Novel Copolymer of Diisopropyl Fumarate and Benzyl Acrylate Synthesized Under Microwave Energy and Quasielastic Light Scattering Measurements

Autores
Oberti, Tamara Gisela; Cortizo, María Cecilia; Alessandrini, José Luis
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Microwave assisted free radical copolymerization of diisopropyl fumarate (DIPF) and benzyl acrylate (BzA) with different copolymer compositions was performed using benzoyl peroxide as initiator. The effect of the reaction conditions on the macromolecular characteristics, monomer reactivity ratio and copolymer properties were studied. The monomer conversion and average molecular weights increase with the content of BzA units in the copolymer. The copolymers were characterized by IR, ¹H and ¹³C-NMR spectroscopies and the molecular weights were analyzed with size exclusion chromatography (SEC). The reactivity ratios obtained from an extended Kelen-Tüdös method under microwave irradiations are a factor which is double than those obtained by thermal copolymerization. The product r₁r₂ = 0.152 suggests a preference of both propagating macroradicals toward consecutive homopolymerization. The hydrodynamic and polydispersity size were measured in ethylacetate, tetrahydrofuran and methylethylketone with a quasi-elastic light scattering (QELS) technique showing that the quality of the solvents increases in the order: EA < THF < MEK.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Instituto de Física La Plata
Materia
Química
Física
copolymer
microwave
diisopropyl fumarate
benzyl acrylate
quasielastic light scattering
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/164056
Acceder
id SEDICI_9011aac04e05df9cb42bc41753c0cfbd
oai_identifier_str oai:sedici.unlp.edu.ar:10915/164056
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Novel Copolymer of Diisopropyl Fumarate and Benzyl Acrylate Synthesized Under Microwave Energy and Quasielastic Light Scattering MeasurementsOberti, Tamara GiselaCortizo, María CeciliaAlessandrini, José LuisQuímicaFísicacopolymermicrowavediisopropyl fumaratebenzyl acrylatequasielastic light scatteringMicrowave assisted free radical copolymerization of diisopropyl fumarate (DIPF) and benzyl acrylate (BzA) with different copolymer compositions was performed using benzoyl peroxide as initiator. The effect of the reaction conditions on the macromolecular characteristics, monomer reactivity ratio and copolymer properties were studied. The monomer conversion and average molecular weights increase with the content of BzA units in the copolymer. The copolymers were characterized by IR, ¹H and ¹³C-NMR spectroscopies and the molecular weights were analyzed with size exclusion chromatography (SEC). The reactivity ratios obtained from an extended Kelen-Tüdös method under microwave irradiations are a factor which is double than those obtained by thermal copolymerization. The product r₁r₂ = 0.152 suggests a preference of both propagating macroradicals toward consecutive homopolymerization. The hydrodynamic and polydispersity size were measured in ethylacetate, tetrahydrofuran and methylethylketone with a quasi-elastic light scattering (QELS) technique showing that the quality of the solvents increases in the order: EA &lt; THF &lt; MEK.Instituto de Investigaciones Fisicoquímicas Teóricas y AplicadasInstituto de Física La Plata2010info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf725-731http://sedici.unlp.edu.ar/handle/10915/164056enginfo:eu-repo/semantics/altIdentifier/issn/1060-1325info:eu-repo/semantics/altIdentifier/issn/1520-5738info:eu-repo/semantics/altIdentifier/doi/10.1080/10601325.2010.483407info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:43:11Zoai:sedici.unlp.edu.ar:10915/164056Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:43:11.345SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Novel Copolymer of Diisopropyl Fumarate and Benzyl Acrylate Synthesized Under Microwave Energy and Quasielastic Light Scattering Measurements
title Novel Copolymer of Diisopropyl Fumarate and Benzyl Acrylate Synthesized Under Microwave Energy and Quasielastic Light Scattering Measurements
spellingShingle Novel Copolymer of Diisopropyl Fumarate and Benzyl Acrylate Synthesized Under Microwave Energy and Quasielastic Light Scattering Measurements
Oberti, Tamara Gisela
Química
