Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics

Autores
Difeo, Mauro César; Rubio Marcos, Fernando; Gibbs, Florencia; Castro, Miriam Susana; Ramajo, Leandro Alfredo
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Here, (K0.44Na0.52Li0.04)(Nb0.9-xTa0.1Sbx)O3 [KNL(N0.9-xTSx)] lead-free ceramics withpotential technological applications are made through B-position substitution on the perovskitestructure by Sb ions. This strategy generates crystal structure changes and stabilizes a tetragonalsymmetry, T, giving place to an orthorhombic (O–T) phase boundary close to room temperature.Specifically, our results establish that an increase in relative volume fractions of the T on the O–Tphase boundary produces an increase in functional properties. More relevantly, this improvement inproperties is accompanied by controlling the grain size. Therefore, an increase in grain size promotesthe increased domain size, favoring more domain wall motion and domain switching. Both effectsresult in an increase in the d33 coefficient. Finally, we believe this work helps to understand the factorsthat determine the improvement in the functional properties of the KNN–based piezoelectric ceramics.
Fil: Difeo, Mauro César. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rubio Marcos, Fernando. Instituto de Cerámica y Vidrio de Madrid; España
Fil: Gibbs, Florencia. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
lead-free piezoelectric
energy harvester
ferroelectric
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/233655
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 CeramicsDifeo, Mauro CésarRubio Marcos, FernandoGibbs, FlorenciaCastro, Miriam SusanaRamajo, Leandro Alfredolead-free piezoelectricenergy harvesterferroelectrichttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Here, (K0.44Na0.52Li0.04)(Nb0.9-xTa0.1Sbx)O3 [KNL(N0.9-xTSx)] lead-free ceramics withpotential technological applications are made through B-position substitution on the perovskitestructure by Sb ions. This strategy generates crystal structure changes and stabilizes a tetragonalsymmetry, T, giving place to an orthorhombic (O–T) phase boundary close to room temperature.Specifically, our results establish that an increase in relative volume fractions of the T on the O–Tphase boundary produces an increase in functional properties. More relevantly, this improvement inproperties is accompanied by controlling the grain size. Therefore, an increase in grain size promotesthe increased domain size, favoring more domain wall motion and domain switching. Both effectsresult in an increase in the d33 coefficient. Finally, we believe this work helps to understand the factorsthat determine the improvement in the functional properties of the KNN–based piezoelectric ceramics.Fil: Difeo, Mauro César. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Rubio Marcos, Fernando. Instituto de Cerámica y Vidrio de Madrid; EspañaFil: Gibbs, Florencia. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaMultidisciplinary Digital Publishing Institute2023-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/233655Difeo, Mauro César; Rubio Marcos, Fernando; Gibbs, Florencia ; Castro, Miriam Susana; Ramajo, Leandro Alfredo; Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics; Multidisciplinary Digital Publishing Institute; Applied Sciences; 13; 992; 3-2023; 1-102076-3417CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2076-3417/13/2/992info:eu-repo/semantics/altIdentifier/doi/10.3390/app13020992info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:43:27Zoai:ri.conicet.gov.ar:11336/233655instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:43:27.833CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics
title Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics
spellingShingle Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics
Difeo, Mauro César
lead-free piezoelectric
energy harvester
ferroelectric
title_short Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics
title_full Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics
title_fullStr Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics
title_full_unstemmed Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics
title_sort Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics
dc.creator.none.fl_str_mv Difeo, Mauro César
Rubio Marcos, Fernando
Gibbs, Florencia
Castro, Miriam Susana
Ramajo, Leandro Alfredo
author Difeo, Mauro César
author_facet Difeo, Mauro César
Rubio Marcos, Fernando
Gibbs, Florencia
Castro, Miriam Susana
Ramajo, Leandro Alfredo
author_role author
author2 Rubio Marcos, Fernando
Gibbs, Florencia
Castro, Miriam Susana
Ramajo, Leandro Alfredo
author2_role author
author
author
author
dc.subject.none.fl_str_mv lead-free piezoelectric
energy harvester
ferroelectric
topic lead-free piezoelectric
energy harvester
ferroelectric
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Here, (K0.44Na0.52Li0.04)(Nb0.9-xTa0.1Sbx)O3 [KNL(N0.9-xTSx)] lead-free ceramics withpotential technological applications are made through B-position substitution on the perovskitestructure by Sb ions. This strategy generates crystal structure changes and stabilizes a tetragonalsymmetry, T, giving place to an orthorhombic (O–T) phase boundary close to room temperature.Specifically, our results establish that an increase in relative volume fractions of the T on the O–Tphase boundary produces an increase in functional properties. More relevantly, this improvement inproperties is accompanied by controlling the grain size. Therefore, an increase in grain size promotesthe increased domain size, favoring more domain wall motion and domain switching. Both effectsresult in an increase in the d33 coefficient. Finally, we believe this work helps to understand the factorsthat determine the improvement in the functional properties of the KNN–based piezoelectric ceramics.
Fil: Difeo, Mauro César. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rubio Marcos, Fernando. Instituto de Cerámica y Vidrio de Madrid; España
Fil: Gibbs, Florencia. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Here, (K0.44Na0.52Li0.04)(Nb0.9-xTa0.1Sbx)O3 [KNL(N0.9-xTSx)] lead-free ceramics withpotential technological applications are made through B-position substitution on the perovskitestructure by Sb ions. This strategy generates crystal structure changes and stabilizes a tetragonalsymmetry, T, giving place to an orthorhombic (O–T) phase boundary close to room temperature.Specifically, our results establish that an increase in relative volume fractions of the T on the O–Tphase boundary produces an increase in functional properties. More relevantly, this improvement inproperties is accompanied by controlling the grain size. Therefore, an increase in grain size promotesthe increased domain size, favoring more domain wall motion and domain switching. Both effectsresult in an increase in the d33 coefficient. Finally, we believe this work helps to understand the factorsthat determine the improvement in the functional properties of the KNN–based piezoelectric ceramics.
publishDate 2023
dc.date.none.fl_str_mv 2023-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/233655
Difeo, Mauro César; Rubio Marcos, Fernando; Gibbs, Florencia ; Castro, Miriam Susana; Ramajo, Leandro Alfredo; Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics; Multidisciplinary Digital Publishing Institute; Applied Sciences; 13; 992; 3-2023; 1-10
2076-3417
CONICET Digital
CONICET
url http://hdl.handle.net/11336/233655
identifier_str_mv Difeo, Mauro César; Rubio Marcos, Fernando; Gibbs, Florencia ; Castro, Miriam Susana; Ramajo, Leandro Alfredo; Effect of Antimony Content on Transition Behavior and Electric Properties of (K0.44Na0.52Li0.04)(Nb0.9−xTa0.10Sbx)O3 Ceramics; Multidisciplinary Digital Publishing Institute; Applied Sciences; 13; 992; 3-2023; 1-10
2076-3417
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2076-3417/13/2/992
info:eu-repo/semantics/altIdentifier/doi/10.3390/app13020992
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842268603200569344
score 13.13397

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