Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde

Autores
Bertolini, Guillermo Ramon; Cabello, Carmen Ines; Muñoz, Mercedes; Casella, Monica Laura; Gazzoli, Delia; Pettiti, Ida; Ferraris, Giovani
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Several catalysts based on [RhMo6O24H6]3− (RhMo6) heteropolyanion supported on -Al2O3 with different textural properties were prepared, characterized and tested in the liquid-phase hydrogenation of cinnamaldehyde. The characterization of pure and supported systems was carried out using several techniques including XRD, SEM-EDS microscopy, Raman microprobe, X-ray photoelectron spectroscopies and temperature programmed reduction (TPR). The catalytic performance was monitored by conversion of the starting cinnamaldehyde as a function of time: the initial activities represented as the turnover frequency (TOF), were measured considering the surface Rh atoms. The planar heteropolyanion RhMo6/(EI) based systems showed enhanced catalytic activity over the RhMo conventional catalyst obtained by successive impregnation of both transition metal ions (Rh(III) chloride and heptamolybdate). The selectivity for the RhMo6 systems was mainly toward HCAL unlike the conventional catalyst which showed selectivity toward CA. This study also showed a synergetic effect between Rh and Mo through which Rh promoted Mo reducibility.
Fil: Bertolini, Guillermo Ramon. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Cabello, Carmen Ines . Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Fil: Muñoz, Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Casella, Monica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Gazzoli, Delia. Dipartimento Di Chimica; Italia
Fil: Pettiti, Ida. Dipartimento Di Chimica; Italia
Fil: Ferraris, Giovani. Dipartimento Di Chimica; Italia
Materia
Heteropolyoxomolybdates
Anderson Phases of Rh(Iii)
Rhmo6/Γ-Al2o3
Cinnamaldehyde
Selective Hydrogenation
Hydrocinnamaldehyde
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/9619
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/9619
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehydeBertolini, Guillermo RamonCabello, Carmen Ines Muñoz, MercedesCasella, Monica LauraGazzoli, DeliaPettiti, IdaFerraris, GiovaniHeteropolyoxomolybdatesAnderson Phases of Rh(Iii)Rhmo6/Γ-Al2o3CinnamaldehydeSelective HydrogenationHydrocinnamaldehydehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Several catalysts based on [RhMo6O24H6]3− (RhMo6) heteropolyanion supported on -Al2O3 with different textural properties were prepared, characterized and tested in the liquid-phase hydrogenation of cinnamaldehyde. The characterization of pure and supported systems was carried out using several techniques including XRD, SEM-EDS microscopy, Raman microprobe, X-ray photoelectron spectroscopies and temperature programmed reduction (TPR). The catalytic performance was monitored by conversion of the starting cinnamaldehyde as a function of time: the initial activities represented as the turnover frequency (TOF), were measured considering the surface Rh atoms. The planar heteropolyanion RhMo6/(EI) based systems showed enhanced catalytic activity over the RhMo conventional catalyst obtained by successive impregnation of both transition metal ions (Rh(III) chloride and heptamolybdate). The selectivity for the RhMo6 systems was mainly toward HCAL unlike the conventional catalyst which showed selectivity toward CA. This study also showed a synergetic effect between Rh and Mo through which Rh promoted Mo reducibility.Fil: Bertolini, Guillermo Ramon. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Cabello, Carmen Ines . Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; ArgentinaFil: Muñoz, Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Casella, Monica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Gazzoli, Delia. Dipartimento Di Chimica; ItaliaFil: Pettiti, Ida. Dipartimento Di Chimica; ItaliaFil: Ferraris, Giovani. Dipartimento Di Chimica; ItaliaElsevier Science2012-09-25info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/9619Bertolini, Guillermo Ramon; Cabello, Carmen Ines ; Muñoz, Mercedes; Casella, Monica Laura; Gazzoli, Delia; et al.; Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde; Elsevier Science; Journal of Molecular Catalysis A: Chemical; 366; 25-9-2012; 109-1151381-1169enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.molcata.2012.09.013info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1381116912003044info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:33:03Zoai:ri.conicet.gov.ar:11336/9619instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:33:03.525CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde
title Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde
spellingShingle Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde
Bertolini, Guillermo Ramon
Heteropolyoxomolybdates
Anderson Phases of Rh(Iii)
