Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications

Autores
Guaras, Maria Paula; Alvarez, Vera Alejandra; Ludueña, Leandro Nicolas
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Thermoplastic starch (TPS)/polycaprolactone(PCL) blends were obtained by melt mixing. First, thebest formulation of thermoplastic starch (starch, plasticizerand additives) was studied. The obtained filmswere characterized by means of differential scanningcalorimetry, DSC (melting temperature and crystallinitydegree); thermogravimetric analysis, TGA (real compositionof the blend and thermal stability); tensile tests(mechanical properties); infrared spectroscopy, FTIR(interactions between components); scanning electronmicroscopy, SEM (morphology); and water absorptiontests. The effect of PCL/TPS ratio on the previouslymentioned characteristics and properties were studied.In addition, the effect of using PCL modified withmaleic anhydride as compatibilizer was also analyzed.An optimal compatibilizer content was found improvingthe mechanical properties and slowing down thedegradation rate in soil of the blends. On the otherhand, a slight increase in the water absorption of theblends was found in comparison with the noncompatibilizedones.
Fil: Guaras, Maria Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Ludueña, Leandro Nicolas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Thermoplastic-Starch
Polycaprolactone
Grafting
Mechanical-Properties
Biodegradability
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5858
Acceder
id CONICETDig_01d6426e4aea1a0a85f7e69489f5b344
oai_identifier_str oai:ri.conicet.gov.ar:11336/5858
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applicationsGuaras, Maria PaulaAlvarez, Vera AlejandraLudueña, Leandro NicolasThermoplastic-StarchPolycaprolactoneGraftingMechanical-PropertiesBiodegradabilityhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Thermoplastic starch (TPS)/polycaprolactone(PCL) blends were obtained by melt mixing. First, thebest formulation of thermoplastic starch (starch, plasticizerand additives) was studied. The obtained filmswere characterized by means of differential scanningcalorimetry, DSC (melting temperature and crystallinitydegree); thermogravimetric analysis, TGA (real compositionof the blend and thermal stability); tensile tests(mechanical properties); infrared spectroscopy, FTIR(interactions between components); scanning electronmicroscopy, SEM (morphology); and water absorptiontests. The effect of PCL/TPS ratio on the previouslymentioned characteristics and properties were studied.In addition, the effect of using PCL modified withmaleic anhydride as compatibilizer was also analyzed.An optimal compatibilizer content was found improvingthe mechanical properties and slowing down thedegradation rate in soil of the blends. On the otherhand, a slight increase in the water absorption of theblends was found in comparison with the noncompatibilizedones.Fil: Guaras, Maria Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Ludueña, Leandro Nicolas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaSpringer2015-08-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5858Guaras, Maria Paula; Alvarez, Vera Alejandra; Ludueña, Leandro Nicolas; Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications; Springer; Journal Of Polymer Research; 22; 7-8-2015; 165-1771022-9760enginfo:eu-repo/semantics/altIdentifier/issn/1022-9760info:eu-repo/semantics/altIdentifier/doi/10.1007/s10965-015-0817-0info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007%2Fs10965-015-0817-0info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:02:57Zoai:ri.conicet.gov.ar:11336/5858instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:02:58.126CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications
title Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications
spellingShingle Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications
Guaras, Maria Paula
Thermoplastic-Starch
Polycaprolactone
Grafting
Mechanical-Properties
Biodegradability
title_short Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications
title_full Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications
title_fullStr Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications
title_full_unstemmed Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications
title_sort Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications
dc.creator.none.fl_str_mv Guaras, Maria Paula
Alvarez, Vera Alejandra
Ludueña, Leandro Nicolas
author Guaras, Maria Paula
author_facet Guaras, Maria Paula
Alvarez, Vera Alejandra
Ludueña, Leandro Nicolas
author_role author
author2 Alvarez, Vera Alejandra
Ludueña, Leandro Nicolas
author2_role author
author
dc.subject.none.fl_str_mv Thermoplastic-Starch
Polycaprolactone
Grafting
Mechanical-Properties
Biodegradability
topic Thermoplastic-Starch
Polycaprolactone
Grafting
Mechanical-Properties
Biodegradability
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Thermoplastic starch (TPS)/polycaprolactone(PCL) blends were obtained by melt mixing. First, thebest formulation of thermoplastic starch (starch, plasticizerand additives) was studied. The obtained filmswere characterized by means of differential scanningcalorimetry, DSC (melting temperature and crystallinitydegree); thermogravimetric analysis, TGA (real compositionof the blend and thermal stability); tensile tests(mechanical properties); infrared spectroscopy, FTIR(interactions between components); scanning electronmicroscopy, SEM (morphology); and water absorptiontests. The effect of PCL/TPS ratio on the previouslymentioned characteristics and properties were studied.In addition, the effect of using PCL modified withmaleic anhydride as compatibilizer was also analyzed.An optimal compatibilizer content was found improvingthe mechanical properties and slowing down thedegradation rate in soil of the blends. On the otherhand, a slight increase in the water absorption of theblends was found in comparison with the noncompatibilizedones.
Fil: Guaras, Maria Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Ludueña, Leandro Nicolas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description Thermoplastic starch (TPS)/polycaprolactone(PCL) blends were obtained by melt mixing. First, thebest formulation of thermoplastic starch (starch, plasticizerand additives) was studied. The obtained filmswere characterized by means of differential scanningcalorimetry, DSC (melting temperature and crystallinitydegree); thermogravimetric analysis, TGA (real compositionof the blend and thermal stability); tensile tests(mechanical properties); infrared spectroscopy, FTIR(interactions between components); scanning electronmicroscopy, SEM (morphology); and water absorptiontests. The effect of PCL/TPS ratio on the previouslymentioned characteristics and properties were studied.In addition, the effect of using PCL modified withmaleic anhydride as compatibilizer was also analyzed.An optimal compatibilizer content was found improvingthe mechanical properties and slowing down thedegradation rate in soil of the blends. On the otherhand, a slight increase in the water absorption of theblends was found in comparison with the noncompatibilizedones.
publishDate 2015
dc.date.none.fl_str_mv 2015-08-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5858
Guaras, Maria Paula; Alvarez, Vera Alejandra; Ludueña, Leandro Nicolas; Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications; Springer; Journal Of Polymer Research; 22; 7-8-2015; 165-177
1022-9760
url http://hdl.handle.net/11336/5858
identifier_str_mv Guaras, Maria Paula; Alvarez, Vera Alejandra; Ludueña, Leandro Nicolas; Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications; Springer; Journal Of Polymer Research; 22; 7-8-2015; 165-177
1022-9760
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1022-9760
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10965-015-0817-0
info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007%2Fs10965-015-0817-0
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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