Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutions
- Autores
- Martins, María Elisa; Castellano, Carlos E.; Calandra, Alfredo J.; Arvia, Alejandro Jorge
- Año de publicación
- 1978
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The electrochemical behaviour of the Au/SCN− (DMSO) interface is studied at 25°C≤T≤65°C, by means of the triangular potential sweep technique and the RDE. Within a relatively limited potential range the main electrode process is: 3 SCN−=(SCN)3−+2e The kinetics of this reaction involves a mixed control. At higher potentials the electrodissolution of the base metal takes place. Side reactions occurring there make the overall process rather complex. The electrochemical behaviours of the Au/SCN− (DMSO) and Au/SCN− (ACN) are compared.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas - Materia
-
Ciencias Exactas
Química
Electrochemical behaviour
Gold
SCN−/dimethylsulfoxide solutions - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/119485
Ver los metadatos del registro completo
| id |
SEDICI_aede2efc63ab5ff2de16782748e54901 |
|---|---|
| oai_identifier_str |
oai:sedici.unlp.edu.ar:10915/119485 |
| network_acronym_str |
SEDICI |
| repository_id_str |
1329 |
| network_name_str |
SEDICI (UNLP) |
| spelling |
Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutionsMartins, María ElisaCastellano, Carlos E.Calandra, Alfredo J.Arvia, Alejandro JorgeCiencias ExactasQuímicaElectrochemical behaviourGoldSCN−/dimethylsulfoxide solutionsThe electrochemical behaviour of the Au/SCN<sup>−</sup> (DMSO) interface is studied at 25°C≤T≤65°C, by means of the triangular potential sweep technique and the RDE. Within a relatively limited potential range the main electrode process is: 3 SCN<sup>−</sup>=(SCN)<sub>3</sub><sup>−</sup>+2e The kinetics of this reaction involves a mixed control. At higher potentials the electrodissolution of the base metal takes place. Side reactions occurring there make the overall process rather complex. The electrochemical behaviours of the Au/SCN<sup>−</sup> (DMSO) and Au/SCN<sup>−</sup> (ACN) are compared.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1978info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf45-53http://sedici.unlp.edu.ar/handle/10915/119485enginfo:eu-repo/semantics/altIdentifier/issn/0022-0728info:eu-repo/semantics/altIdentifier/doi/10.1016/S0022-0728(78)80115-6info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:28:14Zoai:sedici.unlp.edu.ar:10915/119485Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:28:14.587SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutions |
| title |
Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutions |
| spellingShingle |
Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutions Martins, María Elisa Ciencias Exactas Química Electrochemical behaviour Gold SCN−/dimethylsulfoxide solutions |
| title_short |
Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutions |
| title_full |
Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutions |
| title_fullStr |
Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutions |
| title_full_unstemmed |
Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutions |
| title_sort |
Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutions |
| dc.creator.none.fl_str_mv |
Martins, María Elisa Castellano, Carlos E. Calandra, Alfredo J. Arvia, Alejandro Jorge |
| author |
Martins, María Elisa |
| author_facet |
Martins, María Elisa Castellano, Carlos E. Calandra, Alfredo J. Arvia, Alejandro Jorge |
| author_role |
author |
| author2 |
Castellano, Carlos E. Calandra, Alfredo J. Arvia, Alejandro Jorge |
| author2_role |
author author author |
| dc.subject.none.fl_str_mv |
Ciencias Exactas Química Electrochemical behaviour Gold SCN−/dimethylsulfoxide solutions |
| topic |
Ciencias Exactas Química Electrochemical behaviour Gold SCN−/dimethylsulfoxide solutions |
| dc.description.none.fl_txt_mv |
The electrochemical behaviour of the Au/SCN<sup>−</sup> (DMSO) interface is studied at 25°C≤T≤65°C, by means of the triangular potential sweep technique and the RDE. Within a relatively limited potential range the main electrode process is: 3 SCN<sup>−</sup>=(SCN)<sub>3</sub><sup>−</sup>+2e The kinetics of this reaction involves a mixed control. At higher potentials the electrodissolution of the base metal takes place. Side reactions occurring there make the overall process rather complex. The electrochemical behaviours of the Au/SCN<sup>−</sup> (DMSO) and Au/SCN<sup>−</sup> (ACN) are compared. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
| description |
The electrochemical behaviour of the Au/SCN<sup>−</sup> (DMSO) interface is studied at 25°C≤T≤65°C, by means of the triangular potential sweep technique and the RDE. Within a relatively limited potential range the main electrode process is: 3 SCN<sup>−</sup>=(SCN)<sub>3</sub><sup>−</sup>+2e The kinetics of this reaction involves a mixed control. At higher potentials the electrodissolution of the base metal takes place. Side reactions occurring there make the overall process rather complex. The electrochemical behaviours of the Au/SCN<sup>−</sup> (DMSO) and Au/SCN<sup>−</sup> (ACN) are compared. |
| publishDate |
1978 |
| dc.date.none.fl_str_mv |
1978 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/119485 |
| url |
http://sedici.unlp.edu.ar/handle/10915/119485 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/0022-0728 info:eu-repo/semantics/altIdentifier/doi/10.1016/S0022-0728(78)80115-6 |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
| eu_rights_str_mv |
openAccess |
| rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
| dc.format.none.fl_str_mv |
application/pdf 45-53 |
| dc.source.none.fl_str_mv |
reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
| reponame_str |
SEDICI (UNLP) |
| collection |
SEDICI (UNLP) |
| instname_str |
Universidad Nacional de La Plata |
| instacron_str |
UNLP |
| institution |
UNLP |
| repository.name.fl_str_mv |
SEDICI (UNLP) - Universidad Nacional de La Plata |
| repository.mail.fl_str_mv |
alira@sedici.unlp.edu.ar |
| _version_ |
1844616160359743488 |
| score |
13.070432 |