Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde

Autores
Bertolini, Guillermo Ramón; Vetere, Virginia; Gallo, María Angélica; Muñoz, Mercedes; Casella, Mónica Laura; Gambaro, Luis Alberto; Cabello, Carmen Inés
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
New composites based on the [RhMo6O24H6]3− (RhMo6) heteropolyanion supported on pillared (PILC), heterostructured (PCH) and functionalized(PILC-F) and (PCH-F) systems based on clays were prepared, characterized and tested as catalysts in the liquid-phase hydrogenation of cinnamaldehyde. The original phases and supported systems were characterized using several techniques such as powder X-ray diffraction (XRD), scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM–EDS), Raman microprobe studies, X-ray photoelectron spectroscopy (XPS), thermogravimetry and differential thermal analyses (TG-DSC), temperature programmed reduction (TPR), and textural analysis (BET method), which confirmed their functionalization, physicochemical modification and the nature of Mo adsorbed species. Active acidic, basic and redox sites were determined by temperature programmed surface reaction (TPSR). Mo loading reached 7 wt% for the system RhMo6/PCH-F and 3 wt% for the system RhMo6/PILC-F, while unfunctionalized clay systems showed a value of 1 wt% of Mo. The catalytic performance showed that PCH-based composites were the most active and reached up to 56% conversion at 360 min of reaction when tested in liquid-phase cinnamaldehyde hydrogenation. The selectivity for all the systems was mainly toward hydrocinnamic aldehyde (HCAL) and reached 77% for the RhMo6/PCH-F catalyst at 25% conversion.
Facultad de Ingeniería
Centro de Investigación y Desarrollo en Ciencias Aplicadas
Facultad de Ciencias Exactas
Materia
Ingeniería
Ciencias Exactas
Chemical modification
Cinnamaldehyde
Clays
Composites
Liquid-phase hydrogenation
Rh(III)-heteropolymolybdates
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/85930

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repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehydeBertolini, Guillermo RamónVetere, VirginiaGallo, María AngélicaMuñoz, MercedesCasella, Mónica LauraGambaro, Luis AlbertoCabello, Carmen InésIngenieríaCiencias ExactasChemical modificationCinnamaldehydeClaysCompositesLiquid-phase hydrogenationRh(III)-heteropolymolybdatesNew composites based on the [RhMo<SUB>6</SUB>O<SUB>24</SUB>H<SUB>6</SUB>]<SUP>3−</SUP> (RhMo<SUB>6</SUB>) heteropolyanion supported on pillared (PILC), heterostructured (PCH) and functionalized(PILC-F) and (PCH-F) systems based on clays were prepared, characterized and tested as catalysts in the liquid-phase hydrogenation of cinnamaldehyde. The original phases and supported systems were characterized using several techniques such as powder X-ray diffraction (XRD), scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM–EDS), Raman microprobe studies, X-ray photoelectron spectroscopy (XPS), thermogravimetry and differential thermal analyses (TG-DSC), temperature programmed reduction (TPR), and textural analysis (BET method), which confirmed their functionalization, physicochemical modification and the nature of Mo adsorbed species. Active acidic, basic and redox sites were determined by temperature programmed surface reaction (TPSR). Mo loading reached 7 wt% for the system RhMo<SUB>6</SUB>/PCH-F and 3 wt% for the system RhMo<SUB>6</SUB>/PILC-F, while unfunctionalized clay systems showed a value of 1 wt% of Mo. The catalytic performance showed that PCH-based composites were the most active and reached up to 56% conversion at 360 min of reaction when tested in liquid-phase cinnamaldehyde hydrogenation. The selectivity for all the systems was mainly toward hydrocinnamic aldehyde (HCAL) and reached 77% for the RhMo<SUB>6</SUB>/PCH-F catalyst at 25% conversion.Facultad de IngenieríaCentro de Investigación y Desarrollo en Ciencias AplicadasFacultad de Ciencias Exactas2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1174-1183http://sedici.unlp.edu.ar/handle/10915/85930enginfo:eu-repo/semantics/altIdentifier/issn/1631-0748info:eu-repo/semantics/altIdentifier/doi/10.1016/j.crci.2015.09.015info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:16:44Zoai:sedici.unlp.edu.ar:10915/85930Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:16:44.632SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde
title Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde
spellingShingle Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde
Bertolini, Guillermo Ramón
Ingeniería
Ciencias Exactas
Chemical modification
Cinnamaldehyde
Clays
Composites
Liquid-phase hydrogenation
Rh(III)-heteropolymolybdates
title_short Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde
title_full Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde
title_fullStr Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde
title_full_unstemmed Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde
