Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis

Autores
Mercado Castro, Donaldo Fabio; Magnacca, Giuliana; Malandrino, Mery; Rubert, Aldo Alberto; Montoneri, Enzo; Celi, Luisella; Bianco Prevot, Alessandra; Gonzalez, Monica Cristina
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This paper describes the synthesis of paramegnetic iron-containing hydroxyapatite nanoparticles and their increased Cu2+ sorbent capacity when using Ca2+ complexes of soluble bio-organic substrates from urban wastes as synthesis precursors. A thorough characterization of the particles by TEM, XRD, FTIR spectroscopy, specific surface area, TGA, XPS, and DLS, indicates that loss of crystallinity, a higher specific area, an increased surface oxygen content, and formation of surface iron phases strongly enhance Cu2+ adsorption capacity of hydroxyapatite-based materials. However, the major effect of the surface and morphologycal modifications is the size diminution of the aggregates formed in aqueous solutions leading to an increased effective surface available for Cu2+ adsorption. Maximum sorption values of 550 - 850 mg Cu2+ per gram of particles suspended in an aqueous solution at pH 7 were determined; almost 10 times the maximum values observed for hydroxyapatite nanoparticles suspensions under the same conditions.
Fil: Mercado Castro, Donaldo Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Magnacca, Giuliana. Universita Di Torino; Italia
Fil: Malandrino, Mery. Universita Di Torino; Italia
Fil: Rubert, Aldo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Montoneri, Enzo. Universita Di Torino; Italia
Fil: Celi, Luisella. Universita Di Torino; Italia
Fil: Bianco Prevot, Alessandra. Universita Di Torino; Italia
Fil: Gonzalez, Monica Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Materia
MAGNETIC NANOMATERIALS
CU2+ SORPTION
EFFECTIVE SURFACE
BIO-ORGANIC SUBSTRATES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5027
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/5027
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated SynthesisMercado Castro, Donaldo FabioMagnacca, GiulianaMalandrino, MeryRubert, Aldo AlbertoMontoneri, EnzoCeli, LuisellaBianco Prevot, AlessandraGonzalez, Monica CristinaMAGNETIC NANOMATERIALSCU2+ SORPTIONEFFECTIVE SURFACEBIO-ORGANIC SUBSTRATEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This paper describes the synthesis of paramegnetic iron-containing hydroxyapatite nanoparticles and their increased Cu2+ sorbent capacity when using Ca2+ complexes of soluble bio-organic substrates from urban wastes as synthesis precursors. A thorough characterization of the particles by TEM, XRD, FTIR spectroscopy, specific surface area, TGA, XPS, and DLS, indicates that loss of crystallinity, a higher specific area, an increased surface oxygen content, and formation of surface iron phases strongly enhance Cu2+ adsorption capacity of hydroxyapatite-based materials. However, the major effect of the surface and morphologycal modifications is the size diminution of the aggregates formed in aqueous solutions leading to an increased effective surface available for Cu2+ adsorption. Maximum sorption values of 550 - 850 mg Cu2+ per gram of particles suspended in an aqueous solution at pH 7 were determined; almost 10 times the maximum values observed for hydroxyapatite nanoparticles suspensions under the same conditions.Fil: Mercado Castro, Donaldo Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Magnacca, Giuliana. Universita Di Torino; ItaliaFil: Malandrino, Mery. Universita Di Torino; ItaliaFil: Rubert, Aldo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Montoneri, Enzo. Universita Di Torino; ItaliaFil: Celi, Luisella. Universita Di Torino; ItaliaFil: Bianco Prevot, Alessandra. Universita Di Torino; ItaliaFil: Gonzalez, Monica Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaAmerican Chemical Society2014-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5027Mercado Castro, Donaldo Fabio; Magnacca, Giuliana; Malandrino, Mery; Rubert, Aldo Alberto; Montoneri, Enzo; et al.; Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis; American Chemical Society; Acs Applied Materials & Interfaces; 6; 6; 2-2014; 3937–39461944-8244enginfo:eu-repo/semantics/altIdentifier/pmid/24588498info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/pdf/10.1021/am405217jinfo:eu-repo/semantics/altIdentifier/doi/10.1021/am405217jinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:03:58Zoai:ri.conicet.gov.ar:11336/5027instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:03:59.186CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis
title Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis
spellingShingle Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis
Mercado Castro, Donaldo Fabio
MAGNETIC NANOMATERIALS
CU2+ SORPTION
EFFECTIVE SURFACE
