Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)

Autores
Giordano, L.; Vermeij, R.J.; Jares-Erijman, E.A.
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This paper reports a synthesis of novel diheteroarylethenes functionalized for coupling to biomolecules starting from indole derivatives. The strategy is based on the derivatization at the N-atom in the indole substructure. TBDMS protection proved to be superior over BOC protection schemes, leading to higher yields in the overall synthesis. The suitability of the new derivatives as acceptors for pcFRET was calculated for selected donors.
Fil:Giordano, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Jares-Erijman, E.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fuente
Arkivoc 2006;2005(12):268-281
Materia
Diheteroarylethenes
FRET
Indole derivatives
Photochromism
Synthesis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/2.5/ar
Repositorio
Biblioteca Digital (UBA-FCEN)
Institución
Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
OAI Identificador
paperaa:paper_14246376_v2005_n12_p268_Giordano
Acceder
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oai_identifier_str paperaa:paper_14246376_v2005_n12_p268_Giordano
network_acronym_str BDUBAFCEN
repository_id_str 1896
network_name_str Biblioteca Digital (UBA-FCEN)
spelling Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)Giordano, L.Vermeij, R.J.Jares-Erijman, E.A.DiheteroarylethenesFRETIndole derivativesPhotochromismSynthesisThis paper reports a synthesis of novel diheteroarylethenes functionalized for coupling to biomolecules starting from indole derivatives. The strategy is based on the derivatization at the N-atom in the indole substructure. TBDMS protection proved to be superior over BOC protection schemes, leading to higher yields in the overall synthesis. The suitability of the new derivatives as acceptors for pcFRET was calculated for selected donors.Fil:Giordano, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Jares-Erijman, E.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.2006info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12110/paper_14246376_v2005_n12_p268_GiordanoArkivoc 2006;2005(12):268-281reponame:Biblioteca Digital (UBA-FCEN)instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesinstacron:UBA-FCENenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/ar2025-09-04T09:48:45Zpaperaa:paper_14246376_v2005_n12_p268_GiordanoInstitucionalhttps://digital.bl.fcen.uba.ar/Universidad públicaNo correspondehttps://digital.bl.fcen.uba.ar/cgi-bin/oaiserver.cgiana@bl.fcen.uba.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:18962025-09-04 09:48:46.429Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesfalse
dc.title.none.fl_str_mv Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
title Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
spellingShingle Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
Giordano, L.
Diheteroarylethenes
FRET
Indole derivatives
Photochromism
Synthesis
title_short Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
title_full Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
title_fullStr Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
title_full_unstemmed Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
title_sort Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
dc.creator.none.fl_str_mv Giordano, L.
Vermeij, R.J.
Jares-Erijman, E.A.
author Giordano, L.
author_facet Giordano, L.
Vermeij, R.J.
Jares-Erijman, E.A.
author_role author
author2 Vermeij, R.J.
Jares-Erijman, E.A.
author2_role author
author
dc.subject.none.fl_str_mv Diheteroarylethenes
FRET
Indole derivatives
Photochromism
Synthesis
topic Diheteroarylethenes
FRET
Indole derivatives
Photochromism
Synthesis
dc.description.none.fl_txt_mv This paper reports a synthesis of novel diheteroarylethenes functionalized for coupling to biomolecules starting from indole derivatives. The strategy is based on the derivatization at the N-atom in the indole substructure. TBDMS protection proved to be superior over BOC protection schemes, leading to higher yields in the overall synthesis. The suitability of the new derivatives as acceptors for pcFRET was calculated for selected donors.
Fil:Giordano, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Jares-Erijman, E.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
description This paper reports a synthesis of novel diheteroarylethenes functionalized for coupling to biomolecules starting from indole derivatives. The strategy is based on the derivatization at the N-atom in the indole substructure. TBDMS protection proved to be superior over BOC protection schemes, leading to higher yields in the overall synthesis. The suitability of the new derivatives as acceptors for pcFRET was calculated for selected donors.
publishDate 2006
dc.date.none.fl_str_mv 2006
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12110/paper_14246376_v2005_n12_p268_Giordano
url http://hdl.handle.net/20.500.12110/paper_14246376_v2005_n12_p268_Giordano
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/2.5/ar
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv Arkivoc 2006;2005(12):268-281
reponame:Biblioteca Digital (UBA-FCEN)
instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron:UBA-FCEN
reponame_str Biblioteca Digital (UBA-FCEN)
collection Biblioteca Digital (UBA-FCEN)
instname_str Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron_str UBA-FCEN
institution UBA-FCEN
repository.name.fl_str_mv Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
repository.mail.fl_str_mv ana@bl.fcen.uba.ar
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score 12.623145

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