Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde
- Autores
- Bertolini, Guillermo Ramón; Vetere, Virginia; Gallo, María Angélica; Muñoz, Mercedes; Casella, Mónica Laura; Gambaro, Luis Alberto; Cabello, Carmen Inés
- Año de publicación
- 2016
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- New composites based on the [RhMo6O24H6]3− (RhMo6) heteropolyanion supported on pillared (PILC), heterostructured (PCH) and functionalized(PILC-F) and (PCH-F) systems based on clays were prepared, characterized and tested as catalysts in the liquid-phase hydrogenation of cinnamaldehyde. The original phases and supported systems were characterized using several techniques such as powder X-ray diffraction (XRD), scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM–EDS), Raman microprobe studies, X-ray photoelectron spectroscopy (XPS), thermogravimetry and differential thermal analyses (TG-DSC), temperature programmed reduction (TPR), and textural analysis (BET method), which confirmed their functionalization, physicochemical modification and the nature of Mo adsorbed species. Active acidic, basic and redox sites were determined by temperature programmed surface reaction (TPSR). Mo loading reached 7 wt% for the system RhMo6/PCH-F and 3 wt% for the system RhMo6/PILC-F, while unfunctionalized clay systems showed a value of 1 wt% of Mo. The catalytic performance showed that PCH-based composites were the most active and reached up to 56% conversion at 360 min of reaction when tested in liquid-phase cinnamaldehyde hydrogenation. The selectivity for all the systems was mainly toward hydrocinnamic aldehyde (HCAL) and reached 77% for the RhMo6/PCH-F catalyst at 25% conversion.
Facultad de Ingeniería
Centro de Investigación y Desarrollo en Ciencias Aplicadas
Facultad de Ciencias Exactas - Materia
-
Ingeniería
Ciencias Exactas
Chemical modification
Cinnamaldehyde
Clays
Composites
Liquid-phase hydrogenation
Rh(III)-heteropolymolybdates - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/85930
Ver los metadatos del registro completo
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Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehydeBertolini, Guillermo RamónVetere, VirginiaGallo, María AngélicaMuñoz, MercedesCasella, Mónica LauraGambaro, Luis AlbertoCabello, Carmen InésIngenieríaCiencias ExactasChemical modificationCinnamaldehydeClaysCompositesLiquid-phase hydrogenationRh(III)-heteropolymolybdatesNew composites based on the [RhMo<SUB>6</SUB>O<SUB>24</SUB>H<SUB>6</SUB>]<SUP>3−</SUP> (RhMo<SUB>6</SUB>) heteropolyanion supported on pillared (PILC), heterostructured (PCH) and functionalized(PILC-F) and (PCH-F) systems based on clays were prepared, characterized and tested as catalysts in the liquid-phase hydrogenation of cinnamaldehyde. The original phases and supported systems were characterized using several techniques such as powder X-ray diffraction (XRD), scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM–EDS), Raman microprobe studies, X-ray photoelectron spectroscopy (XPS), thermogravimetry and differential thermal analyses (TG-DSC), temperature programmed reduction (TPR), and textural analysis (BET method), which confirmed their functionalization, physicochemical modification and the nature of Mo adsorbed species. Active acidic, basic and redox sites were determined by temperature programmed surface reaction (TPSR). Mo loading reached 7 wt% for the system RhMo<SUB>6</SUB>/PCH-F and 3 wt% for the system RhMo<SUB>6</SUB>/PILC-F, while unfunctionalized clay systems showed a value of 1 wt% of Mo. The catalytic performance showed that PCH-based composites were the most active and reached up to 56% conversion at 360 min of reaction when tested in liquid-phase cinnamaldehyde hydrogenation. The selectivity for all the systems was mainly toward hydrocinnamic aldehyde (HCAL) and reached 77% for the RhMo<SUB>6</SUB>/PCH-F catalyst at 25% conversion.Facultad de IngenieríaCentro de Investigación y Desarrollo en Ciencias AplicadasFacultad de Ciencias Exactas2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1174-1183http://sedici.unlp.edu.ar/handle/10915/85930enginfo:eu-repo/semantics/altIdentifier/issn/1631-0748info:eu-repo/semantics/altIdentifier/doi/10.1016/j.crci.2015.09.015info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:16:44Zoai:sedici.unlp.edu.ar:10915/85930Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:16:44.632SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde |
title |
Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde |
spellingShingle |
Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde Bertolini, Guillermo Ramón Ingeniería Ciencias Exactas Chemical modification Cinnamaldehyde Clays Composites Liquid-phase hydrogenation Rh(III)-heteropolymolybdates |
title_short |
Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde |
title_full |
Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde |
