Versatile Fe-Containing Hydroxyapatite Nanomaterials as Efficient Substrates for Lead Ions Adsorption

Autores
Mercado, D. F.; Rubert, Aldo Alberto; Magnacca, G.; Malandrino, M.; Sapino, S.; Caregnato, Paula; Bianco Prevot, A.; González, Mónica Cristina
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The capability of paramegnetic iron-containing hydroxyapatite (Fe-nAp) and waste bioorganic subtrates templeted iron-containing hydroxyapatite (SBO-Fe-nAp) nanoparticles, as Pb(II) cations adsorbants were investigated and compared to those of synthetic hydroxyapatite (nAp). Surface and bulk characterization techniques as XPS, XRD, electrophoretic mobility, FTIR spectroscopy, DLS, and TEM were used to investigate the adsorption mechanisms involved and ICP-AES to determine Pb(II) concentrations in aqueous solutions. The apatite-based nanoparticles were found to be efficient materials for the irreversible adsorption of Pb(II) ions from aqueous solutions, with maximum adsorption capacity increasing as: hydroxyapatite<waste bioorganic subtrates templeted ironcontaining hydroxyapatite < iron-containing hydroxyapatite. Adsorption capacities of 1500 mg g−1 observed for iron-containing hydroxyapatite, are among the highest reported for Pb(II) adsorption. The high surface to volume ratio, low crystallinity, and the negatively charged surface, strongly favour aqueous Pb(II) adsorption on Fe-containing apatites over the positively charged crystalline hydroxyapatite. The adsorption mechanisms involved depend on the available surface hydroxyl and carboxyl groups as well as on the formation of stable lead-containing hydroxyapatite-like structures. Moreover, bimetal adsorption experiments involving Cu(II) and Pb(II) ions show particular selectivity depending on the surface chemistry of the hydroxyapatite-based adsorbent. While hydroxyapatite is selective towards Pb(II), Fe-containing hydroxyapatite selectivity depends on the relative [Pb]/[Cu] ratio, and waste bioorganic subtrates templeted Fe-containing hydroxyapatite, adsorbs both ions with similar capability.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Química
Paramagnetic Nanoparticles
Pb(II) Adsorption
Cu(II) Adsorption
Bio-Organic Substrates
Surface Chemistry
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/170140
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/170140
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Versatile Fe-Containing Hydroxyapatite Nanomaterials as Efficient Substrates for Lead Ions AdsorptionMercado, D. F.Rubert, Aldo AlbertoMagnacca, G.Malandrino, M.Sapino, S.Caregnato, PaulaBianco Prevot, A.González, Mónica CristinaQuímicaParamagnetic NanoparticlesPb(II) AdsorptionCu(II) AdsorptionBio-Organic SubstratesSurface ChemistryThe capability of paramegnetic iron-containing hydroxyapatite (Fe-nAp) and waste bioorganic subtrates templeted iron-containing hydroxyapatite (SBO-Fe-nAp) nanoparticles, as Pb(II) cations adsorbants were investigated and compared to those of synthetic hydroxyapatite (nAp). Surface and bulk characterization techniques as XPS, XRD, electrophoretic mobility, FTIR spectroscopy, DLS, and TEM were used to investigate the adsorption mechanisms involved and ICP-AES to determine Pb(II) concentrations in aqueous solutions. The apatite-based nanoparticles were found to be efficient materials for the irreversible adsorption of Pb(II) ions from aqueous solutions, with maximum adsorption capacity increasing as: hydroxyapatite&lt;waste bioorganic subtrates templeted ironcontaining hydroxyapatite &lt; iron-containing hydroxyapatite. Adsorption capacities of 1500 mg g−1 observed for iron-containing hydroxyapatite, are among the highest reported for Pb(II) adsorption. The high surface to volume ratio, low crystallinity, and the negatively charged surface, strongly favour aqueous Pb(II) adsorption on Fe-containing apatites over the positively charged crystalline hydroxyapatite. The adsorption mechanisms involved depend on the available surface hydroxyl and carboxyl groups as well as on the formation of stable lead-containing hydroxyapatite-like structures. Moreover, bimetal adsorption experiments involving Cu(II) and Pb(II) ions show particular selectivity depending on the surface chemistry of the hydroxyapatite-based adsorbent. While hydroxyapatite is selective towards Pb(II), Fe-containing hydroxyapatite selectivity depends on the relative [Pb]/[Cu] ratio, and waste bioorganic subtrates templeted Fe-containing hydroxyapatite, adsorbs both ions with similar capability.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/170140enginfo:eu-repo/semantics/altIdentifier/issn/1533-4899info:eu-repo/semantics/altIdentifier/doi/10.1166/jnn.2017.13870info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:45:36Zoai:sedici.unlp.edu.ar:10915/170140Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:45:37.299SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Versatile Fe-Containing Hydroxyapatite Nanomaterials as Efficient Substrates for Lead Ions Adsorption
title Versatile Fe-Containing Hydroxyapatite Nanomaterials as Efficient Substrates for Lead Ions Adsorption
spellingShingle Versatile Fe-Containing Hydroxyapatite Nanomaterials as Efficient Substrates for Lead Ions Adsorption
Mercado, D. F.
