Bioinspired templates for the synthesis of silica nanostructures

Autores
Hassan, Natalia; Soltero, Armando; Pozzo, Danilo; Messina, Paula Verónica; Ruso, Juan M.
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Herein we report a facile method for the preparation of hierarchical silica nanostructures through a biomimetic approach. Toward this goal, a protein-directed approach has been proposed to template silica into 3D architectures through a hydrogel matrix formed from physically cross-linked fibrinogen. The hydrogel matrix has tunable physicochemical properties based on the thermal unfolding of the main domains of the protein. The network structures of the gels that are obtained are quite similar but differ in the mean pore size and rheological properties. These nanopores are then filled with silica precursors, under acidic conditions, where the condensation reaction is initiated. The protein hydrogel template is subsequently removed by calcination. The final materials show two different topologies. The origin of these two topologies lies on the anisotropic shape of the fibrinogen, driving stochastic interactions with the inorganic precursor and thus generating sponge-like (normal interactions) and polygonal fiber (parallel interactions) architectures.
Fil: Hassan, Natalia. Universidad de Santiago de Compostela; España
Fil: Soltero, Armando. Universidad de Guadalajara; México
Fil: Pozzo, Danilo. University of Washington; Estados Unidos
Fil: Messina, Paula Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Ruso, Juan M.. Universidad de Santiago de Compostela; España
Materia
Fibrinogen
Silica Materials
Hydrogels
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/60835
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Bioinspired templates for the synthesis of silica nanostructuresHassan, NataliaSoltero, ArmandoPozzo, DaniloMessina, Paula VerónicaRuso, Juan M.FibrinogenSilica MaterialsHydrogelshttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Herein we report a facile method for the preparation of hierarchical silica nanostructures through a biomimetic approach. Toward this goal, a protein-directed approach has been proposed to template silica into 3D architectures through a hydrogel matrix formed from physically cross-linked fibrinogen. The hydrogel matrix has tunable physicochemical properties based on the thermal unfolding of the main domains of the protein. The network structures of the gels that are obtained are quite similar but differ in the mean pore size and rheological properties. These nanopores are then filled with silica precursors, under acidic conditions, where the condensation reaction is initiated. The protein hydrogel template is subsequently removed by calcination. The final materials show two different topologies. The origin of these two topologies lies on the anisotropic shape of the fibrinogen, driving stochastic interactions with the inorganic precursor and thus generating sponge-like (normal interactions) and polygonal fiber (parallel interactions) architectures.Fil: Hassan, Natalia. Universidad de Santiago de Compostela; EspañaFil: Soltero, Armando. Universidad de Guadalajara; MéxicoFil: Pozzo, Danilo. University of Washington; Estados UnidosFil: Messina, Paula Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Ruso, Juan M.. Universidad de Santiago de Compostela; EspañaRoyal Society of Chemistry2012-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/60835Hassan, Natalia; Soltero, Armando; Pozzo, Danilo; Messina, Paula Verónica; Ruso, Juan M.; Bioinspired templates for the synthesis of silica nanostructures; Royal Society of Chemistry; Soft Matter; 8; 37; 10-2012; 9553-95621744-683XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2012/sm/c2sm26263k#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/c2sm26263kinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:10Zoai:ri.conicet.gov.ar:11336/60835instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:10.978CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Bioinspired templates for the synthesis of silica nanostructures
title Bioinspired templates for the synthesis of silica nanostructures
spellingShingle Bioinspired templates for the synthesis of silica nanostructures
Hassan, Natalia
Fibrinogen
Silica Materials
Hydrogels
title_short Bioinspired templates for the synthesis of silica nanostructures
title_full Bioinspired templates for the synthesis of silica nanostructures
title_fullStr Bioinspired templates for the synthesis of silica nanostructures
title_full_unstemmed Bioinspired templates for the synthesis of silica nanostructures
title_sort Bioinspired templates for the synthesis of silica nanostructures
dc.creator.none.fl_str_mv Hassan, Natalia
Soltero, Armando
Pozzo, Danilo
Messina, Paula Verónica
Ruso, Juan M.
author Hassan, Natalia
author_facet Hassan, Natalia
Soltero, Armando
Pozzo, Danilo
Messina, Paula Verónica
Ruso, Juan M.
author_role author
author2 Soltero, Armando
Pozzo, Danilo
Messina, Paula Verónica
Ruso, Juan M.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Fibrinogen
Silica Materials
Hydrogels
topic Fibrinogen
Silica Materials
Hydrogels
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Herein we report a facile method for the preparation of hierarchical silica nanostructures through a biomimetic approach. Toward this goal, a protein-directed approach has been proposed to template silica into 3D architectures through a hydrogel matrix formed from physically cross-linked fibrinogen. The hydrogel matrix has tunable physicochemical properties based on the thermal unfolding of the main domains of the protein. The network structures of the gels that are obtained are quite similar but differ in the mean pore size and rheological properties. These nanopores are then filled with silica precursors, under acidic conditions, where the condensation reaction is initiated. The protein hydrogel template is subsequently removed by calcination. The final materials show two different topologies. The origin of these two topologies lies on the anisotropic shape of the fibrinogen, driving stochastic interactions with the inorganic precursor and thus generating sponge-like (normal interactions) and polygonal fiber (parallel interactions) architectures.
Fil: Hassan, Natalia. Universidad de Santiago de Compostela; España
Fil: Soltero, Armando. Universidad de Guadalajara; México
Fil: Pozzo, Danilo. University of Washington; Estados Unidos
Fil: Messina, Paula Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Ruso, Juan M.. Universidad de Santiago de Compostela; España
description Herein we report a facile method for the preparation of hierarchical silica nanostructures through a biomimetic approach. Toward this goal, a protein-directed approach has been proposed to template silica into 3D architectures through a hydrogel matrix formed from physically cross-linked fibrinogen. The hydrogel matrix has tunable physicochemical properties based on the thermal unfolding of the main domains of the protein. The network structures of the gels that are obtained are quite similar but differ in the mean pore size and rheological properties. These nanopores are then filled with silica precursors, under acidic conditions, where the condensation reaction is initiated. The protein hydrogel template is subsequently removed by calcination. The final materials show two different topologies. The origin of these two topologies lies on the anisotropic shape of the fibrinogen, driving stochastic interactions with the inorganic precursor and thus generating sponge-like (normal interactions) and polygonal fiber (parallel interactions) architectures.
publishDate 2012
dc.date.none.fl_str_mv 2012-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/60835
Hassan, Natalia; Soltero, Armando; Pozzo, Danilo; Messina, Paula Verónica; Ruso, Juan M.; Bioinspired templates for the synthesis of silica nanostructures; Royal Society of Chemistry; Soft Matter; 8; 37; 10-2012; 9553-9562
1744-683X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/60835
identifier_str_mv Hassan, Natalia; Soltero, Armando; Pozzo, Danilo; Messina, Paula Verónica; Ruso, Juan M.; Bioinspired templates for the synthesis of silica nanostructures; Royal Society of Chemistry; Soft Matter; 8; 37; 10-2012; 9553-9562
1744-683X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2012/sm/c2sm26263k#!divAbstract
info:eu-repo/semantics/altIdentifier/doi/10.1039/c2sm26263k
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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