Potassium Selenocyanate
- Autores
- Heredia, Adrián Alberto
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Potassium selenocyanate (KSeCN) is an easy-to-handle and readily available reagent. It is crystalline, colorless, highly hygroscopic, and air sensitive. Non-adequate storage may lead to its decomposition. This salt is soluble in protic solvents and non-protic polar solvent such as DMF, DMSO, NMP, and acetonitrile. This reagent is commercially available and seldom prepared in the laboratory. It can be synthesized from metallic selenium and potassium cyanide in hot water or ethanol. Methodologies employing KSeCN as the selenium source in the synthesis of organic selenocyanates and isoselenocyanates are practical and versatile. Because this functional group has a moderate reactivity, its conversion into other functional groups is highly interesting, allowing the formation of new C–Se bonds and the further generation of compounds with significant synthetic, pharmacological, and biological value.
Fil: Heredia, Adrián Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina - Materia
-
Synthesis
Ksecn - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/31226
Ver los metadatos del registro completo
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CONICET Digital (CONICET) |
spelling |
Potassium SelenocyanateHeredia, Adrián AlbertoSynthesisKsecnhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Potassium selenocyanate (KSeCN) is an easy-to-handle and readily available reagent. It is crystalline, colorless, highly hygroscopic, and air sensitive. Non-adequate storage may lead to its decomposition. This salt is soluble in protic solvents and non-protic polar solvent such as DMF, DMSO, NMP, and acetonitrile. This reagent is commercially available and seldom prepared in the laboratory. It can be synthesized from metallic selenium and potassium cyanide in hot water or ethanol. Methodologies employing KSeCN as the selenium source in the synthesis of organic selenocyanates and isoselenocyanates are practical and versatile. Because this functional group has a moderate reactivity, its conversion into other functional groups is highly interesting, allowing the formation of new C–Se bonds and the further generation of compounds with significant synthetic, pharmacological, and biological value.Fil: Heredia, Adrián Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaGeorg Thieme Verlag Kg2014-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31226Potassium Selenocyanate; Georg Thieme Verlag Kg; Synlett; 25; 5; 3-2014; 748-7490936-5214CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.thieme-connect.de/DOI/DOI?10.1055/s-0033-1340638info:eu-repo/semantics/altIdentifier/doi/10.1055/s-0033-1340638info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:48:25Zoai:ri.conicet.gov.ar:11336/31226instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:48:25.671CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Potassium Selenocyanate |
title |
Potassium Selenocyanate |
spellingShingle |
Potassium Selenocyanate Heredia, Adrián Alberto Synthesis Ksecn |
title_short |
Potassium Selenocyanate |
title_full |
Potassium Selenocyanate |
title_fullStr |
Potassium Selenocyanate |
title_full_unstemmed |
Potassium Selenocyanate |
title_sort |
Potassium Selenocyanate |
dc.creator.none.fl_str_mv |
Heredia, Adrián Alberto |
author |
Heredia, Adrián Alberto |
author_facet |
Heredia, Adrián Alberto |
author_role |
author |
dc.subject.none.fl_str_mv |
Synthesis Ksecn |
topic |
Synthesis Ksecn |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Potassium selenocyanate (KSeCN) is an easy-to-handle and readily available reagent. It is crystalline, colorless, highly hygroscopic, and air sensitive. Non-adequate storage may lead to its decomposition. This salt is soluble in protic solvents and non-protic polar solvent such as DMF, DMSO, NMP, and acetonitrile. This reagent is commercially available and seldom prepared in the laboratory. It can be synthesized from metallic selenium and potassium cyanide in hot water or ethanol. Methodologies employing KSeCN as the selenium source in the synthesis of organic selenocyanates and isoselenocyanates are practical and versatile. Because this functional group has a moderate reactivity, its conversion into other functional groups is highly interesting, allowing the formation of new C–Se bonds and the further generation of compounds with significant synthetic, pharmacological, and biological value. Fil: Heredia, Adrián Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina |
description |
Potassium selenocyanate (KSeCN) is an easy-to-handle and readily available reagent. It is crystalline, colorless, highly hygroscopic, and air sensitive. Non-adequate storage may lead to its decomposition. This salt is soluble in protic solvents and non-protic polar solvent such as DMF, DMSO, NMP, and acetonitrile. This reagent is commercially available and seldom prepared in the laboratory. It can be synthesized from metallic selenium and potassium cyanide in hot water or ethanol. Methodologies employing KSeCN as the selenium source in the synthesis of organic selenocyanates and isoselenocyanates are practical and versatile. Because this functional group has a moderate reactivity, its conversion into other functional groups is highly interesting, allowing the formation of new C–Se bonds and the further generation of compounds with significant synthetic, pharmacological, and biological value. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/31226 Potassium Selenocyanate; Georg Thieme Verlag Kg; Synlett; 25; 5; 3-2014; 748-749 0936-5214 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/31226 |
identifier_str_mv |
Potassium Selenocyanate; Georg Thieme Verlag Kg; Synlett; 25; 5; 3-2014; 748-749 0936-5214 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.thieme-connect.de/DOI/DOI?10.1055/s-0033-1340638 info:eu-repo/semantics/altIdentifier/doi/10.1055/s-0033-1340638 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Georg Thieme Verlag Kg |
publisher.none.fl_str_mv |
Georg Thieme Verlag Kg |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613504250675200 |
score |
13.070432 |