A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate

Autores
Etcheverry, Susana Beatriz; Williams, Patricia Ana María; Baran, Enrique José
Año de publicación
1996
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The interaction of the vanadyl (IV) cation with N-acetyl-D-galactosamine, D-galactosamine, and D-glucuronic acid has been investigated by electron absorption spectroscopy at different mental to ligand ratios and pH values. In the case of D-glucuronic acid, a more detailed study was undertaken, using differential IR spectroscopy in solution. The results show that the cation interacts with the two nitrogenated molecules only at higher pH values, generating 2∶1 lig-and to metal complexes in which coordination occurs through two pairs of deprotonated OH groups of the rings. In the case of D-glucuronic acid, the IR-measurements allowed a wider insight into the structural characteristics of the complexes generated in acidic media. The involvement of the glycosidic oxygen atom in coordination, is suggested at pH=3.
Facultad de Ciencias Exactas
Materia
Química
D-glucuronic acid interactions
Infrared and electronic spectra
Coordination properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/143601
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/143601
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfateEtcheverry, Susana BeatrizWilliams, Patricia Ana MaríaBaran, Enrique JoséQuímicaD-glucuronic acid interactionsInfrared and electronic spectraCoordination propertiesThe interaction of the vanadyl (IV) cation with N-acetyl-D-galactosamine, D-galactosamine, and D-glucuronic acid has been investigated by electron absorption spectroscopy at different mental to ligand ratios and pH values. In the case of D-glucuronic acid, a more detailed study was undertaken, using differential IR spectroscopy in solution. The results show that the cation interacts with the two nitrogenated molecules only at higher pH values, generating 2∶1 lig-and to metal complexes in which coordination occurs through two pairs of deprotonated OH groups of the rings. In the case of D-glucuronic acid, the IR-measurements allowed a wider insight into the structural characteristics of the complexes generated in acidic media. The involvement of the glycosidic oxygen atom in coordination, is suggested at pH=3.Facultad de Ciencias Exactas1996info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf169-176http://sedici.unlp.edu.ar/handle/10915/143601enginfo:eu-repo/semantics/altIdentifier/issn/0163-4984info:eu-repo/semantics/altIdentifier/issn/1559-0720info:eu-repo/semantics/altIdentifier/doi/10.1007/bf02785436info:eu-repo/semantics/altIdentifier/pmid/8907020info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-11-05T13:11:31Zoai:sedici.unlp.edu.ar:10915/143601Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-11-05 13:11:32.175SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate
title A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate
spellingShingle A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate
Etcheverry, Susana Beatriz
Química
D-glucuronic acid interactions
Infrared and electronic spectra
Coordination properties
title_short A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate
title_full A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate
title_fullStr A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate
title_full_unstemmed A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate
title_sort A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate
dc.creator.none.fl_str_mv Etcheverry, Susana Beatriz
Williams, Patricia Ana María
Baran, Enrique José
author Etcheverry, Susana Beatriz
author_facet Etcheverry, Susana Beatriz
Williams, Patricia Ana María
Baran, Enrique José
author_role author
author2 Williams, Patricia Ana María
Baran, Enrique José
author2_role author
author
dc.subject.none.fl_str_mv Química
D-glucuronic acid interactions
Infrared and electronic spectra
Coordination properties
topic Química
D-glucuronic acid interactions
Infrared and electronic spectra
Coordination properties
dc.description.none.fl_txt_mv The interaction of the vanadyl (IV) cation with N-acetyl-D-galactosamine, D-galactosamine, and D-glucuronic acid has been investigated by electron absorption spectroscopy at different mental to ligand ratios and pH values. In the case of D-glucuronic acid, a more detailed study was undertaken, using differential IR spectroscopy in solution. The results show that the cation interacts with the two nitrogenated molecules only at higher pH values, generating 2∶1 lig-and to metal complexes in which coordination occurs through two pairs of deprotonated OH groups of the rings. In the case of D-glucuronic acid, the IR-measurements allowed a wider insight into the structural characteristics of the complexes generated in acidic media. The involvement of the glycosidic oxygen atom in coordination, is suggested at pH=3.
Facultad de Ciencias Exactas
description The interaction of the vanadyl (IV) cation with N-acetyl-D-galactosamine, D-galactosamine, and D-glucuronic acid has been investigated by electron absorption spectroscopy at different mental to ligand ratios and pH values. In the case of D-glucuronic acid, a more detailed study was undertaken, using differential IR spectroscopy in solution. The results show that the cation interacts with the two nitrogenated molecules only at higher pH values, generating 2∶1 lig-and to metal complexes in which coordination occurs through two pairs of deprotonated OH groups of the rings. In the case of D-glucuronic acid, the IR-measurements allowed a wider insight into the structural characteristics of the complexes generated in acidic media. The involvement of the glycosidic oxygen atom in coordination, is suggested at pH=3.
publishDate 1996
dc.date.none.fl_str_mv 1996
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/143601
url http://sedici.unlp.edu.ar/handle/10915/143601
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0163-4984
info:eu-repo/semantics/altIdentifier/issn/1559-0720
info:eu-repo/semantics/altIdentifier/doi/10.1007/bf02785436
info:eu-repo/semantics/altIdentifier/pmid/8907020
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
169-176
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.142177

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