Silane as adhesion promoter in damaged areas

Autores
Deyá, Marta Cecilia
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Silanes have been studied as adhesion promoters between metals (aluminum, galvanized steel and steel) and paints such as polyurethanes. The objective of this work was to study γ-glycidoxypropyltrimethoxysilano (glymo) as adhesion promoter between sandblasted steel and one water-based epoxy paint formulated in the laboratory. In some cases, the silane film was doped with sodium phosphate or sodium benzoate, and in other cases, glymo or extra epoxy resin were incorporated as part of the paint formulation. The performance of the metal-glymo-paint system was studied by electrochemical noise technique and accelerated tests (salt spray cabinet and humidity chamber). Dry and wet adhesions were also determined. The results showed that the incorporation of γ-glycidoxypropyltrimethoxysilane as pretreatment or in paint formulation does not enhance paint adhesion in undamaged areas. However, when the painted area was damaged, the incorporation of silane in the paint or doped silane in the pretreatment enhances paint performance in these areas.
Centro de Investigación y Desarrollo en Tecnología de Pinturas
Materia
Ingeniería Química
Thin films
Coatings
Corrosion tests
Scanning electron microscopy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/96628
Acceder
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network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Silane as adhesion promoter in damaged areasDeyá, Marta CeciliaIngeniería QuímicaThin filmsCoatingsCorrosion testsScanning electron microscopySilanes have been studied as adhesion promoters between metals (aluminum, galvanized steel and steel) and paints such as polyurethanes. The objective of this work was to study γ-glycidoxypropyltrimethoxysilano (glymo) as adhesion promoter between sandblasted steel and one water-based epoxy paint formulated in the laboratory. In some cases, the silane film was doped with sodium phosphate or sodium benzoate, and in other cases, glymo or extra epoxy resin were incorporated as part of the paint formulation. The performance of the metal-glymo-paint system was studied by electrochemical noise technique and accelerated tests (salt spray cabinet and humidity chamber). Dry and wet adhesions were also determined. The results showed that the incorporation of γ-glycidoxypropyltrimethoxysilane as pretreatment or in paint formulation does not enhance paint adhesion in undamaged areas. However, when the painted area was damaged, the incorporation of silane in the paint or doped silane in the pretreatment enhances paint performance in these areas.Centro de Investigación y Desarrollo en Tecnología de Pinturas2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf28-33http://sedici.unlp.edu.ar/handle/10915/96628enginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0300944015301120info:eu-repo/semantics/altIdentifier/issn/0300-9440info:eu-repo/semantics/altIdentifier/doi/10.1016/j.porgcoat.2015.09.001info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:12:39Zoai:sedici.unlp.edu.ar:10915/96628Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:12:39.656SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Silane as adhesion promoter in damaged areas
title Silane as adhesion promoter in damaged areas
spellingShingle Silane as adhesion promoter in damaged areas
Deyá, Marta Cecilia
Ingeniería Química
Thin films
Coatings
Corrosion tests
Scanning electron microscopy
title_short Silane as adhesion promoter in damaged areas
title_full Silane as adhesion promoter in damaged areas
title_fullStr Silane as adhesion promoter in damaged areas
title_full_unstemmed Silane as adhesion promoter in damaged areas
title_sort Silane as adhesion promoter in damaged areas
dc.creator.none.fl_str_mv Deyá, Marta Cecilia
author Deyá, Marta Cecilia
author_facet Deyá, Marta Cecilia
author_role author
dc.subject.none.fl_str_mv Ingeniería Química
Thin films
Coatings
Corrosion tests
Scanning electron microscopy
topic Ingeniería Química
Thin films
Coatings
Corrosion tests
Scanning electron microscopy
dc.description.none.fl_txt_mv Silanes have been studied as adhesion promoters between metals (aluminum, galvanized steel and steel) and paints such as polyurethanes. The objective of this work was to study γ-glycidoxypropyltrimethoxysilano (glymo) as adhesion promoter between sandblasted steel and one water-based epoxy paint formulated in the laboratory. In some cases, the silane film was doped with sodium phosphate or sodium benzoate, and in other cases, glymo or extra epoxy resin were incorporated as part of the paint formulation. The performance of the metal-glymo-paint system was studied by electrochemical noise technique and accelerated tests (salt spray cabinet and humidity chamber). Dry and wet adhesions were also determined. The results showed that the incorporation of γ-glycidoxypropyltrimethoxysilane as pretreatment or in paint formulation does not enhance paint adhesion in undamaged areas. However, when the painted area was damaged, the incorporation of silane in the paint or doped silane in the pretreatment enhances paint performance in these areas.
Centro de Investigación y Desarrollo en Tecnología de Pinturas
description Silanes have been studied as adhesion promoters between metals (aluminum, galvanized steel and steel) and paints such as polyurethanes. The objective of this work was to study γ-glycidoxypropyltrimethoxysilano (glymo) as adhesion promoter between sandblasted steel and one water-based epoxy paint formulated in the laboratory. In some cases, the silane film was doped with sodium phosphate or sodium benzoate, and in other cases, glymo or extra epoxy resin were incorporated as part of the paint formulation. The performance of the metal-glymo-paint system was studied by electrochemical noise technique and accelerated tests (salt spray cabinet and humidity chamber). Dry and wet adhesions were also determined. The results showed that the incorporation of γ-glycidoxypropyltrimethoxysilane as pretreatment or in paint formulation does not enhance paint adhesion in undamaged areas. However, when the painted area was damaged, the incorporation of silane in the paint or doped silane in the pretreatment enhances paint performance in these areas.
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/96628
url http://sedici.unlp.edu.ar/handle/10915/96628
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0300944015301120
info:eu-repo/semantics/altIdentifier/issn/0300-9440
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.porgcoat.2015.09.001
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.format.none.fl_str_mv application/pdf
28-33
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
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institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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