Electrochemical and ellipsometric data related to the formation of soluble silver (I) during the potentiodynamic polarization of polycrystalline silver in basic solutions
- Autores
- Zerbino, Jorge Omar; Lopez Teijelo, Manuel; Vilche, Jorge Roberto; Arvia, Alejandro Jorge
- Año de publicación
- 1985
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Soluble Ag(I) species is formed in the early stages of voltammetric silver electrooxidation in 0.1 M NaOH and 0.1 M NaOH + 1 M NaClO4 solutions at 25°C, as demonstrated by the rotating ring-disc technique. This result allows a reasonable interpretation of ellipsometric data obtained for the anodization of silver under different voltammetric conditions. Correspondingly, two anodic layers of different optical constants are electroformed. The hydrous Ag(I) oxide layer behaves as a porous structure with an average thickness of about 2.5 times greater than that of the anhydrous oxide.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas - Materia
-
Ciencias Exactas
Química
Electrochemical data
Ellipsometric data
Silver - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/119402
Ver los metadatos del registro completo
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Electrochemical and ellipsometric data related to the formation of soluble silver (I) during the potentiodynamic polarization of polycrystalline silver in basic solutionsZerbino, Jorge OmarLopez Teijelo, ManuelVilche, Jorge RobertoArvia, Alejandro JorgeCiencias ExactasQuímicaElectrochemical dataEllipsometric dataSilverSoluble Ag(I) species is formed in the early stages of voltammetric silver electrooxidation in 0.1 M NaOH and 0.1 M NaOH + 1 M NaClO<sub>4</sub> solutions at 25°C, as demonstrated by the rotating ring-disc technique. This result allows a reasonable interpretation of ellipsometric data obtained for the anodization of silver under different voltammetric conditions. Correspondingly, two anodic layers of different optical constants are electroformed. The hydrous Ag(I) oxide layer behaves as a porous structure with an average thickness of about 2.5 times greater than that of the anhydrous oxide.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1985info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1521-1525http://sedici.unlp.edu.ar/handle/10915/119402enginfo:eu-repo/semantics/altIdentifier/issn/0013-4686info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(85)80014-1info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:28:10Zoai:sedici.unlp.edu.ar:10915/119402Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:28:10.706SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Electrochemical and ellipsometric data related to the formation of soluble silver (I) during the potentiodynamic polarization of polycrystalline silver in basic solutions |
title |
Electrochemical and ellipsometric data related to the formation of soluble silver (I) during the potentiodynamic polarization of polycrystalline silver in basic solutions |
spellingShingle |
Electrochemical and ellipsometric data related to the formation of soluble silver (I) during the potentiodynamic polarization of polycrystalline silver in basic solutions Zerbino, Jorge Omar Ciencias Exactas Química Electrochemical data Ellipsometric data Silver |
title_short |
Electrochemical and ellipsometric data related to the formation of soluble silver (I) during the potentiodynamic polarization of polycrystalline silver in basic solutions |
title_full |
Electrochemical and ellipsometric data related to the formation of soluble silver (I) during the potentiodynamic polarization of polycrystalline silver in basic solutions |
title_fullStr |
Electrochemical and ellipsometric data related to the formation of soluble silver (I) during the potentiodynamic polarization of polycrystalline silver in basic solutions |
title_full_unstemmed |
Electrochemical and ellipsometric data related to the formation of soluble silver (I) during the potentiodynamic polarization of polycrystalline silver in basic solutions |
title_sort |
Electrochemical and ellipsometric data related to the formation of soluble silver (I) during the potentiodynamic polarization of polycrystalline silver in basic solutions |
dc.creator.none.fl_str_mv |
Zerbino, Jorge Omar Lopez Teijelo, Manuel Vilche, Jorge Roberto Arvia, Alejandro Jorge |
author |
Zerbino, Jorge Omar |
author_facet |
Zerbino, Jorge Omar Lopez Teijelo, Manuel Vilche, Jorge Roberto Arvia, Alejandro Jorge |
author_role |
author |
author2 |
Lopez Teijelo, Manuel Vilche, Jorge Roberto Arvia, Alejandro Jorge |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Ciencias Exactas Química Electrochemical data Ellipsometric data Silver |
topic |
Ciencias Exactas Química Electrochemical data Ellipsometric data Silver |
dc.description.none.fl_txt_mv |
Soluble Ag(I) species is formed in the early stages of voltammetric silver electrooxidation in 0.1 M NaOH and 0.1 M NaOH + 1 M NaClO<sub>4</sub> solutions at 25°C, as demonstrated by the rotating ring-disc technique. This result allows a reasonable interpretation of ellipsometric data obtained for the anodization of silver under different voltammetric conditions. Correspondingly, two anodic layers of different optical constants are electroformed. The hydrous Ag(I) oxide layer behaves as a porous structure with an average thickness of about 2.5 times greater than that of the anhydrous oxide. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
description |
Soluble Ag(I) species is formed in the early stages of voltammetric silver electrooxidation in 0.1 M NaOH and 0.1 M NaOH + 1 M NaClO<sub>4</sub> solutions at 25°C, as demonstrated by the rotating ring-disc technique. This result allows a reasonable interpretation of ellipsometric data obtained for the anodization of silver under different voltammetric conditions. Correspondingly, two anodic layers of different optical constants are electroformed. The hydrous Ag(I) oxide layer behaves as a porous structure with an average thickness of about 2.5 times greater than that of the anhydrous oxide. |
publishDate |
1985 |
dc.date.none.fl_str_mv |
1985 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/119402 |
url |
http://sedici.unlp.edu.ar/handle/10915/119402 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/0013-4686 info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(85)80014-1 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
dc.format.none.fl_str_mv |
application/pdf 1521-1525 |
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reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
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SEDICI (UNLP) |
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Universidad Nacional de La Plata |
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UNLP |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
repository.mail.fl_str_mv |
alira@sedici.unlp.edu.ar |
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score |
13.070432 |