Química
Paramagnetic Nanoparticles
Pb(II) Adsorption
Cu(II) Adsorption
Bio-Organic Substrates
Surface Chemistry
title_short Versatile Fe-Containing Hydroxyapatite Nanomaterials as Efficient Substrates for Lead Ions Adsorption
title_full Versatile Fe-Containing Hydroxyapatite Nanomaterials as Efficient Substrates for Lead Ions Adsorption
title_fullStr Versatile Fe-Containing Hydroxyapatite Nanomaterials as Efficient Substrates for Lead Ions Adsorption
title_full_unstemmed Versatile Fe-Containing Hydroxyapatite Nanomaterials as Efficient Substrates for Lead Ions Adsorption
title_sort Versatile Fe-Containing Hydroxyapatite Nanomaterials as Efficient Substrates for Lead Ions Adsorption
dc.creator.none.fl_str_mv Mercado, D. F.
Rubert, Aldo Alberto
Magnacca, G.
Malandrino, M.
Sapino, S.
Caregnato, Paula
Bianco Prevot, A.
González, Mónica Cristina
author Mercado, D. F.
author_facet Mercado, D. F.
Rubert, Aldo Alberto
Magnacca, G.
Malandrino, M.
Sapino, S.
Caregnato, Paula
Bianco Prevot, A.
González, Mónica Cristina
author_role author
author2 Rubert, Aldo Alberto
Magnacca, G.
Malandrino, M.
Sapino, S.
Caregnato, Paula
Bianco Prevot, A.
González, Mónica Cristina
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Química
Paramagnetic Nanoparticles
Pb(II) Adsorption
Cu(II) Adsorption
Bio-Organic Substrates
Surface Chemistry
topic Química
Paramagnetic Nanoparticles
Pb(II) Adsorption
Cu(II) Adsorption
Bio-Organic Substrates
Surface Chemistry
dc.description.none.fl_txt_mv The capability of paramegnetic iron-containing hydroxyapatite (Fe-nAp) and waste bioorganic subtrates templeted iron-containing hydroxyapatite (SBO-Fe-nAp) nanoparticles, as Pb(II) cations adsorbants were investigated and compared to those of synthetic hydroxyapatite (nAp). Surface and bulk characterization techniques as XPS, XRD, electrophoretic mobility, FTIR spectroscopy, DLS, and TEM were used to investigate the adsorption mechanisms involved and ICP-AES to determine Pb(II) concentrations in aqueous solutions. The apatite-based nanoparticles were found to be efficient materials for the irreversible adsorption of Pb(II) ions from aqueous solutions, with maximum adsorption capacity increasing as: hydroxyapatite&lt;waste bioorganic subtrates templeted ironcontaining hydroxyapatite &lt; iron-containing hydroxyapatite. Adsorption capacities of 1500 mg g−1 observed for iron-containing hydroxyapatite, are among the highest reported for Pb(II) adsorption. The high surface to volume ratio, low crystallinity, and the negatively charged surface, strongly favour aqueous Pb(II) adsorption on Fe-containing apatites over the positively charged crystalline hydroxyapatite. The adsorption mechanisms involved depend on the available surface hydroxyl and carboxyl groups as well as on the formation of stable lead-containing hydroxyapatite-like structures. Moreover, bimetal adsorption experiments involving Cu(II) and Pb(II) ions show particular selectivity depending on the surface chemistry of the hydroxyapatite-based adsorbent. While hydroxyapatite is selective towards Pb(II), Fe-containing hydroxyapatite selectivity depends on the relative [Pb]/[Cu] ratio, and waste bioorganic subtrates templeted Fe-containing hydroxyapatite, adsorbs both ions with similar capability.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description The capability of paramegnetic iron-containing hydroxyapatite (Fe-nAp) and waste bioorganic subtrates templeted iron-containing hydroxyapatite (SBO-Fe-nAp) nanoparticles, as Pb(II) cations adsorbants were investigated and compared to those of synthetic hydroxyapatite (nAp). Surface and bulk characterization techniques as XPS, XRD, electrophoretic mobility, FTIR spectroscopy, DLS, and TEM were used to investigate the adsorption mechanisms involved and ICP-AES to determine Pb(II) concentrations in aqueous solutions. The apatite-based nanoparticles were found to be efficient materials for the irreversible adsorption of Pb(II) ions from aqueous solutions, with maximum adsorption capacity increasing as: hydroxyapatite&lt;waste bioorganic subtrates templeted ironcontaining hydroxyapatite &lt; iron-containing hydroxyapatite. Adsorption capacities of 1500 mg g−1 observed for iron-containing hydroxyapatite, are among the highest reported for Pb(II) adsorption. The high surface to volume ratio, low crystallinity, and the negatively charged surface, strongly favour aqueous Pb(II) adsorption on Fe-containing apatites over the positively charged crystalline hydroxyapatite. The adsorption mechanisms involved depend on the available surface hydroxyl and carboxyl groups as well as on the formation of stable lead-containing hydroxyapatite-like structures. Moreover, bimetal adsorption experiments involving Cu(II) and Pb(II) ions show particular selectivity depending on the surface chemistry of the hydroxyapatite-based adsorbent. While hydroxyapatite is selective towards Pb(II), Fe-containing hydroxyapatite selectivity depends on the relative [Pb]/[Cu] ratio, and waste bioorganic subtrates templeted Fe-containing hydroxyapatite, adsorbs both ions with similar capability.
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/170140
url http://sedici.unlp.edu.ar/handle/10915/170140
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1533-4899
info:eu-repo/semantics/altIdentifier/doi/10.1166/jnn.2017.13870
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
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reponame_str SEDICI (UNLP)
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instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
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