Potassium Selenocyanate

Autores
Heredia, Adrián Alberto
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Potassium selenocyanate (KSeCN) is an easy-to-handle and readily available reagent. It is crystalline, colorless, highly hygroscopic, and air sensitive. Non-adequate storage may lead to its decomposition. This salt is soluble in protic solvents and non-protic polar solvent such as DMF, DMSO, NMP, and acetonitrile. This reagent is commercially available and seldom prepared in the laboratory. It can be synthesized from metallic selenium and potassium cyanide in hot water or ethanol. Methodologies employing KSeCN as the selenium source in the synthesis of organic selenocyanates and isoselenocyanates are practical and versatile. Because this functional group has a moderate reactivity, its conversion into other functional groups is highly interesting, allowing the formation of new C–Se bonds and the further generation of compounds with significant synthetic, pharmacological, and biological value.
Fil: Heredia, Adrián Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Synthesis
Ksecn
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31226
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31226
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Potassium SelenocyanateHeredia, Adrián AlbertoSynthesisKsecnhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Potassium selenocyanate (KSeCN) is an easy-to-handle and readily available reagent. It is crystalline, colorless, highly hygroscopic, and air sensitive. Non-adequate storage may lead to its decomposition. This salt is soluble in protic solvents and non-protic polar solvent such as DMF, DMSO, NMP, and acetonitrile. This reagent is commercially available and seldom prepared in the laboratory. It can be synthesized from metallic selenium and potassium cyanide in hot water or ethanol. Methodologies employing KSeCN as the selenium source in the synthesis of organic selenocyanates and isoselenocyanates are practical and versatile. Because this functional group has a moderate reactivity, its conversion into other functional groups is highly interesting, allowing the formation of new C–Se bonds and the further generation of compounds with significant synthetic, pharmacological, and biological value.Fil: Heredia, Adrián Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaGeorg Thieme Verlag Kg2014-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31226Potassium Selenocyanate; Georg Thieme Verlag Kg; Synlett; 25; 5; 3-2014; 748-7490936-5214CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.thieme-connect.de/DOI/DOI?10.1055/s-0033-1340638info:eu-repo/semantics/altIdentifier/doi/10.1055/s-0033-1340638info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:17:25Zoai:ri.conicet.gov.ar:11336/31226instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:17:25.44CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Potassium Selenocyanate
title Potassium Selenocyanate
spellingShingle Potassium Selenocyanate
Heredia, Adrián Alberto
Synthesis
Ksecn
title_short Potassium Selenocyanate
title_full Potassium Selenocyanate
title_fullStr Potassium Selenocyanate
title_full_unstemmed Potassium Selenocyanate
title_sort Potassium Selenocyanate
dc.creator.none.fl_str_mv Heredia, Adrián Alberto
author Heredia, Adrián Alberto
author_facet Heredia, Adrián Alberto
author_role author
dc.subject.none.fl_str_mv Synthesis
Ksecn
topic Synthesis
Ksecn
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Potassium selenocyanate (KSeCN) is an easy-to-handle and readily available reagent. It is crystalline, colorless, highly hygroscopic, and air sensitive. Non-adequate storage may lead to its decomposition. This salt is soluble in protic solvents and non-protic polar solvent such as DMF, DMSO, NMP, and acetonitrile. This reagent is commercially available and seldom prepared in the laboratory. It can be synthesized from metallic selenium and potassium cyanide in hot water or ethanol. Methodologies employing KSeCN as the selenium source in the synthesis of organic selenocyanates and isoselenocyanates are practical and versatile. Because this functional group has a moderate reactivity, its conversion into other functional groups is highly interesting, allowing the formation of new C–Se bonds and the further generation of compounds with significant synthetic, pharmacological, and biological value.
Fil: Heredia, Adrián Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description Potassium selenocyanate (KSeCN) is an easy-to-handle and readily available reagent. It is crystalline, colorless, highly hygroscopic, and air sensitive. Non-adequate storage may lead to its decomposition. This salt is soluble in protic solvents and non-protic polar solvent such as DMF, DMSO, NMP, and acetonitrile. This reagent is commercially available and seldom prepared in the laboratory. It can be synthesized from metallic selenium and potassium cyanide in hot water or ethanol. Methodologies employing KSeCN as the selenium source in the synthesis of organic selenocyanates and isoselenocyanates are practical and versatile. Because this functional group has a moderate reactivity, its conversion into other functional groups is highly interesting, allowing the formation of new C–Se bonds and the further generation of compounds with significant synthetic, pharmacological, and biological value.
publishDate 2014
dc.date.none.fl_str_mv 2014-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31226
Potassium Selenocyanate; Georg Thieme Verlag Kg; Synlett; 25; 5; 3-2014; 748-749
0936-5214
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31226
identifier_str_mv Potassium Selenocyanate; Georg Thieme Verlag Kg; Synlett; 25; 5; 3-2014; 748-749
0936-5214
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.thieme-connect.de/DOI/DOI?10.1055/s-0033-1340638
info:eu-repo/semantics/altIdentifier/doi/10.1055/s-0033-1340638
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Georg Thieme Verlag Kg
publisher.none.fl_str_mv Georg Thieme Verlag Kg
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781633559003136
score 12.982451

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