Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon

Autores
Calvo, Walter Andrés; Ortega, P.; Velasco, M. J.; Muñoz, Vanesa; Pena, P.; Tomba Martinez, Analia Gladys
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The present paper is a continuation of previous ones focused on the characterization of alumina-magnesia-carbon refractories (AMC) bricks. Unlike those characterised materials which only have aluminium as an antioxidant, a brick also containing silicon is comparatively analysed in this paper. Along with metallic aluminium, silicon is among the most commonly used antioxidant additives in oxide-C refractories, but the studies on the incorporation of this metal into AMC bricks are rather limited. In this work, several complementary techniques were used in combination to achieve a detailed characterization in relation to the physical and chemical characteristics and thermal evolution of the Si-containing AMC refractory: X-ray fluorescence, plasma emission spectroscopy, gravimetry, granulometry, X-ray diffraction, differential thermal and thermogravimetric analyses, reflection optical and scanning electron microscopies, mercury intrusion porosimetry, and density, porosity, permanent linear change and permeability measurements. In addition, the characterization was completed by evaluating the chemical resistance to air and to a basic slag and calculating the equilibrium composition of the brick when it is subjected to high temperatures (up to 1400 °C). A comparison with the results obtained for previously characterised AMC bricks with similar MgO contents and metallic aluminium as an antioxidant was also made. The presence of silicon was related to finer open porosity and higher oxidation resistance at high temperature (1400 °C).
Fil: Calvo, Walter Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ortega, P.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Velasco, M. J.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Muñoz, Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Pena, P.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Tomba Martinez, Analia Gladys. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Al2o3
Carbon
Mgo
Refractories
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/81562
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/81562
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and siliconCalvo, Walter AndrésOrtega, P.Velasco, M. J.Muñoz, VanesaPena, P.Tomba Martinez, Analia GladysAl2o3CarbonMgoRefractorieshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The present paper is a continuation of previous ones focused on the characterization of alumina-magnesia-carbon refractories (AMC) bricks. Unlike those characterised materials which only have aluminium as an antioxidant, a brick also containing silicon is comparatively analysed in this paper. Along with metallic aluminium, silicon is among the most commonly used antioxidant additives in oxide-C refractories, but the studies on the incorporation of this metal into AMC bricks are rather limited. In this work, several complementary techniques were used in combination to achieve a detailed characterization in relation to the physical and chemical characteristics and thermal evolution of the Si-containing AMC refractory: X-ray fluorescence, plasma emission spectroscopy, gravimetry, granulometry, X-ray diffraction, differential thermal and thermogravimetric analyses, reflection optical and scanning electron microscopies, mercury intrusion porosimetry, and density, porosity, permanent linear change and permeability measurements. In addition, the characterization was completed by evaluating the chemical resistance to air and to a basic slag and calculating the equilibrium composition of the brick when it is subjected to high temperatures (up to 1400 °C). A comparison with the results obtained for previously characterised AMC bricks with similar MgO contents and metallic aluminium as an antioxidant was also made. The presence of silicon was related to finer open porosity and higher oxidation resistance at high temperature (1400 °C).Fil: Calvo, Walter Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ortega, P.. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Velasco, M. J.. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Muñoz, Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Pena, P.. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Tomba Martinez, Analia Gladys. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier2018-02-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/81562Calvo, Walter Andrés; Ortega, P.; Velasco, M. J.; Muñoz, Vanesa; Pena, P.; et al.; Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon; Elsevier; Ceramics International; 44; 8; 8-2-2018; 8842-88550272-8842CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0272884218303687info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceramint.2018.02.069info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:46:53Zoai:ri.conicet.gov.ar:11336/81562instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:46:53.849CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon
title Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon
spellingShingle Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon
Calvo, Walter Andrés
Al2o3
Carbon
Mgo
Refractories
title_short Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon
title_full Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon
title_fullStr Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon
title_full_unstemmed Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon
title_sort Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon
dc.creator.none.fl_str_mv Calvo, Walter Andrés
Ortega, P.
Velasco, M. J.
