Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy
- Autores
- Oberti, Tamara Gisela; Alessandrini, José Luis; Cortizo, María Susana
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Copolymers of p-nitrobenzyl acrylate and diisopropyl fumarate with different feed ratios were synthesized under microwave and thermal heating conditions, and then characterized by IR, ¹H-, and ¹³C-NMR spectroscopy. Average molecular weights were analyzed by size exclusion chromatography (SEC). Monomer reactivity ratios were obtained from an extended Kelen–Tüdös method. Differential scanning calorimetry and thermogravimetry were used to evaluate the thermal behavior of all copolymers synthesized under microwave energy. Based on the products analyzed by SEC and gas chromatography–mass spectrometry, a possible mechanism of degradation is postulated.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Instituto de Física La Plata - Materia
-
Química
Física
p-nitrobenzyl acrylate
glass transition temperature
microwave polymerization
thermogravimetry analysis
thermal degradation - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/164025
Ver los metadatos del registro completo
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spelling |
Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energyOberti, Tamara GiselaAlessandrini, José LuisCortizo, María SusanaQuímicaFísicap-nitrobenzyl acrylateglass transition temperaturemicrowave polymerizationthermogravimetry analysisthermal degradationCopolymers of p-nitrobenzyl acrylate and diisopropyl fumarate with different feed ratios were synthesized under microwave and thermal heating conditions, and then characterized by IR, ¹H-, and ¹³C-NMR spectroscopy. Average molecular weights were analyzed by size exclusion chromatography (SEC). Monomer reactivity ratios were obtained from an extended Kelen–Tüdös method. Differential scanning calorimetry and thermogravimetry were used to evaluate the thermal behavior of all copolymers synthesized under microwave energy. Based on the products analyzed by SEC and gas chromatography–mass spectrometry, a possible mechanism of degradation is postulated.Instituto de Investigaciones Fisicoquímicas Teóricas y AplicadasInstituto de Física La Plata2012-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1525-1531http://sedici.unlp.edu.ar/handle/10915/164025enginfo:eu-repo/semantics/altIdentifier/issn/1388-6150info:eu-repo/semantics/altIdentifier/issn/1572-8943info:eu-repo/semantics/altIdentifier/doi/10.1007/s10973-011-1917-7info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:43:11Zoai:sedici.unlp.edu.ar:10915/164025Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:43:11.281SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy |
title |
Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy |
spellingShingle |
Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy Oberti, Tamara Gisela Química Física p-nitrobenzyl acrylate glass transition temperature microwave polymerization thermogravimetry analysis thermal degradation |
title_short |
Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy |
title_full |
Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy |
title_fullStr |
Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy |
title_full_unstemmed |
Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy |
title_sort |
Thermal characterization of novel p-nitrobenzylacrylate–diisopropyl fumarate copolymer synthesized under microwave energy |
dc.creator.none.fl_str_mv |
Oberti, Tamara Gisela Alessandrini, José Luis Cortizo, María Susana |
author |
Oberti, Tamara Gisela |
author_facet |
Oberti, Tamara Gisela Alessandrini, José Luis Cortizo, María Susana |
author_role |
author |
author2 |
Alessandrini, José Luis Cortizo, María Susana |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Química Física p-nitrobenzyl acrylate glass transition temperature microwave polymerization thermogravimetry analysis thermal degradation |
topic |
Química Física p-nitrobenzyl acrylate glass transition temperature microwave polymerization thermogravimetry analysis thermal degradation |
dc.description.none.fl_txt_mv |
Copolymers of p-nitrobenzyl acrylate and diisopropyl fumarate with different feed ratios were synthesized under microwave and thermal heating conditions, and then characterized by IR, ¹H-, and ¹³C-NMR spectroscopy. Average molecular weights were analyzed by size exclusion chromatography (SEC). Monomer reactivity ratios were obtained from an extended Kelen–Tüdös method. Differential scanning calorimetry and thermogravimetry were used to evaluate the thermal behavior of all copolymers synthesized under microwave energy. Based on the products analyzed by SEC and gas chromatography–mass spectrometry, a possible mechanism of degradation is postulated. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas Instituto de Física La Plata |
description |
Copolymers of p-nitrobenzyl acrylate and diisopropyl fumarate with different feed ratios were synthesized under microwave and thermal heating conditions, and then characterized by IR, ¹H-, and ¹³C-NMR spectroscopy. Average molecular weights were analyzed by size exclusion chromatography (SEC). Monomer reactivity ratios were obtained from an extended Kelen–Tüdös method. Differential scanning calorimetry and thermogravimetry were used to evaluate the thermal behavior of all copolymers synthesized under microwave energy. Based on the products analyzed by SEC and gas chromatography–mass spectrometry, a possible mechanism of degradation is postulated. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/164025 |
url |
http://sedici.unlp.edu.ar/handle/10915/164025 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/1388-6150 info:eu-repo/semantics/altIdentifier/issn/1572-8943 info:eu-repo/semantics/altIdentifier/doi/10.1007/s10973-011-1917-7 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
dc.format.none.fl_str_mv |
application/pdf 1525-1531 |
dc.source.none.fl_str_mv |
reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
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Universidad Nacional de La Plata |
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UNLP |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
repository.mail.fl_str_mv |
alira@sedici.unlp.edu.ar |
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score |
13.070432 |