Low temperature crystal structure of natural diosgenone

Autores
Piro, Oscar Enrique; Castellano, Eduardo Ernesto; Tobón Zapata, Gloria E.; Blair Trujillo, Silvia; Barán, Enrique José
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The molecular structure of diosgenone, a natural steroidal sapogenin, closely related to diosgenin and isolated from Solanum nudum, was solved by single crystal X-ray diffractometry at 120 K and refined by full-matrix least-squares to an agreement factor, R1 = 0.054. It crystallizes in the monoclinic space group P21, with a = 15.1870(4) Å, b = 7.2710(2) Å, c = 21.2840(6) Å, β = 99.251(1)°, and four molecules in the unit cell (Z = 4). The results constitute the first structural report on a steroidal sapogenin from the diosgenin group.
Facultad de Ciencias Exactas
Centro de Química Inorgánica
Materia
Química
Antimalarial Activity
Crystal Structure
Diosgenone
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/83480

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network_name_str SEDICI (UNLP)
spelling Low temperature crystal structure of natural diosgenonePiro, Oscar EnriqueCastellano, Eduardo ErnestoTobón Zapata, Gloria E.Blair Trujillo, SilviaBarán, Enrique JoséQuímicaAntimalarial ActivityCrystal StructureDiosgenoneThe molecular structure of diosgenone, a natural steroidal sapogenin, closely related to diosgenin and isolated from Solanum nudum, was solved by single crystal X-ray diffractometry at 120 K and refined by full-matrix least-squares to an agreement factor, R1 = 0.054. It crystallizes in the monoclinic space group P21, with a = 15.1870(4) Å, b = 7.2710(2) Å, c = 21.2840(6) Å, β = 99.251(1)°, and four molecules in the unit cell (Z = 4). The results constitute the first structural report on a steroidal sapogenin from the diosgenin group.Facultad de Ciencias ExactasCentro de Química Inorgánica2002info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf947-950http://sedici.unlp.edu.ar/handle/10915/83480enginfo:eu-repo/semantics/altIdentifier/issn/0939-5075info:eu-repo/semantics/altIdentifier/doi/10.1515/znc-2002-9-1032info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:15:50Zoai:sedici.unlp.edu.ar:10915/83480Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:15:50.874SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Low temperature crystal structure of natural diosgenone
title Low temperature crystal structure of natural diosgenone
spellingShingle Low temperature crystal structure of natural diosgenone
Piro, Oscar Enrique
Química
Antimalarial Activity
Crystal Structure
Diosgenone
title_short Low temperature crystal structure of natural diosgenone
title_full Low temperature crystal structure of natural diosgenone
title_fullStr Low temperature crystal structure of natural diosgenone
title_full_unstemmed Low temperature crystal structure of natural diosgenone
title_sort Low temperature crystal structure of natural diosgenone
dc.creator.none.fl_str_mv Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Tobón Zapata, Gloria E.
Blair Trujillo, Silvia
Barán, Enrique José
author Piro, Oscar Enrique
author_facet Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Tobón Zapata, Gloria E.
Blair Trujillo, Silvia
Barán, Enrique José
author_role author
author2 Castellano, Eduardo Ernesto
Tobón Zapata, Gloria E.
Blair Trujillo, Silvia
Barán, Enrique José
author2_role author
author
author
author
dc.subject.none.fl_str_mv Química
Antimalarial Activity
Crystal Structure
Diosgenone
topic Química
Antimalarial Activity
Crystal Structure
Diosgenone
dc.description.none.fl_txt_mv The molecular structure of diosgenone, a natural steroidal sapogenin, closely related to diosgenin and isolated from Solanum nudum, was solved by single crystal X-ray diffractometry at 120 K and refined by full-matrix least-squares to an agreement factor, R1 = 0.054. It crystallizes in the monoclinic space group P21, with a = 15.1870(4) Å, b = 7.2710(2) Å, c = 21.2840(6) Å, β = 99.251(1)°, and four molecules in the unit cell (Z = 4). The results constitute the first structural report on a steroidal sapogenin from the diosgenin group.
Facultad de Ciencias Exactas
Centro de Química Inorgánica
description The molecular structure of diosgenone, a natural steroidal sapogenin, closely related to diosgenin and isolated from Solanum nudum, was solved by single crystal X-ray diffractometry at 120 K and refined by full-matrix least-squares to an agreement factor, R1 = 0.054. It crystallizes in the monoclinic space group P21, with a = 15.1870(4) Å, b = 7.2710(2) Å, c = 21.2840(6) Å, β = 99.251(1)°, and four molecules in the unit cell (Z = 4). The results constitute the first structural report on a steroidal sapogenin from the diosgenin group.
publishDate 2002
dc.date.none.fl_str_mv 2002
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
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info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/83480
url http://sedici.unlp.edu.ar/handle/10915/83480
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0939-5075
info:eu-repo/semantics/altIdentifier/doi/10.1515/znc-2002-9-1032
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
947-950
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reponame_str SEDICI (UNLP)
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