Rhmo6/Γ-Al2o3
Cinnamaldehyde
Selective Hydrogenation
Hydrocinnamaldehyde
title_short Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde
title_full Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde
title_fullStr Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde
title_full_unstemmed Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde
title_sort Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde
dc.creator.none.fl_str_mv Bertolini, Guillermo Ramon
Cabello, Carmen Ines
Muñoz, Mercedes
Casella, Monica Laura
Gazzoli, Delia
Pettiti, Ida
Ferraris, Giovani
author Bertolini, Guillermo Ramon
author_facet Bertolini, Guillermo Ramon
Cabello, Carmen Ines
Muñoz, Mercedes
Casella, Monica Laura
Gazzoli, Delia
Pettiti, Ida
Ferraris, Giovani
author_role author
author2 Cabello, Carmen Ines
Muñoz, Mercedes
Casella, Monica Laura
Gazzoli, Delia
Pettiti, Ida
Ferraris, Giovani
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Heteropolyoxomolybdates
Anderson Phases of Rh(Iii)
Rhmo6/Γ-Al2o3
Cinnamaldehyde
Selective Hydrogenation
Hydrocinnamaldehyde
topic Heteropolyoxomolybdates
Anderson Phases of Rh(Iii)
Rhmo6/Γ-Al2o3
Cinnamaldehyde
Selective Hydrogenation
Hydrocinnamaldehyde
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Several catalysts based on [RhMo6O24H6]3− (RhMo6) heteropolyanion supported on -Al2O3 with different textural properties were prepared, characterized and tested in the liquid-phase hydrogenation of cinnamaldehyde. The characterization of pure and supported systems was carried out using several techniques including XRD, SEM-EDS microscopy, Raman microprobe, X-ray photoelectron spectroscopies and temperature programmed reduction (TPR). The catalytic performance was monitored by conversion of the starting cinnamaldehyde as a function of time: the initial activities represented as the turnover frequency (TOF), were measured considering the surface Rh atoms. The planar heteropolyanion RhMo6/(EI) based systems showed enhanced catalytic activity over the RhMo conventional catalyst obtained by successive impregnation of both transition metal ions (Rh(III) chloride and heptamolybdate). The selectivity for the RhMo6 systems was mainly toward HCAL unlike the conventional catalyst which showed selectivity toward CA. This study also showed a synergetic effect between Rh and Mo through which Rh promoted Mo reducibility.
Fil: Bertolini, Guillermo Ramon. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Cabello, Carmen Ines . Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Fil: Muñoz, Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Casella, Monica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Gazzoli, Delia. Dipartimento Di Chimica; Italia
Fil: Pettiti, Ida. Dipartimento Di Chimica; Italia
Fil: Ferraris, Giovani. Dipartimento Di Chimica; Italia
description Several catalysts based on [RhMo6O24H6]3− (RhMo6) heteropolyanion supported on -Al2O3 with different textural properties were prepared, characterized and tested in the liquid-phase hydrogenation of cinnamaldehyde. The characterization of pure and supported systems was carried out using several techniques including XRD, SEM-EDS microscopy, Raman microprobe, X-ray photoelectron spectroscopies and temperature programmed reduction (TPR). The catalytic performance was monitored by conversion of the starting cinnamaldehyde as a function of time: the initial activities represented as the turnover frequency (TOF), were measured considering the surface Rh atoms. The planar heteropolyanion RhMo6/(EI) based systems showed enhanced catalytic activity over the RhMo conventional catalyst obtained by successive impregnation of both transition metal ions (Rh(III) chloride and heptamolybdate). The selectivity for the RhMo6 systems was mainly toward HCAL unlike the conventional catalyst which showed selectivity toward CA. This study also showed a synergetic effect between Rh and Mo through which Rh promoted Mo reducibility.
publishDate 2012
dc.date.none.fl_str_mv 2012-09-25
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/9619
Bertolini, Guillermo Ramon; Cabello, Carmen Ines ; Muñoz, Mercedes; Casella, Monica Laura; Gazzoli, Delia; et al.; Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde; Elsevier Science; Journal of Molecular Catalysis A: Chemical; 366; 25-9-2012; 109-115
1381-1169
url http://hdl.handle.net/11336/9619
identifier_str_mv Bertolini, Guillermo Ramon; Cabello, Carmen Ines ; Muñoz, Mercedes; Casella, Monica Laura; Gazzoli, Delia; et al.; Catalysts based on Rh(III)-hexamolybdate/g-Al2O3 and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde; Elsevier Science; Journal of Molecular Catalysis A: Chemical; 366; 25-9-2012; 109-115
1381-1169
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.molcata.2012.09.013
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1381116912003044
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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