On the Hydrides of B, C, N, O and F
- Autores
- Bucknum, Michael J.; Castro, Eduardo Alberto
- Año de publicación
- 2011
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- This paper reports a productive discussion of bonding principles in the non-metallic 2nd row hydrides. It suggests the inversion of a bonding character, potentially from hydrides of B & C, which may display unsaturation and electronic deficiency accompanied by electronic delocalization in 1D or 2D or 3D. Contrasted with the opposite possibility, within the finite number of hydrides of N, O and F, that display apparently extensive H-bonding and subsequently proton delocalization in 1D and 2D (in HF & ice polymorphs, respectively), and now potentially in 3D in a corresponding hydride of N called Rice's blue material, or perhaps polyimidogen. Where polyimidogen is a crystalline NH lattice that is a polymorph of the ammonium azide structure-type thus.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas - Materia
-
Química
Delocalization in 1D-2D & 3D
Hydrides
H-bonding
Resonance - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/3.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/124076
Ver los metadatos del registro completo
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On the Hydrides of B, C, N, O and FBucknum, Michael J.Castro, Eduardo AlbertoQuímicaDelocalization in 1D-2D & 3DHydridesH-bondingResonanceThis paper reports a productive discussion of bonding principles in the non-metallic 2nd row hydrides. It suggests the inversion of a bonding character, potentially from hydrides of B & C, which may display unsaturation and electronic deficiency accompanied by electronic delocalization in 1D or 2D or 3D. Contrasted with the opposite possibility, within the finite number of hydrides of N, O and F, that display apparently extensive H-bonding and subsequently proton delocalization in 1D and 2D (in HF & ice polymorphs, respectively), and now potentially in 3D in a corresponding hydride of N called Rice's blue material, or perhaps polyimidogen. Where polyimidogen is a crystalline NH lattice that is a polymorph of the ammonium azide structure-type thus.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2011info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/124076enginfo:eu-repo/semantics/altIdentifier/issn/1756-0357info:eu-repo/semantics/altIdentifier/doi/10.1038/npre.2011.2541.3info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/3.0/Creative Commons Attribution 3.0 Unported (CC BY 3.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-29T15:34:29Zoai:sedici.unlp.edu.ar:10915/124076Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-29 15:34:29.482SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
On the Hydrides of B, C, N, O and F |
| title |
On the Hydrides of B, C, N, O and F |
| spellingShingle |
On the Hydrides of B, C, N, O and F Bucknum, Michael J. Química Delocalization in 1D-2D & 3D Hydrides H-bonding Resonance |
| title_short |
On the Hydrides of B, C, N, O and F |
| title_full |
On the Hydrides of B, C, N, O and F |
| title_fullStr |
On the Hydrides of B, C, N, O and F |
| title_full_unstemmed |
On the Hydrides of B, C, N, O and F |
| title_sort |
On the Hydrides of B, C, N, O and F |
| dc.creator.none.fl_str_mv |
Bucknum, Michael J. Castro, Eduardo Alberto |
| author |
Bucknum, Michael J. |
| author_facet |
Bucknum, Michael J. Castro, Eduardo Alberto |
| author_role |
author |
| author2 |
Castro, Eduardo Alberto |
| author2_role |
author |
| dc.subject.none.fl_str_mv |
Química Delocalization in 1D-2D & 3D Hydrides H-bonding Resonance |
| topic |
Química Delocalization in 1D-2D & 3D Hydrides H-bonding Resonance |
| dc.description.none.fl_txt_mv |
This paper reports a productive discussion of bonding principles in the non-metallic 2nd row hydrides. It suggests the inversion of a bonding character, potentially from hydrides of B & C, which may display unsaturation and electronic deficiency accompanied by electronic delocalization in 1D or 2D or 3D. Contrasted with the opposite possibility, within the finite number of hydrides of N, O and F, that display apparently extensive H-bonding and subsequently proton delocalization in 1D and 2D (in HF & ice polymorphs, respectively), and now potentially in 3D in a corresponding hydride of N called Rice's blue material, or perhaps polyimidogen. Where polyimidogen is a crystalline NH lattice that is a polymorph of the ammonium azide structure-type thus. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
| description |
This paper reports a productive discussion of bonding principles in the non-metallic 2nd row hydrides. It suggests the inversion of a bonding character, potentially from hydrides of B & C, which may display unsaturation and electronic deficiency accompanied by electronic delocalization in 1D or 2D or 3D. Contrasted with the opposite possibility, within the finite number of hydrides of N, O and F, that display apparently extensive H-bonding and subsequently proton delocalization in 1D and 2D (in HF & ice polymorphs, respectively), and now potentially in 3D in a corresponding hydride of N called Rice's blue material, or perhaps polyimidogen. Where polyimidogen is a crystalline NH lattice that is a polymorph of the ammonium azide structure-type thus. |
| publishDate |
2011 |
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2011 |
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eng |
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info:eu-repo/semantics/altIdentifier/issn/1756-0357 info:eu-repo/semantics/altIdentifier/doi/10.1038/npre.2011.2541.3 |
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