A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate

Autores
Zelcer, A.; Chaia, Z.D.; Cukiernik, F.D.; Castellano, E.E.; Piro, O.E.
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound, catena-poly[[tetrakis(μ-decanoato- κ2O:O′)-diruthenium(II, III) (Ru - Ru)]- μ-octanesulfonato-κ2O:O′], [Ru2(C10H19O2)4 (C8H17O3S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains.
Fil:Zelcer, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Chaia, Z.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Cukiernik, F.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fuente
Acta Crystallogr Sect C Cryst Struct Commun 2002;58(3):m144-m146
Materia
Crystal structure
Liquid crystals
Negative ions
Ruthenium compounds
X ray diffraction analysis
Diruthenium tetradecanoate
Long chain carboxylate
Organometallics
Catena
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/2.5/ar
Repositorio
Biblioteca Digital (UBA-FCEN)
Institución
Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
OAI Identificador
paperaa:paper_01082701_v58_n3_pm144_Zelcer
Acceder
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oai_identifier_str paperaa:paper_01082701_v58_n3_pm144_Zelcer
network_acronym_str BDUBAFCEN
repository_id_str 1896
network_name_str Biblioteca Digital (UBA-FCEN)
spelling A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylateZelcer, A.Chaia, Z.D.Cukiernik, F.D.Castellano, E.E.Piro, O.E.Crystal structureLiquid crystalsNegative ionsRuthenium compoundsX ray diffraction analysisDiruthenium tetradecanoateLong chain carboxylateOrganometallicsCatenaThe title compound, catena-poly[[tetrakis(μ-decanoato- κ2O:O′)-diruthenium(II, III) (Ru - Ru)]- μ-octanesulfonato-κ2O:O′], [Ru2(C10H19O2)4 (C8H17O3S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains.Fil:Zelcer, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Chaia, Z.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Cukiernik, F.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.2002info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12110/paper_01082701_v58_n3_pm144_ZelcerActa Crystallogr Sect C Cryst Struct Commun 2002;58(3):m144-m146reponame:Biblioteca Digital (UBA-FCEN)instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesinstacron:UBA-FCENenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/ar2025-10-16T09:30:20Zpaperaa:paper_01082701_v58_n3_pm144_ZelcerInstitucionalhttps://digital.bl.fcen.uba.ar/Universidad públicaNo correspondehttps://digital.bl.fcen.uba.ar/cgi-bin/oaiserver.cgiana@bl.fcen.uba.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:18962025-10-16 09:30:22.665Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesfalse
dc.title.none.fl_str_mv A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
title A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
spellingShingle A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
Zelcer, A.
Crystal structure
Liquid crystals
Negative ions
Ruthenium compounds
X ray diffraction analysis
Diruthenium tetradecanoate
Long chain carboxylate
Organometallics
Catena
title_short A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
title_full A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
title_fullStr A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
title_full_unstemmed A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
title_sort A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
dc.creator.none.fl_str_mv Zelcer, A.
Chaia, Z.D.
Cukiernik, F.D.
Castellano, E.E.
Piro, O.E.
author Zelcer, A.
author_facet Zelcer, A.
Chaia, Z.D.
Cukiernik, F.D.
Castellano, E.E.
Piro, O.E.
author_role author
author2 Chaia, Z.D.
Cukiernik, F.D.
Castellano, E.E.
Piro, O.E.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Crystal structure
Liquid crystals
Negative ions
Ruthenium compounds
X ray diffraction analysis
Diruthenium tetradecanoate
Long chain carboxylate
Organometallics
Catena
topic Crystal structure
Liquid crystals
Negative ions
Ruthenium compounds
X ray diffraction analysis
Diruthenium tetradecanoate
Long chain carboxylate
Organometallics
Catena
dc.description.none.fl_txt_mv The title compound, catena-poly[[tetrakis(μ-decanoato- κ2O:O′)-diruthenium(II, III) (Ru - Ru)]- μ-octanesulfonato-κ2O:O′], [Ru2(C10H19O2)4 (C8H17O3S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains.
Fil:Zelcer, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Chaia, Z.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Cukiernik, F.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
description The title compound, catena-poly[[tetrakis(μ-decanoato- κ2O:O′)-diruthenium(II, III) (Ru - Ru)]- μ-octanesulfonato-κ2O:O′], [Ru2(C10H19O2)4 (C8H17O3S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains.
publishDate 2002
dc.date.none.fl_str_mv 2002
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12110/paper_01082701_v58_n3_pm144_Zelcer
url http://hdl.handle.net/20.500.12110/paper_01082701_v58_n3_pm144_Zelcer
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/2.5/ar
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv Acta Crystallogr Sect C Cryst Struct Commun 2002;58(3):m144-m146
reponame:Biblioteca Digital (UBA-FCEN)
instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron:UBA-FCEN
reponame_str Biblioteca Digital (UBA-FCEN)
collection Biblioteca Digital (UBA-FCEN)
instname_str Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron_str UBA-FCEN
institution UBA-FCEN
repository.name.fl_str_mv Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
repository.mail.fl_str_mv ana@bl.fcen.uba.ar
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score 12.712165

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