Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics

Autores
Ramajo, Leandro Alfredo; Castro, Miriam Susana; Del Campo, A.; Fernandez, J. F.; Rubio Marcos, F.
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of B-site compositional homogeneity on microstructure, piezoelectric properties and dielectric behaviour of lead-free piezoelectric ceramics, (K0.44Na0.52Li0.04) (Nb0.86Ta0.10Sb0.04)O3, is investigated. The B-site compositional homogeneity is evaluated by using an intermediate precursor obtained by solid state reaction between adequate amounts of Nb2O5, Ta2O5 and Sb2O5, calcined at 1350 °C and attrition milled. The B-site precursor powder is mixed with alkaline carbonates to synthesize perovskite powders and, finally, sinter piezoceramics. X-ray diffraction and Raman spectroscopy reveal the formation of a perovskite phase, although tetragonal tungsten-bronze structure is detected as minor secondary phase. Ceramics processed by using B-site precursor show different crystalline structure as a function of sintering conditions or K/Na ratio. The B-site precursor route produces thus lower piezoelectric properties, but the control of alkali volatilization by using sintering powder bed resulted in a relevant decrease of dielectric losses that favours the d33 enhancement.
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Del Campo, A.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Fernandez, J. F.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Rubio Marcos, F.. Instituto de Ceramica y Vidrio de Madrid; España
Materia
Lead-Free Piezoelectrics
Knl-Nts
Piezoelectric Ceramics
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/10422
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/10422
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramicsRamajo, Leandro AlfredoCastro, Miriam SusanaDel Campo, A.Fernandez, J. F.Rubio Marcos, F.Lead-Free PiezoelectricsKnl-NtsPiezoelectric Ceramicshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The effect of B-site compositional homogeneity on microstructure, piezoelectric properties and dielectric behaviour of lead-free piezoelectric ceramics, (K0.44Na0.52Li0.04) (Nb0.86Ta0.10Sb0.04)O3, is investigated. The B-site compositional homogeneity is evaluated by using an intermediate precursor obtained by solid state reaction between adequate amounts of Nb2O5, Ta2O5 and Sb2O5, calcined at 1350 °C and attrition milled. The B-site precursor powder is mixed with alkaline carbonates to synthesize perovskite powders and, finally, sinter piezoceramics. X-ray diffraction and Raman spectroscopy reveal the formation of a perovskite phase, although tetragonal tungsten-bronze structure is detected as minor secondary phase. Ceramics processed by using B-site precursor show different crystalline structure as a function of sintering conditions or K/Na ratio. The B-site precursor route produces thus lower piezoelectric properties, but the control of alkali volatilization by using sintering powder bed resulted in a relevant decrease of dielectric losses that favours the d33 enhancement.Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Del Campo, A.. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Fernandez, J. F.. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Rubio Marcos, F.. Instituto de Ceramica y Vidrio de Madrid; EspañaElsevier2014-03-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10422Ramajo, Leandro Alfredo; Castro, Miriam Susana; Del Campo, A.; Fernandez, J. F.; Rubio Marcos, F.; Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics; Elsevier; Journal Of The European Ceramic Society; 34; 10; 5-3-2014; 2249-22570955-2219enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jeurceramsoc.2014.02.002info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0955221914000788info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:47:15Zoai:ri.conicet.gov.ar:11336/10422instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:47:15.346CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics
title Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics
spellingShingle Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics
Ramajo, Leandro Alfredo
Lead-Free Piezoelectrics
Knl-Nts
Piezoelectric Ceramics
title_short Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics
title_full Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics
title_fullStr Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics
title_full_unstemmed Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics
title_sort Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics
dc.creator.none.fl_str_mv Ramajo, Leandro Alfredo
Castro, Miriam Susana
Del Campo, A.
Fernandez, J. F.
Rubio Marcos, F.
author Ramajo, Leandro Alfredo
author_facet Ramajo, Leandro Alfredo
Castro, Miriam Susana
Del Campo, A.
Fernandez, J. F.
Rubio Marcos, F.
author_role author
author2 Castro, Miriam Susana
Del Campo, A.
Fernandez, J. F.
Rubio Marcos, F.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Lead-Free Piezoelectrics
Knl-Nts
Piezoelectric Ceramics
topic Lead-Free Piezoelectrics
Knl-Nts
Piezoelectric Ceramics
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The effect of B-site compositional homogeneity on microstructure, piezoelectric properties and dielectric behaviour of lead-free piezoelectric ceramics, (K0.44Na0.52Li0.04) (Nb0.86Ta0.10Sb0.04)O3, is investigated. The B-site compositional homogeneity is evaluated by using an intermediate precursor obtained by solid state reaction between adequate amounts of Nb2O5, Ta2O5 and Sb2O5, calcined at 1350 °C and attrition milled. The B-site precursor powder is mixed with alkaline carbonates to synthesize perovskite powders and, finally, sinter piezoceramics. X-ray diffraction and Raman spectroscopy reveal the formation of a perovskite phase, although tetragonal tungsten-bronze structure is detected as minor secondary phase. Ceramics processed by using B-site precursor show different crystalline structure as a function of sintering conditions or K/Na ratio. The B-site precursor route produces thus lower piezoelectric properties, but the control of alkali volatilization by using sintering powder bed resulted in a relevant decrease of dielectric losses that favours the d33 enhancement.
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Del Campo, A.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Fernandez, J. F.. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Rubio Marcos, F.. Instituto de Ceramica y Vidrio de Madrid; España
description The effect of B-site compositional homogeneity on microstructure, piezoelectric properties and dielectric behaviour of lead-free piezoelectric ceramics, (K0.44Na0.52Li0.04) (Nb0.86Ta0.10Sb0.04)O3, is investigated. The B-site compositional homogeneity is evaluated by using an intermediate precursor obtained by solid state reaction between adequate amounts of Nb2O5, Ta2O5 and Sb2O5, calcined at 1350 °C and attrition milled. The B-site precursor powder is mixed with alkaline carbonates to synthesize perovskite powders and, finally, sinter piezoceramics. X-ray diffraction and Raman spectroscopy reveal the formation of a perovskite phase, although tetragonal tungsten-bronze structure is detected as minor secondary phase. Ceramics processed by using B-site precursor show different crystalline structure as a function of sintering conditions or K/Na ratio. The B-site precursor route produces thus lower piezoelectric properties, but the control of alkali volatilization by using sintering powder bed resulted in a relevant decrease of dielectric losses that favours the d33 enhancement.
publishDate 2014
dc.date.none.fl_str_mv 2014-03-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/10422
Ramajo, Leandro Alfredo; Castro, Miriam Susana; Del Campo, A.; Fernandez, J. F.; Rubio Marcos, F.; Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics; Elsevier; Journal Of The European Ceramic Society; 34; 10; 5-3-2014; 2249-2257
0955-2219
url http://hdl.handle.net/11336/10422
identifier_str_mv Ramajo, Leandro Alfredo; Castro, Miriam Susana; Del Campo, A.; Fernandez, J. F.; Rubio Marcos, F.; Influence of B-site compositional homogeneity on properties of (K0.44Na0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3-based piezoelectric ceramics; Elsevier; Journal Of The European Ceramic Society; 34; 10; 5-3-2014; 2249-2257
0955-2219
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jeurceramsoc.2014.02.002
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0955221914000788
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.976206

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