Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy

Autores
Oberti, Tamara Gisela; Alessandrini, José Luis; Cortizo, María Susana
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Copolymers of p-nitrobenzyl acrylate and diisopropyl fumarate with different feed ratios were synthesized under microwave and thermal heating conditions, and then characterized by IR, ¹H-, and ¹³C-NMR spectroscopy. Average molecular weights were analyzed by size exclusion chromatography (SEC). Monomer reactivity ratios were obtained from an extended Kelen–Tüdös method. Differential scanning calorimetry and thermogravimetry were used to evaluate the thermal behavior of all copolymers synthesized under microwave energy. Based on the products analyzed by SEC and gas chromatography–mass spectrometry, a possible mechanism of degradation is postulated.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Instituto de Física La Plata
Materia
Química
Física
p-nitrobenzyl acrylate
glass transition temperature
microwave polymerization
thermogravimetry analysis
thermal degradation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/164025
Acceder
id SEDICI_119ed3b17b82fd3928b7ad24536f0d0d
oai_identifier_str oai:sedici.unlp.edu.ar:10915/164025
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energyOberti, Tamara GiselaAlessandrini, José LuisCortizo, María SusanaQuímicaFísicap-nitrobenzyl acrylateglass transition temperaturemicrowave polymerizationthermogravimetry analysisthermal degradationCopolymers of p-nitrobenzyl acrylate and diisopropyl fumarate with different feed ratios were synthesized under microwave and thermal heating conditions, and then characterized by IR, ¹H-, and ¹³C-NMR spectroscopy. Average molecular weights were analyzed by size exclusion chromatography (SEC). Monomer reactivity ratios were obtained from an extended Kelen–Tüdös method. Differential scanning calorimetry and thermogravimetry were used to evaluate the thermal behavior of all copolymers synthesized under microwave energy. Based on the products analyzed by SEC and gas chromatography–mass spectrometry, a possible mechanism of degradation is postulated.Instituto de Investigaciones Fisicoquímicas Teóricas y AplicadasInstituto de Física La Plata2012-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1525-1531http://sedici.unlp.edu.ar/handle/10915/164025enginfo:eu-repo/semantics/altIdentifier/issn/1388-6150info:eu-repo/semantics/altIdentifier/issn/1572-8943info:eu-repo/semantics/altIdentifier/doi/10.1007/s10973-011-1917-7info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:34:57Zoai:sedici.unlp.edu.ar:10915/164025Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:34:57.939SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy
title Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy
spellingShingle Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy
Oberti, Tamara Gisela
Química
Física
p-nitrobenzyl acrylate
glass transition temperature
microwave polymerization
thermogravimetry analysis
thermal degradation
title_short Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy
title_full Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy
title_fullStr Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy
title_full_unstemmed Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy
title_sort Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy
dc.creator.none.fl_str_mv Oberti, Tamara Gisela
Alessandrini, José Luis
Cortizo, María Susana
author Oberti, Tamara Gisela
author_facet Oberti, Tamara Gisela
Alessandrini, José Luis
Cortizo, María Susana
author_role author
author2 Alessandrini, José Luis
Cortizo, María Susana
author2_role author
author
dc.subject.none.fl_str_mv Química
Física
p-nitrobenzyl acrylate
glass transition temperature
microwave polymerization
thermogravimetry analysis
thermal degradation
topic Química
Física
p-nitrobenzyl acrylate
glass transition temperature
microwave polymerization
thermogravimetry analysis
thermal degradation
dc.description.none.fl_txt_mv Copolymers of p-nitrobenzyl acrylate and diisopropyl fumarate with different feed ratios were synthesized under microwave and thermal heating conditions, and then characterized by IR, ¹H-, and ¹³C-NMR spectroscopy. Average molecular weights were analyzed by size exclusion chromatography (SEC). Monomer reactivity ratios were obtained from an extended Kelen–Tüdös method. Differential scanning calorimetry and thermogravimetry were used to evaluate the thermal behavior of all copolymers synthesized under microwave energy. Based on the products analyzed by SEC and gas chromatography–mass spectrometry, a possible mechanism of degradation is postulated.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Instituto de Física La Plata
description Copolymers of p-nitrobenzyl acrylate and diisopropyl fumarate with different feed ratios were synthesized under microwave and thermal heating conditions, and then characterized by IR, ¹H-, and ¹³C-NMR spectroscopy. Average molecular weights were analyzed by size exclusion chromatography (SEC). Monomer reactivity ratios were obtained from an extended Kelen–Tüdös method. Differential scanning calorimetry and thermogravimetry were used to evaluate the thermal behavior of all copolymers synthesized under microwave energy. Based on the products analyzed by SEC and gas chromatography–mass spectrometry, a possible mechanism of degradation is postulated.
publishDate 2012
dc.date.none.fl_str_mv 2012-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/164025
url http://sedici.unlp.edu.ar/handle/10915/164025
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1388-6150
info:eu-repo/semantics/altIdentifier/issn/1572-8943
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10973-011-1917-7
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
1525-1531
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.22299

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