Muñoz, Vanesa
Pena, P.
Tomba Martinez, Analia Gladys
author Calvo, Walter Andrés
author_facet Calvo, Walter Andrés
Ortega, P.
Velasco, M. J.
Muñoz, Vanesa
Pena, P.
Tomba Martinez, Analia Gladys
author_role author
author2 Ortega, P.
Velasco, M. J.
Muñoz, Vanesa
Pena, P.
Tomba Martinez, Analia Gladys
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Al2o3
Carbon
Mgo
Refractories
topic Al2o3
Carbon
Mgo
Refractories
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The present paper is a continuation of previous ones focused on the characterization of alumina-magnesia-carbon refractories (AMC) bricks. Unlike those characterised materials which only have aluminium as an antioxidant, a brick also containing silicon is comparatively analysed in this paper. Along with metallic aluminium, silicon is among the most commonly used antioxidant additives in oxide-C refractories, but the studies on the incorporation of this metal into AMC bricks are rather limited. In this work, several complementary techniques were used in combination to achieve a detailed characterization in relation to the physical and chemical characteristics and thermal evolution of the Si-containing AMC refractory: X-ray fluorescence, plasma emission spectroscopy, gravimetry, granulometry, X-ray diffraction, differential thermal and thermogravimetric analyses, reflection optical and scanning electron microscopies, mercury intrusion porosimetry, and density, porosity, permanent linear change and permeability measurements. In addition, the characterization was completed by evaluating the chemical resistance to air and to a basic slag and calculating the equilibrium composition of the brick when it is subjected to high temperatures (up to 1400 °C). A comparison with the results obtained for previously characterised AMC bricks with similar MgO contents and metallic aluminium as an antioxidant was also made. The presence of silicon was related to finer open porosity and higher oxidation resistance at high temperature (1400 °C).
Fil: Calvo, Walter Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ortega, P.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Velasco, M. J.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Muñoz, Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Pena, P.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Tomba Martinez, Analia Gladys. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description The present paper is a continuation of previous ones focused on the characterization of alumina-magnesia-carbon refractories (AMC) bricks. Unlike those characterised materials which only have aluminium as an antioxidant, a brick also containing silicon is comparatively analysed in this paper. Along with metallic aluminium, silicon is among the most commonly used antioxidant additives in oxide-C refractories, but the studies on the incorporation of this metal into AMC bricks are rather limited. In this work, several complementary techniques were used in combination to achieve a detailed characterization in relation to the physical and chemical characteristics and thermal evolution of the Si-containing AMC refractory: X-ray fluorescence, plasma emission spectroscopy, gravimetry, granulometry, X-ray diffraction, differential thermal and thermogravimetric analyses, reflection optical and scanning electron microscopies, mercury intrusion porosimetry, and density, porosity, permanent linear change and permeability measurements. In addition, the characterization was completed by evaluating the chemical resistance to air and to a basic slag and calculating the equilibrium composition of the brick when it is subjected to high temperatures (up to 1400 °C). A comparison with the results obtained for previously characterised AMC bricks with similar MgO contents and metallic aluminium as an antioxidant was also made. The presence of silicon was related to finer open porosity and higher oxidation resistance at high temperature (1400 °C).
publishDate 2018
dc.date.none.fl_str_mv 2018-02-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/81562
Calvo, Walter Andrés; Ortega, P.; Velasco, M. J.; Muñoz, Vanesa; Pena, P.; et al.; Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon; Elsevier; Ceramics International; 44; 8; 8-2-2018; 8842-8855
0272-8842
CONICET Digital
CONICET
url http://hdl.handle.net/11336/81562
identifier_str_mv Calvo, Walter Andrés; Ortega, P.; Velasco, M. J.; Muñoz, Vanesa; Pena, P.; et al.; Characterization of alumina-magnesia-carbon refractory bricks containing aluminium and silicon; Elsevier; Ceramics International; 44; 8; 8-2-2018; 8842-8855
0272-8842
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0272884218303687
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceramint.2018.02.069
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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