A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate
- Autores
- Zelcer, Andrés; Chaia, Zulema D.; Cukiernik, Fabio D.; Castellano, Eduardo Ernesto; Piro, Oscar Enrique
- Año de publicación
- 2002
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The title compound, catena-poly[[tetrakis(μ-decanoato-κ2O:O′)diruthenium(II,III)(Ru—Ru)]-μ-octanesulfonato-κ2O:O′], [Ru2(C10H19O2)4(C8H17O3S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains.
Facultad de Ciencias Exactas - Materia
-
Ciencias Exactas
Química
octanesulfonate
diruthenium tetradecanoate
ruthenium - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/126412
Ver los metadatos del registro completo
| id |
SEDICI_d373d08271af41b62f982bc6a843db7b |
|---|---|
| oai_identifier_str |
oai:sedici.unlp.edu.ar:10915/126412 |
| network_acronym_str |
SEDICI |
| repository_id_str |
1329 |
| network_name_str |
SEDICI (UNLP) |
| spelling |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylateZelcer, AndrésChaia, Zulema D.Cukiernik, Fabio D.Castellano, Eduardo ErnestoPiro, Oscar EnriqueCiencias ExactasQuímicaoctanesulfonatediruthenium tetradecanoaterutheniumThe title compound, catena-poly[[tetrakis(μ-decanoato-κ<sup>2</sup>O:O′)diruthenium(II,III)(Ru—Ru)]-μ-octanesulfonato-κ2O:O′], [Ru<sub>2</sub>(C<sub>10</sub>H<sub>19</sub>O<sub>2</sub>)<sub>4</sub>(C<sub>8</sub>H<sub>17</sub>O<sub>3</sub>S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains.Facultad de Ciencias Exactas2002-02-13info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfm144-m146http://sedici.unlp.edu.ar/handle/10915/126412enginfo:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S0108270101021540info:eu-repo/semantics/altIdentifier/issn/0108-2701info:eu-repo/semantics/altIdentifier/issn/1600-5759info:eu-repo/semantics/altIdentifier/doi/10.1107/s0108270101021540info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:22:15Zoai:sedici.unlp.edu.ar:10915/126412Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:22:16.036SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| title |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| spellingShingle |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate Zelcer, Andrés Ciencias Exactas Química octanesulfonate diruthenium tetradecanoate ruthenium |
| title_short |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| title_full |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| title_fullStr |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| title_full_unstemmed |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| title_sort |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| dc.creator.none.fl_str_mv |
Zelcer, Andrés Chaia, Zulema D. Cukiernik, Fabio D. Castellano, Eduardo Ernesto Piro, Oscar Enrique |
| author |
Zelcer, Andrés |
| author_facet |
Zelcer, Andrés Chaia, Zulema D. Cukiernik, Fabio D. Castellano, Eduardo Ernesto Piro, Oscar Enrique |
| author_role |
author |
| author2 |
Chaia, Zulema D. Cukiernik, Fabio D. Castellano, Eduardo Ernesto Piro, Oscar Enrique |
| author2_role |
author author author author |
| dc.subject.none.fl_str_mv |
Ciencias Exactas Química octanesulfonate diruthenium tetradecanoate ruthenium |
| topic |
Ciencias Exactas Química octanesulfonate diruthenium tetradecanoate ruthenium |
| dc.description.none.fl_txt_mv |
The title compound, catena-poly[[tetrakis(μ-decanoato-κ<sup>2</sup>O:O′)diruthenium(II,III)(Ru—Ru)]-μ-octanesulfonato-κ2O:O′], [Ru<sub>2</sub>(C<sub>10</sub>H<sub>19</sub>O<sub>2</sub>)<sub>4</sub>(C<sub>8</sub>H<sub>17</sub>O<sub>3</sub>S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains. Facultad de Ciencias Exactas |
| description |
The title compound, catena-poly[[tetrakis(μ-decanoato-κ<sup>2</sup>O:O′)diruthenium(II,III)(Ru—Ru)]-μ-octanesulfonato-κ2O:O′], [Ru<sub>2</sub>(C<sub>10</sub>H<sub>19</sub>O<sub>2</sub>)<sub>4</sub>(C<sub>8</sub>H<sub>17</sub>O<sub>3</sub>S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains. |
| publishDate |
2002 |
| dc.date.none.fl_str_mv |
2002-02-13 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/126412 |
| url |
http://sedici.unlp.edu.ar/handle/10915/126412 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S0108270101021540 info:eu-repo/semantics/altIdentifier/issn/0108-2701 info:eu-repo/semantics/altIdentifier/issn/1600-5759 info:eu-repo/semantics/altIdentifier/doi/10.1107/s0108270101021540 |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
| eu_rights_str_mv |
openAccess |
| rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
| dc.format.none.fl_str_mv |
application/pdf m144-m146 |
| dc.source.none.fl_str_mv |
reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
| reponame_str |
SEDICI (UNLP) |
| collection |
SEDICI (UNLP) |
| instname_str |
Universidad Nacional de La Plata |
| instacron_str |
UNLP |
| institution |
UNLP |
| repository.name.fl_str_mv |
SEDICI (UNLP) - Universidad Nacional de La Plata |
| repository.mail.fl_str_mv |
alira@sedici.unlp.edu.ar |
| _version_ |
1846064278616932352 |
| score |
13.22299 |