A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism

Autores
Larregola, Sebastian Alberto; Pedregosa, Jose Carmelo; Algueró, Miguel; Jiménez, Ricardo; García Hernandez, Mar; Fernández Díaz, María T.; Alonso, José A.
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report on the crystal structure evolution and the physical properties of the complex perovskite Pb(Fe0.5Ti0.25W0.25)O3. It presents a paraelectric to ferroelectric transition at TC= 293 K, determined by permittivity measurements. The room-temperature neutron powder diffraction pattern (NPD) shows an admixture of the ferroelectric phase (34%, P4mm space group) and the paraelectric polymorph (66%,  space group). In both polymorphs the perovskite crystal structure contains the three B cations (Fe, Ti, W) distributed at random at the octahedral sites, and Pb is shifted away from the center of the cubic (sub-)cell. On the other hand, the presence of iron drives the appearance of magnetic interactions above room temperature. This is related to the existence of Fe-rich islands where the strong Fe3+-O-Fe3+ superexchange interactions govern the magnetic behavior. The magnetic structure has been determined from low-temperature NPD experiments as a G-type antiferromagnetic (AFM) cell. Furthermore, there is a net magnetization in the entire range of temperature, which is related to the existence of non-compensated spins in each island. The coexistence of ferroelectricity and a magnetically ordered system, and the observation of a possible coupling between both phenomena allow us to suggest the multiferroic-magnetoelectric nature of the sample.
Fil: Larregola, Sebastian Alberto. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Algueró, Miguel. Instituto de Ciencia de Materiales de Madrid; España
Fil: Jiménez, Ricardo. Instituto de Ciencia de Materiales de Madrid; España
Fil: García Hernandez, Mar. Instituto de Ciencia de Materiales de Madrid; España
Fil: Fernández Díaz, María T.. Institute Laue-langevin; Francia
Fil: Alonso, José A.. Instituto de Ciencia de Materiales de Madrid; España
Materia
PEROVSKITE
FERROELECTRIC
MULTIFERROIC
MAGNETOELECTRIC
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/268188
Acceder
id CONICETDig_d3a483db979ca6bd9cb6ef5a707b29af
oai_identifier_str oai:ri.conicet.gov.ar:11336/268188
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetismLarregola, Sebastian AlbertoPedregosa, Jose CarmeloAlgueró, MiguelJiménez, RicardoGarcía Hernandez, MarFernández Díaz, María T.Alonso, José A.PEROVSKITEFERROELECTRICMULTIFERROICMAGNETOELECTRIChttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We report on the crystal structure evolution and the physical properties of the complex perovskite Pb(Fe0.5Ti0.25W0.25)O3. It presents a paraelectric to ferroelectric transition at TC= 293 K, determined by permittivity measurements. The room-temperature neutron powder diffraction pattern (NPD) shows an admixture of the ferroelectric phase (34%, P4mm space group) and the paraelectric polymorph (66%,  space group). In both polymorphs the perovskite crystal structure contains the three B cations (Fe, Ti, W) distributed at random at the octahedral sites, and Pb is shifted away from the center of the cubic (sub-)cell. On the other hand, the presence of iron drives the appearance of magnetic interactions above room temperature. This is related to the existence of Fe-rich islands where the strong Fe3+-O-Fe3+ superexchange interactions govern the magnetic behavior. The magnetic structure has been determined from low-temperature NPD experiments as a G-type antiferromagnetic (AFM) cell. Furthermore, there is a net magnetization in the entire range of temperature, which is related to the existence of non-compensated spins in each island. The coexistence of ferroelectricity and a magnetically ordered system, and the observation of a possible coupling between both phenomena allow us to suggest the multiferroic-magnetoelectric nature of the sample.Fil: Larregola, Sebastian Alberto. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Algueró, Miguel. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Jiménez, Ricardo. Instituto de Ciencia de Materiales de Madrid; EspañaFil: García Hernandez, Mar. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Fernández Díaz, María T.. Institute Laue-langevin; FranciaFil: Alonso, José A.. Instituto de Ciencia de Materiales de Madrid; EspañaAmerican Chemical Society2012-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/268188Larregola, Sebastian Alberto; Pedregosa, Jose Carmelo; Algueró, Miguel; Jiménez, Ricardo; García Hernandez, Mar; et al.; A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism; American Chemical Society; Chemistry Of Materials; 24; 14; 7-2012; 2664-26720897-4756CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/cm300470finfo:eu-repo/semantics/altIdentifier/doi/10.1021/cm300470finfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:30:00Zoai:ri.conicet.gov.ar:11336/268188instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:30:00.308CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism
title A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism
spellingShingle A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism
Larregola, Sebastian Alberto
PEROVSKITE
FERROELECTRIC
MULTIFERROIC
MAGNETOELECTRIC
title_short A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism
title_full A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism
title_fullStr A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism
title_full_unstemmed A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism
title_sort A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism
dc.creator.none.fl_str_mv Larregola, Sebastian Alberto
Pedregosa, Jose Carmelo
Algueró, Miguel
Jiménez, Ricardo
García Hernandez, Mar
Fernández Díaz, María T.
