Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air

Autores
Camerucci, Maria Andrea; Galliano, Pablo German; Cavalieri, Ana Lia; Tomba Martinez, Analia Gladys
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, the chemical degradation in air of different commercial MgO-C refractories used in the steelmaking industry was studied. Materials were characterized by mineralogical, microstructural, differential thermal and thermo-gravimetric analyses and measurements of density and porosity. Cylindrical samples were subjected to isothermal treatments at different temperatures and times in air and then, the weight loss and percentage of decarburized area were determined. Moreover, different surface conditionings (protective antioxidant paint and graphite powder muffle) were evaluated in regard to gas attack, and compared with non-conditioned specimens. The obtained results showed differences between the studied refractory materials according to the experimental conditions (temperature and time). At the low temperature regimen, pitch-based refractories exhibited the smallest chemical degradation whereas at high temperature, the material bonded with resin was the most resistant to oxygen chemical attack. The analysis of other phenomena related to microstructural changes helps to achieve a description of thermo-chemical processes occurring in the refractory samples during thermal treatments.
Fil: Camerucci, Maria Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Galliano, Pablo German. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Cavalieri, Ana Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Tomba Martinez, Analia Gladys. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
MgO-C REFRACTORIES
BINDER PYROLYSIS
DIRECT OXIDATION
INDIRECT OXIDATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/243675
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/243675
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in AirCamerucci, Maria AndreaGalliano, Pablo GermanCavalieri, Ana LiaTomba Martinez, Analia GladysMgO-C REFRACTORIESBINDER PYROLYSISDIRECT OXIDATIONINDIRECT OXIDATIONhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In this work, the chemical degradation in air of different commercial MgO-C refractories used in the steelmaking industry was studied. Materials were characterized by mineralogical, microstructural, differential thermal and thermo-gravimetric analyses and measurements of density and porosity. Cylindrical samples were subjected to isothermal treatments at different temperatures and times in air and then, the weight loss and percentage of decarburized area were determined. Moreover, different surface conditionings (protective antioxidant paint and graphite powder muffle) were evaluated in regard to gas attack, and compared with non-conditioned specimens. The obtained results showed differences between the studied refractory materials according to the experimental conditions (temperature and time). At the low temperature regimen, pitch-based refractories exhibited the smallest chemical degradation whereas at high temperature, the material bonded with resin was the most resistant to oxygen chemical attack. The analysis of other phenomena related to microstructural changes helps to achieve a description of thermo-chemical processes occurring in the refractory samples during thermal treatments.Fil: Camerucci, Maria Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Galliano, Pablo German. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Cavalieri, Ana Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Tomba Martinez, Analia Gladys. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaVerlag SchmidGmbH2012-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/243675Camerucci, Maria Andrea; Galliano, Pablo German; Cavalieri, Ana Lia; Tomba Martinez, Analia Gladys; Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air; Verlag SchmidGmbH; Interceram; 61; 4; 4-2012; 198-2040020-5214CONICET DigitalCONICETenginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:35Zoai:ri.conicet.gov.ar:11336/243675instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:35.343CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air
title Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air
spellingShingle Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air
Camerucci, Maria Andrea
MgO-C REFRACTORIES
BINDER PYROLYSIS
DIRECT OXIDATION
INDIRECT OXIDATION
title_short Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air
title_full Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air
title_fullStr Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air
title_full_unstemmed Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air
title_sort Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air
dc.creator.none.fl_str_mv Camerucci, Maria Andrea
Galliano, Pablo German
Cavalieri, Ana Lia
Tomba Martinez, Analia Gladys
author Camerucci, Maria Andrea
author_facet Camerucci, Maria Andrea
Galliano, Pablo German
Cavalieri, Ana Lia
Tomba Martinez, Analia Gladys
author_role author
author2 Galliano, Pablo German
Cavalieri, Ana Lia
Tomba Martinez, Analia Gladys
author2_role author
author
author
dc.subject.none.fl_str_mv MgO-C REFRACTORIES
BINDER PYROLYSIS
DIRECT OXIDATION
INDIRECT OXIDATION
topic MgO-C REFRACTORIES
BINDER PYROLYSIS
DIRECT OXIDATION
INDIRECT OXIDATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work, the chemical degradation in air of different commercial MgO-C refractories used in the steelmaking industry was studied. Materials were characterized by mineralogical, microstructural, differential thermal and thermo-gravimetric analyses and measurements of density and porosity. Cylindrical samples were subjected to isothermal treatments at different temperatures and times in air and then, the weight loss and percentage of decarburized area were determined. Moreover, different surface conditionings (protective antioxidant paint and graphite powder muffle) were evaluated in regard to gas attack, and compared with non-conditioned specimens. The obtained results showed differences between the studied refractory materials according to the experimental conditions (temperature and time). At the low temperature regimen, pitch-based refractories exhibited the smallest chemical degradation whereas at high temperature, the material bonded with resin was the most resistant to oxygen chemical attack. The analysis of other phenomena related to microstructural changes helps to achieve a description of thermo-chemical processes occurring in the refractory samples during thermal treatments.
Fil: Camerucci, Maria Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Galliano, Pablo German. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Cavalieri, Ana Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Tomba Martinez, Analia Gladys. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description In this work, the chemical degradation in air of different commercial MgO-C refractories used in the steelmaking industry was studied. Materials were characterized by mineralogical, microstructural, differential thermal and thermo-gravimetric analyses and measurements of density and porosity. Cylindrical samples were subjected to isothermal treatments at different temperatures and times in air and then, the weight loss and percentage of decarburized area were determined. Moreover, different surface conditionings (protective antioxidant paint and graphite powder muffle) were evaluated in regard to gas attack, and compared with non-conditioned specimens. The obtained results showed differences between the studied refractory materials according to the experimental conditions (temperature and time). At the low temperature regimen, pitch-based refractories exhibited the smallest chemical degradation whereas at high temperature, the material bonded with resin was the most resistant to oxygen chemical attack. The analysis of other phenomena related to microstructural changes helps to achieve a description of thermo-chemical processes occurring in the refractory samples during thermal treatments.
publishDate 2012
dc.date.none.fl_str_mv 2012-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/243675
Camerucci, Maria Andrea; Galliano, Pablo German; Cavalieri, Ana Lia; Tomba Martinez, Analia Gladys; Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air; Verlag SchmidGmbH; Interceram; 61; 4; 4-2012; 198-204
0020-5214
CONICET Digital
CONICET
url http://hdl.handle.net/11336/243675
identifier_str_mv Camerucci, Maria Andrea; Galliano, Pablo German; Cavalieri, Ana Lia; Tomba Martinez, Analia Gladys; Chemical Wear of Commercial Magnesia-Carbon Refractory Bricks in Air; Verlag SchmidGmbH; Interceram; 61; 4; 4-2012; 198-204
0020-5214
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Verlag SchmidGmbH
publisher.none.fl_str_mv Verlag SchmidGmbH
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842270087324631040
score 13.13397

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