title_sort Composites based on modified clay assembled Rh(III)–heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde
dc.creator.none.fl_str_mv Bertolini, Guillermo Ramón
Vetere, Virginia
Gallo, María Angélica
Muñoz, Mercedes
Casella, Mónica Laura
Gambaro, Luis Alberto
Cabello, Carmen Inés
author Bertolini, Guillermo Ramón
author_facet Bertolini, Guillermo Ramón
Vetere, Virginia
Gallo, María Angélica
Muñoz, Mercedes
Casella, Mónica Laura
Gambaro, Luis Alberto
Cabello, Carmen Inés
author_role author
author2 Vetere, Virginia
Gallo, María Angélica
Muñoz, Mercedes
Casella, Mónica Laura
Gambaro, Luis Alberto
Cabello, Carmen Inés
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Ingeniería
Ciencias Exactas
Chemical modification
Cinnamaldehyde
Clays
Composites
Liquid-phase hydrogenation
Rh(III)-heteropolymolybdates
topic Ingeniería
Ciencias Exactas
Chemical modification
Cinnamaldehyde
Clays
Composites
Liquid-phase hydrogenation
Rh(III)-heteropolymolybdates
dc.description.none.fl_txt_mv New composites based on the [RhMo<SUB>6</SUB>O<SUB>24</SUB>H<SUB>6</SUB>]<SUP>3−</SUP> (RhMo<SUB>6</SUB>) heteropolyanion supported on pillared (PILC), heterostructured (PCH) and functionalized(PILC-F) and (PCH-F) systems based on clays were prepared, characterized and tested as catalysts in the liquid-phase hydrogenation of cinnamaldehyde. The original phases and supported systems were characterized using several techniques such as powder X-ray diffraction (XRD), scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM–EDS), Raman microprobe studies, X-ray photoelectron spectroscopy (XPS), thermogravimetry and differential thermal analyses (TG-DSC), temperature programmed reduction (TPR), and textural analysis (BET method), which confirmed their functionalization, physicochemical modification and the nature of Mo adsorbed species. Active acidic, basic and redox sites were determined by temperature programmed surface reaction (TPSR). Mo loading reached 7 wt% for the system RhMo<SUB>6</SUB>/PCH-F and 3 wt% for the system RhMo<SUB>6</SUB>/PILC-F, while unfunctionalized clay systems showed a value of 1 wt% of Mo. The catalytic performance showed that PCH-based composites were the most active and reached up to 56% conversion at 360 min of reaction when tested in liquid-phase cinnamaldehyde hydrogenation. The selectivity for all the systems was mainly toward hydrocinnamic aldehyde (HCAL) and reached 77% for the RhMo<SUB>6</SUB>/PCH-F catalyst at 25% conversion.
Facultad de Ingeniería
Centro de Investigación y Desarrollo en Ciencias Aplicadas
Facultad de Ciencias Exactas
description New composites based on the [RhMo<SUB>6</SUB>O<SUB>24</SUB>H<SUB>6</SUB>]<SUP>3−</SUP> (RhMo<SUB>6</SUB>) heteropolyanion supported on pillared (PILC), heterostructured (PCH) and functionalized(PILC-F) and (PCH-F) systems based on clays were prepared, characterized and tested as catalysts in the liquid-phase hydrogenation of cinnamaldehyde. The original phases and supported systems were characterized using several techniques such as powder X-ray diffraction (XRD), scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM–EDS), Raman microprobe studies, X-ray photoelectron spectroscopy (XPS), thermogravimetry and differential thermal analyses (TG-DSC), temperature programmed reduction (TPR), and textural analysis (BET method), which confirmed their functionalization, physicochemical modification and the nature of Mo adsorbed species. Active acidic, basic and redox sites were determined by temperature programmed surface reaction (TPSR). Mo loading reached 7 wt% for the system RhMo<SUB>6</SUB>/PCH-F and 3 wt% for the system RhMo<SUB>6</SUB>/PILC-F, while unfunctionalized clay systems showed a value of 1 wt% of Mo. The catalytic performance showed that PCH-based composites were the most active and reached up to 56% conversion at 360 min of reaction when tested in liquid-phase cinnamaldehyde hydrogenation. The selectivity for all the systems was mainly toward hydrocinnamic aldehyde (HCAL) and reached 77% for the RhMo<SUB>6</SUB>/PCH-F catalyst at 25% conversion.
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
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info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/85930
url http://sedici.unlp.edu.ar/handle/10915/85930
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1631-0748
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.crci.2015.09.015
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
1174-1183
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instname:Universidad Nacional de La Plata
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reponame_str SEDICI (UNLP)
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instname_str Universidad Nacional de La Plata
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repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
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