Alonso, José A.
author Larregola, Sebastian Alberto
author_facet Larregola, Sebastian Alberto
Pedregosa, Jose Carmelo
Algueró, Miguel
Jiménez, Ricardo
García Hernandez, Mar
Fernández Díaz, María T.
Alonso, José A.
author_role author
author2 Pedregosa, Jose Carmelo
Algueró, Miguel
Jiménez, Ricardo
García Hernandez, Mar
Fernández Díaz, María T.
Alonso, José A.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv PEROVSKITE
FERROELECTRIC
MULTIFERROIC
MAGNETOELECTRIC
topic PEROVSKITE
FERROELECTRIC
MULTIFERROIC
MAGNETOELECTRIC
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We report on the crystal structure evolution and the physical properties of the complex perovskite Pb(Fe0.5Ti0.25W0.25)O3. It presents a paraelectric to ferroelectric transition at TC= 293 K, determined by permittivity measurements. The room-temperature neutron powder diffraction pattern (NPD) shows an admixture of the ferroelectric phase (34%, P4mm space group) and the paraelectric polymorph (66%,  space group). In both polymorphs the perovskite crystal structure contains the three B cations (Fe, Ti, W) distributed at random at the octahedral sites, and Pb is shifted away from the center of the cubic (sub-)cell. On the other hand, the presence of iron drives the appearance of magnetic interactions above room temperature. This is related to the existence of Fe-rich islands where the strong Fe3+-O-Fe3+ superexchange interactions govern the magnetic behavior. The magnetic structure has been determined from low-temperature NPD experiments as a G-type antiferromagnetic (AFM) cell. Furthermore, there is a net magnetization in the entire range of temperature, which is related to the existence of non-compensated spins in each island. The coexistence of ferroelectricity and a magnetically ordered system, and the observation of a possible coupling between both phenomena allow us to suggest the multiferroic-magnetoelectric nature of the sample.
Fil: Larregola, Sebastian Alberto. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Algueró, Miguel. Instituto de Ciencia de Materiales de Madrid; España
Fil: Jiménez, Ricardo. Instituto de Ciencia de Materiales de Madrid; España
Fil: García Hernandez, Mar. Instituto de Ciencia de Materiales de Madrid; España
Fil: Fernández Díaz, María T.. Institute Laue-langevin; Francia
Fil: Alonso, José A.. Instituto de Ciencia de Materiales de Madrid; España
description We report on the crystal structure evolution and the physical properties of the complex perovskite Pb(Fe0.5Ti0.25W0.25)O3. It presents a paraelectric to ferroelectric transition at TC= 293 K, determined by permittivity measurements. The room-temperature neutron powder diffraction pattern (NPD) shows an admixture of the ferroelectric phase (34%, P4mm space group) and the paraelectric polymorph (66%,  space group). In both polymorphs the perovskite crystal structure contains the three B cations (Fe, Ti, W) distributed at random at the octahedral sites, and Pb is shifted away from the center of the cubic (sub-)cell. On the other hand, the presence of iron drives the appearance of magnetic interactions above room temperature. This is related to the existence of Fe-rich islands where the strong Fe3+-O-Fe3+ superexchange interactions govern the magnetic behavior. The magnetic structure has been determined from low-temperature NPD experiments as a G-type antiferromagnetic (AFM) cell. Furthermore, there is a net magnetization in the entire range of temperature, which is related to the existence of non-compensated spins in each island. The coexistence of ferroelectricity and a magnetically ordered system, and the observation of a possible coupling between both phenomena allow us to suggest the multiferroic-magnetoelectric nature of the sample.
publishDate 2012
dc.date.none.fl_str_mv 2012-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/268188
Larregola, Sebastian Alberto; Pedregosa, Jose Carmelo; Algueró, Miguel; Jiménez, Ricardo; García Hernandez, Mar; et al.; A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism; American Chemical Society; Chemistry Of Materials; 24; 14; 7-2012; 2664-2672
0897-4756
CONICET Digital
CONICET
url http://hdl.handle.net/11336/268188
identifier_str_mv Larregola, Sebastian Alberto; Pedregosa, Jose Carmelo; Algueró, Miguel; Jiménez, Ricardo; García Hernandez, Mar; et al.; A novel near-room-temperature type I multiferroic: Pb(Fe0.5Ti0.25W0.25)O3 with coexistence of ferroelectricity and weak ferromagnetism; American Chemical Society; Chemistry Of Materials; 24; 14; 7-2012; 2664-2672
0897-4756
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/cm300470f
info:eu-repo/semantics/altIdentifier/doi/10.1021/cm300470f
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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