title_fullStr |
Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde |
title_full_unstemmed |
Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde |
title_sort |
Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde |
dc.creator.none.fl_str_mv |
Bertolini, Guillermo Ramón Vetere, Virginia Gallo, María Angélica Muñoz, Mercedes Casella, Mónica Laura Gambaro, Luis Alberto Cabello, Carmen Inés |
author |
Bertolini, Guillermo Ramón |
author_facet |
Bertolini, Guillermo Ramón Vetere, Virginia Gallo, María Angélica Muñoz, Mercedes Casella, Mónica Laura Gambaro, Luis Alberto Cabello, Carmen Inés |
author_role |
author |
author2 |
Vetere, Virginia Gallo, María Angélica Muñoz, Mercedes Casella, Mónica Laura Gambaro, Luis Alberto Cabello, Carmen Inés |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
Ingeniería Ciencias Exactas Chemical modification Cinnamaldehyde Clays Composites Liquid-phase hydrogenation Rh(III)-heteropolymolybdates |
topic |
Ingeniería Ciencias Exactas Chemical modification Cinnamaldehyde Clays Composites Liquid-phase hydrogenation Rh(III)-heteropolymolybdates |
dc.description.none.fl_txt_mv |
New composites based on the [RhMo<SUB>6</SUB>O<SUB>24</SUB>H<SUB>6</SUB>]<SUP>3−</SUP> (RhMo<SUB>6</SUB>) heteropolyanion supported on pillared (PILC), heterostructured (PCH) and functionalized(PILC-F) and (PCH-F) systems based on clays were prepared, characterized and tested as catalysts in the liquid-phase hydrogenation of cinnamaldehyde. The original phases and supported systems were characterized using several techniques such as powder X-ray diffraction (XRD), scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM–EDS), Raman microprobe studies, X-ray photoelectron spectroscopy (XPS), thermogravimetry and differential thermal analyses (TG-DSC), temperature programmed reduction (TPR), and textural analysis (BET method), which confirmed their functionalization, physicochemical modification and the nature of Mo adsorbed species. Active acidic, basic and redox sites were determined by temperature programmed surface reaction (TPSR). Mo loading reached 7 wt% for the system RhMo<SUB>6</SUB>/PCH-F and 3 wt% for the system RhMo<SUB>6</SUB>/PILC-F, while unfunctionalized clay systems showed a value of 1 wt% of Mo. The catalytic performance showed that PCH-based composites were the most active and reached up to 56% conversion at 360 min of reaction when tested in liquid-phase cinnamaldehyde hydrogenation. The selectivity for all the systems was mainly toward hydrocinnamic aldehyde (HCAL) and reached 77% for the RhMo<SUB>6</SUB>/PCH-F catalyst at 25% conversion. Facultad de Ingeniería Centro de Investigación y Desarrollo en Ciencias Aplicadas Facultad de Ciencias Exactas |
description |
New composites based on the [RhMo<SUB>6</SUB>O<SUB>24</SUB>H<SUB>6</SUB>]<SUP>3−</SUP> (RhMo<SUB>6</SUB>) heteropolyanion supported on pillared (PILC), heterostructured (PCH) and functionalized(PILC-F) and (PCH-F) systems based on clays were prepared, characterized and tested as catalysts in the liquid-phase hydrogenation of cinnamaldehyde. The original phases and supported systems were characterized using several techniques such as powder X-ray diffraction (XRD), scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM–EDS), Raman microprobe studies, X-ray photoelectron spectroscopy (XPS), thermogravimetry and differential thermal analyses (TG-DSC), temperature programmed reduction (TPR), and textural analysis (BET method), which confirmed their functionalization, physicochemical modification and the nature of Mo adsorbed species. Active acidic, basic and redox sites were determined by temperature programmed surface reaction (TPSR). Mo loading reached 7 wt% for the system RhMo<SUB>6</SUB>/PCH-F and 3 wt% for the system RhMo<SUB>6</SUB>/PILC-F, while unfunctionalized clay systems showed a value of 1 wt% of Mo. The catalytic performance showed that PCH-based composites were the most active and reached up to 56% conversion at 360 min of reaction when tested in liquid-phase cinnamaldehyde hydrogenation. The selectivity for all the systems was mainly toward hydrocinnamic aldehyde (HCAL) and reached 77% for the RhMo<SUB>6</SUB>/PCH-F catalyst at 25% conversion. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/85930 |
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http://sedici.unlp.edu.ar/handle/10915/85930 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/1631-0748 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.crci.2015.09.015 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
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openAccess |
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http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
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application/pdf 1174-1183 |
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