The interaction between sulfathiazole and cobalt(II): potentiometric studies
- Autores
- Bellú, Sebastián; Rizzotto, Marcela; Okulik, Nora Beatriz; Jubert, Alicia Haydeé
- Año de publicación
- 2007
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Potentiometric studies of sulfathiazole (HST) in the presence and absence of cobalt(II) were performed. Equilibrium constants for the formation of the detected species, [Co(ST)]+ and [Co(ST)(OH)], are reported. UV-Vis spectrophotometric measurements suggest that the coordination Co(II)-sulfathiazole might be through a N atom, which, in agreement with MO calculations, could be a thiazolic one. In spite of sulfonamides being better ligands at pH >7, [Co(ST)]+ was found at pH ≈ 3.
Facultad de Ciencias Exactas - Materia
-
Química
Potenciometría
Cobalto
Sulfatiazoles - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc/3.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/29433
Ver los metadatos del registro completo
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The interaction between sulfathiazole and cobalt(II): potentiometric studiesBellú, SebastiánRizzotto, MarcelaOkulik, Nora BeatrizJubert, Alicia HaydeéQuímicaPotenciometríaCobaltoSulfatiazolesPotentiometric studies of sulfathiazole (HST) in the presence and absence of cobalt(II) were performed. Equilibrium constants for the formation of the detected species, [Co(ST)]<sup>+</sup> and [Co(ST)(OH)], are reported. UV-Vis spectrophotometric measurements suggest that the coordination Co(II)-sulfathiazole might be through a N atom, which, in agreement with MO calculations, could be a thiazolic one. In spite of sulfonamides being better ligands at pH >7, [Co(ST)]<sup>+</sup> was found at pH ≈ 3.Facultad de Ciencias Exactas2007info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1136-1142http://sedici.unlp.edu.ar/handle/10915/29433enginfo:eu-repo/semantics/altIdentifier/url/http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500016&lng=en&nrm=iso&tlng=eninfo:eu-repo/semantics/altIdentifier/issn/0100-4042info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc/3.0/Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T10:57:12Zoai:sedici.unlp.edu.ar:10915/29433Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 10:57:13.143SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
The interaction between sulfathiazole and cobalt(II): potentiometric studies |
title |
The interaction between sulfathiazole and cobalt(II): potentiometric studies |
spellingShingle |
The interaction between sulfathiazole and cobalt(II): potentiometric studies Bellú, Sebastián Química Potenciometría Cobalto Sulfatiazoles |
title_short |
The interaction between sulfathiazole and cobalt(II): potentiometric studies |
title_full |
The interaction between sulfathiazole and cobalt(II): potentiometric studies |
title_fullStr |
The interaction between sulfathiazole and cobalt(II): potentiometric studies |
title_full_unstemmed |
The interaction between sulfathiazole and cobalt(II): potentiometric studies |
title_sort |
The interaction between sulfathiazole and cobalt(II): potentiometric studies |
dc.creator.none.fl_str_mv |
Bellú, Sebastián Rizzotto, Marcela Okulik, Nora Beatriz Jubert, Alicia Haydeé |
author |
Bellú, Sebastián |
author_facet |
Bellú, Sebastián Rizzotto, Marcela Okulik, Nora Beatriz Jubert, Alicia Haydeé |
author_role |
author |
author2 |
Rizzotto, Marcela Okulik, Nora Beatriz Jubert, Alicia Haydeé |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Química Potenciometría Cobalto Sulfatiazoles |
topic |
Química Potenciometría Cobalto Sulfatiazoles |
dc.description.none.fl_txt_mv |
Potentiometric studies of sulfathiazole (HST) in the presence and absence of cobalt(II) were performed. Equilibrium constants for the formation of the detected species, [Co(ST)]<sup>+</sup> and [Co(ST)(OH)], are reported. UV-Vis spectrophotometric measurements suggest that the coordination Co(II)-sulfathiazole might be through a N atom, which, in agreement with MO calculations, could be a thiazolic one. In spite of sulfonamides being better ligands at pH >7, [Co(ST)]<sup>+</sup> was found at pH ≈ 3. Facultad de Ciencias Exactas |
description |
Potentiometric studies of sulfathiazole (HST) in the presence and absence of cobalt(II) were performed. Equilibrium constants for the formation of the detected species, [Co(ST)]<sup>+</sup> and [Co(ST)(OH)], are reported. UV-Vis spectrophotometric measurements suggest that the coordination Co(II)-sulfathiazole might be through a N atom, which, in agreement with MO calculations, could be a thiazolic one. In spite of sulfonamides being better ligands at pH >7, [Co(ST)]<sup>+</sup> was found at pH ≈ 3. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/29433 |
url |
http://sedici.unlp.edu.ar/handle/10915/29433 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500016&lng=en&nrm=iso&tlng=en info:eu-repo/semantics/altIdentifier/issn/0100-4042 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc/3.0/ Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc/3.0/ Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0) |
dc.format.none.fl_str_mv |
application/pdf 1136-1142 |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
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