Física
copolymer
microwave
diisopropyl fumarate
benzyl acrylate
quasielastic light scattering
title_short Novel Copolymer of Diisopropyl Fumarate and Benzyl Acrylate Synthesized Under Microwave Energy and Quasielastic Light Scattering Measurements
title_full Novel Copolymer of Diisopropyl Fumarate and Benzyl Acrylate Synthesized Under Microwave Energy and Quasielastic Light Scattering Measurements
title_fullStr Novel Copolymer of Diisopropyl Fumarate and Benzyl Acrylate Synthesized Under Microwave Energy and Quasielastic Light Scattering Measurements
title_full_unstemmed Novel Copolymer of Diisopropyl Fumarate and Benzyl Acrylate Synthesized Under Microwave Energy and Quasielastic Light Scattering Measurements
title_sort Novel Copolymer of Diisopropyl Fumarate and Benzyl Acrylate Synthesized Under Microwave Energy and Quasielastic Light Scattering Measurements
dc.creator.none.fl_str_mv Oberti, Tamara Gisela
Cortizo, María Cecilia
Alessandrini, José Luis
author Oberti, Tamara Gisela
author_facet Oberti, Tamara Gisela
Cortizo, María Cecilia
Alessandrini, José Luis
author_role author
author2 Cortizo, María Cecilia
Alessandrini, José Luis
author2_role author
author
dc.subject.none.fl_str_mv Química
Física
copolymer
microwave
diisopropyl fumarate
benzyl acrylate
quasielastic light scattering
topic Química
Física
copolymer
microwave
diisopropyl fumarate
benzyl acrylate
quasielastic light scattering
dc.description.none.fl_txt_mv Microwave assisted free radical copolymerization of diisopropyl fumarate (DIPF) and benzyl acrylate (BzA) with different copolymer compositions was performed using benzoyl peroxide as initiator. The effect of the reaction conditions on the macromolecular characteristics, monomer reactivity ratio and copolymer properties were studied. The monomer conversion and average molecular weights increase with the content of BzA units in the copolymer. The copolymers were characterized by IR, ¹H and ¹³C-NMR spectroscopies and the molecular weights were analyzed with size exclusion chromatography (SEC). The reactivity ratios obtained from an extended Kelen-Tüdös method under microwave irradiations are a factor which is double than those obtained by thermal copolymerization. The product r₁r₂ = 0.152 suggests a preference of both propagating macroradicals toward consecutive homopolymerization. The hydrodynamic and polydispersity size were measured in ethylacetate, tetrahydrofuran and methylethylketone with a quasi-elastic light scattering (QELS) technique showing that the quality of the solvents increases in the order: EA &lt; THF &lt; MEK.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Instituto de Física La Plata
description Microwave assisted free radical copolymerization of diisopropyl fumarate (DIPF) and benzyl acrylate (BzA) with different copolymer compositions was performed using benzoyl peroxide as initiator. The effect of the reaction conditions on the macromolecular characteristics, monomer reactivity ratio and copolymer properties were studied. The monomer conversion and average molecular weights increase with the content of BzA units in the copolymer. The copolymers were characterized by IR, ¹H and ¹³C-NMR spectroscopies and the molecular weights were analyzed with size exclusion chromatography (SEC). The reactivity ratios obtained from an extended Kelen-Tüdös method under microwave irradiations are a factor which is double than those obtained by thermal copolymerization. The product r₁r₂ = 0.152 suggests a preference of both propagating macroradicals toward consecutive homopolymerization. The hydrodynamic and polydispersity size were measured in ethylacetate, tetrahydrofuran and methylethylketone with a quasi-elastic light scattering (QELS) technique showing that the quality of the solvents increases in the order: EA &lt; THF &lt; MEK.
publishDate 2010
dc.date.none.fl_str_mv 2010
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/164056
url http://sedici.unlp.edu.ar/handle/10915/164056
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1060-1325
info:eu-repo/semantics/altIdentifier/issn/1520-5738
info:eu-repo/semantics/altIdentifier/doi/10.1080/10601325.2010.483407
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
725-731
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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