Low temperature crystal structure of natural diosgenone
- Autores
- Piro, Oscar Enrique; Castellano, Eduardo Ernesto; Tobón Zapata, Gloria E.; Blair Trujillo, Silvia; Barán, Enrique José
- Año de publicación
- 2002
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The molecular structure of diosgenone, a natural steroidal sapogenin, closely related to diosgenin and isolated from Solanum nudum, was solved by single crystal X-ray diffractometry at 120 K and refined by full-matrix least-squares to an agreement factor, R1 = 0.054. It crystallizes in the monoclinic space group P21, with a = 15.1870(4) Å, b = 7.2710(2) Å, c = 21.2840(6) Å, β = 99.251(1)°, and four molecules in the unit cell (Z = 4). The results constitute the first structural report on a steroidal sapogenin from the diosgenin group.
Facultad de Ciencias Exactas
Centro de Química Inorgánica - Materia
-
Química
Antimalarial Activity
Crystal Structure
Diosgenone - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/83480
Ver los metadatos del registro completo
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Low temperature crystal structure of natural diosgenonePiro, Oscar EnriqueCastellano, Eduardo ErnestoTobón Zapata, Gloria E.Blair Trujillo, SilviaBarán, Enrique JoséQuímicaAntimalarial ActivityCrystal StructureDiosgenoneThe molecular structure of diosgenone, a natural steroidal sapogenin, closely related to diosgenin and isolated from Solanum nudum, was solved by single crystal X-ray diffractometry at 120 K and refined by full-matrix least-squares to an agreement factor, R1 = 0.054. It crystallizes in the monoclinic space group P21, with a = 15.1870(4) Å, b = 7.2710(2) Å, c = 21.2840(6) Å, β = 99.251(1)°, and four molecules in the unit cell (Z = 4). The results constitute the first structural report on a steroidal sapogenin from the diosgenin group.Facultad de Ciencias ExactasCentro de Química Inorgánica2002info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf947-950http://sedici.unlp.edu.ar/handle/10915/83480enginfo:eu-repo/semantics/altIdentifier/issn/0939-5075info:eu-repo/semantics/altIdentifier/doi/10.1515/znc-2002-9-1032info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:15:50Zoai:sedici.unlp.edu.ar:10915/83480Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:15:50.874SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Low temperature crystal structure of natural diosgenone |
title |
Low temperature crystal structure of natural diosgenone |
spellingShingle |
Low temperature crystal structure of natural diosgenone Piro, Oscar Enrique Química Antimalarial Activity Crystal Structure Diosgenone |
title_short |
Low temperature crystal structure of natural diosgenone |
title_full |
Low temperature crystal structure of natural diosgenone |
title_fullStr |
Low temperature crystal structure of natural diosgenone |
title_full_unstemmed |
Low temperature crystal structure of natural diosgenone |
title_sort |
Low temperature crystal structure of natural diosgenone |
dc.creator.none.fl_str_mv |
Piro, Oscar Enrique Castellano, Eduardo Ernesto Tobón Zapata, Gloria E. Blair Trujillo, Silvia Barán, Enrique José |
author |
Piro, Oscar Enrique |
author_facet |
Piro, Oscar Enrique Castellano, Eduardo Ernesto Tobón Zapata, Gloria E. Blair Trujillo, Silvia Barán, Enrique José |
author_role |
author |
author2 |
Castellano, Eduardo Ernesto Tobón Zapata, Gloria E. Blair Trujillo, Silvia Barán, Enrique José |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Química Antimalarial Activity Crystal Structure Diosgenone |
topic |
Química Antimalarial Activity Crystal Structure Diosgenone |
dc.description.none.fl_txt_mv |
The molecular structure of diosgenone, a natural steroidal sapogenin, closely related to diosgenin and isolated from Solanum nudum, was solved by single crystal X-ray diffractometry at 120 K and refined by full-matrix least-squares to an agreement factor, R1 = 0.054. It crystallizes in the monoclinic space group P21, with a = 15.1870(4) Å, b = 7.2710(2) Å, c = 21.2840(6) Å, β = 99.251(1)°, and four molecules in the unit cell (Z = 4). The results constitute the first structural report on a steroidal sapogenin from the diosgenin group. Facultad de Ciencias Exactas Centro de Química Inorgánica |
description |
The molecular structure of diosgenone, a natural steroidal sapogenin, closely related to diosgenin and isolated from Solanum nudum, was solved by single crystal X-ray diffractometry at 120 K and refined by full-matrix least-squares to an agreement factor, R1 = 0.054. It crystallizes in the monoclinic space group P21, with a = 15.1870(4) Å, b = 7.2710(2) Å, c = 21.2840(6) Å, β = 99.251(1)°, and four molecules in the unit cell (Z = 4). The results constitute the first structural report on a steroidal sapogenin from the diosgenin group. |
publishDate |
2002 |
dc.date.none.fl_str_mv |
2002 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/83480 |
url |
http://sedici.unlp.edu.ar/handle/10915/83480 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/0939-5075 info:eu-repo/semantics/altIdentifier/doi/10.1515/znc-2002-9-1032 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
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openAccess |
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http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
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application/pdf 947-950 |
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