BIO-ORGANIC SUBSTRATES
title_short Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis
title_full Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis
title_fullStr Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis
title_full_unstemmed Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis
title_sort Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis
dc.creator.none.fl_str_mv Mercado Castro, Donaldo Fabio
Magnacca, Giuliana
Malandrino, Mery
Rubert, Aldo Alberto
Montoneri, Enzo
Celi, Luisella
Bianco Prevot, Alessandra
Gonzalez, Monica Cristina
author Mercado Castro, Donaldo Fabio
author_facet Mercado Castro, Donaldo Fabio
Magnacca, Giuliana
Malandrino, Mery
Rubert, Aldo Alberto
Montoneri, Enzo
Celi, Luisella
Bianco Prevot, Alessandra
Gonzalez, Monica Cristina
author_role author
author2 Magnacca, Giuliana
Malandrino, Mery
Rubert, Aldo Alberto
Montoneri, Enzo
Celi, Luisella
Bianco Prevot, Alessandra
Gonzalez, Monica Cristina
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv MAGNETIC NANOMATERIALS
CU2+ SORPTION
EFFECTIVE SURFACE
BIO-ORGANIC SUBSTRATES
topic MAGNETIC NANOMATERIALS
CU2+ SORPTION
EFFECTIVE SURFACE
BIO-ORGANIC SUBSTRATES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This paper describes the synthesis of paramegnetic iron-containing hydroxyapatite nanoparticles and their increased Cu2+ sorbent capacity when using Ca2+ complexes of soluble bio-organic substrates from urban wastes as synthesis precursors. A thorough characterization of the particles by TEM, XRD, FTIR spectroscopy, specific surface area, TGA, XPS, and DLS, indicates that loss of crystallinity, a higher specific area, an increased surface oxygen content, and formation of surface iron phases strongly enhance Cu2+ adsorption capacity of hydroxyapatite-based materials. However, the major effect of the surface and morphologycal modifications is the size diminution of the aggregates formed in aqueous solutions leading to an increased effective surface available for Cu2+ adsorption. Maximum sorption values of 550 - 850 mg Cu2+ per gram of particles suspended in an aqueous solution at pH 7 were determined; almost 10 times the maximum values observed for hydroxyapatite nanoparticles suspensions under the same conditions.
Fil: Mercado Castro, Donaldo Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Magnacca, Giuliana. Universita Di Torino; Italia
Fil: Malandrino, Mery. Universita Di Torino; Italia
Fil: Rubert, Aldo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Montoneri, Enzo. Universita Di Torino; Italia
Fil: Celi, Luisella. Universita Di Torino; Italia
Fil: Bianco Prevot, Alessandra. Universita Di Torino; Italia
Fil: Gonzalez, Monica Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
description This paper describes the synthesis of paramegnetic iron-containing hydroxyapatite nanoparticles and their increased Cu2+ sorbent capacity when using Ca2+ complexes of soluble bio-organic substrates from urban wastes as synthesis precursors. A thorough characterization of the particles by TEM, XRD, FTIR spectroscopy, specific surface area, TGA, XPS, and DLS, indicates that loss of crystallinity, a higher specific area, an increased surface oxygen content, and formation of surface iron phases strongly enhance Cu2+ adsorption capacity of hydroxyapatite-based materials. However, the major effect of the surface and morphologycal modifications is the size diminution of the aggregates formed in aqueous solutions leading to an increased effective surface available for Cu2+ adsorption. Maximum sorption values of 550 - 850 mg Cu2+ per gram of particles suspended in an aqueous solution at pH 7 were determined; almost 10 times the maximum values observed for hydroxyapatite nanoparticles suspensions under the same conditions.
publishDate 2014
dc.date.none.fl_str_mv 2014-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5027
Mercado Castro, Donaldo Fabio; Magnacca, Giuliana; Malandrino, Mery; Rubert, Aldo Alberto; Montoneri, Enzo; et al.; Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis; American Chemical Society; Acs Applied Materials & Interfaces; 6; 6; 2-2014; 3937–3946
1944-8244
url http://hdl.handle.net/11336/5027
identifier_str_mv Mercado Castro, Donaldo Fabio; Magnacca, Giuliana; Malandrino, Mery; Rubert, Aldo Alberto; Montoneri, Enzo; et al.; Paramagnetic Iron-Doped Hydroxyapatite Nanoparticles with Improved Metal Sorption Properties. A Bio-Organic Substrates-Mediated Synthesis; American Chemical Society; Acs Applied Materials & Interfaces; 6; 6; 2-2014; 3937–3946
1944-8244
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/pmid/24588498
info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/pdf/10.1021/am405217j
info:eu-repo/semantics/altIdentifier/doi/10.1021/am405217j
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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