity
Selectivity
Hydrogenation
Methyl Oleate
topic Activity
Selectivity
Hydrogenation
Methyl Oleate
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The influence of the kind of support (Al2O3, SiO2, and TiO2) on the catalytic activity and selectivity of Ru−Sn−Bcatalysts for the hydrogenation of methyl oleate to oleyl alcohol was studied. The results show that the most active and selectivecatalyst for producing oleyl alcohol is Ru(1%)−Sn(2%)−B/Al2O3. This was attributed to the catalyst having a favorable surfaceSn/Ru ratio (∼2). The SiO2-supported Ru−Sn−B catalyst had a good activity and hydrogenated both C═C double bonds andthe C═O group, thus producing stearyl alcohol with a high yield. It however deactivated, to a great extent, its final conversionbeing lower than that of the bimetallic catalysts supported on Al2O3 and TiO2. The TiO2-supported catalyst had a high selectivityto saturated methyl esters because it hydrogenated C═C double bonds but had little activity for hydrogenation of the C═Ogroup
Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description The influence of the kind of support (Al2O3, SiO2, and TiO2) on the catalytic activity and selectivity of Ru−Sn−Bcatalysts for the hydrogenation of methyl oleate to oleyl alcohol was studied. The results show that the most active and selectivecatalyst for producing oleyl alcohol is Ru(1%)−Sn(2%)−B/Al2O3. This was attributed to the catalyst having a favorable surfaceSn/Ru ratio (∼2). The SiO2-supported Ru−Sn−B catalyst had a good activity and hydrogenated both C═C double bonds andthe C═O group, thus producing stearyl alcohol with a high yield. It however deactivated, to a great extent, its final conversionbeing lower than that of the bimetallic catalysts supported on Al2O3 and TiO2. The TiO2-supported catalyst had a high selectivityto saturated methyl esters because it hydrogenated C═C double bonds but had little activity for hydrogenation of the C═Ogroup
publishDate 2015
dc.date.none.fl_str_mv 2015-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/34992
Sánchez, María Amparo; Mazzieri, Vanina Alejandra; Vicerich, Maria Ana; Vera, Carlos Roman; Pieck, Carlos Luis; Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate; American Chemical Society; Industrial & Engineering Chemical Research; 54; 27; 4-2015; 6845-6854
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/34992
identifier_str_mv Sánchez, María Amparo; Mazzieri, Vanina Alejandra; Vicerich, Maria Ana; Vera, Carlos Roman; Pieck, Carlos Luis; Influence of the support material on the activity and selectivity of Ru-Sn-B catalysts for the selective hydrogenation of methyl oleate; American Chemical Society; Industrial & Engineering Chemical Research; 54; 27; 4-2015; 6845-6854
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.iecr.5b01038
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acs.iecr.5b01038
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613566955520000
score 13.070432

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