Spectroscopic and magnetic properties of a Ni(II) complex with citric acid

Autores
Bovi Mitre, M. G.; Wierna, Norma Rosario; Wagner, Claudia Cecilia; Baran, Enrique José
Año de publicación
2000
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The complex compound K₂[Ni(cit)(H₂O)₂]₂·4H₂O (cit = triionized citrate ion) seems to be a good model for the investigation of Ni(II)/citrate interactions that are of interest in relation to nickel metabolism and bioaccumulation. Its infrared and Raman spectra were recorded and analyzed on the basis of its structural peculiarities. The magnetic susceptibility, investigated in the temperature range between 1.9 and 300 K, shows the absence of magnetic interactions between the two metal centers present in this structure.
Centro de Química Inorgánica
Materia
Química
Nickel
Citrate
Raman spectrum
IR spectrum
Magnetic susceptibility
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/146411
Acceder
id SEDICI_793dce8389b0106b5d93ae5525ab1cf2
oai_identifier_str oai:sedici.unlp.edu.ar:10915/146411
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Spectroscopic and magnetic properties of a Ni(II) complex with citric acidBovi Mitre, M. G.Wierna, Norma RosarioWagner, Claudia CeciliaBaran, Enrique JoséQuímicaNickelCitrateRaman spectrumIR spectrumMagnetic susceptibilityThe complex compound K₂[Ni(cit)(H₂O)₂]₂·4H₂O (cit = triionized citrate ion) seems to be a good model for the investigation of Ni(II)/citrate interactions that are of interest in relation to nickel metabolism and bioaccumulation. Its infrared and Raman spectra were recorded and analyzed on the basis of its structural peculiarities. The magnetic susceptibility, investigated in the temperature range between 1.9 and 300 K, shows the absence of magnetic interactions between the two metal centers present in this structure.Centro de Química Inorgánica2000info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf183-190http://sedici.unlp.edu.ar/handle/10915/146411enginfo:eu-repo/semantics/altIdentifier/issn/0163-4984info:eu-repo/semantics/altIdentifier/issn/1559-0720info:eu-repo/semantics/altIdentifier/doi/10.1385/bter:76:2:183info:eu-repo/semantics/altIdentifier/pmid/11049232info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:32:26Zoai:sedici.unlp.edu.ar:10915/146411Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:32:27.06SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
title Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
spellingShingle Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
Bovi Mitre, M. G.
Química
Nickel
Citrate
Raman spectrum
IR spectrum
Magnetic susceptibility
title_short Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
title_full Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
title_fullStr Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
title_full_unstemmed Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
title_sort Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
dc.creator.none.fl_str_mv Bovi Mitre, M. G.
Wierna, Norma Rosario
Wagner, Claudia Cecilia
Baran, Enrique José
author Bovi Mitre, M. G.
author_facet Bovi Mitre, M. G.
Wierna, Norma Rosario
Wagner, Claudia Cecilia
Baran, Enrique José
author_role author
author2 Wierna, Norma Rosario
Wagner, Claudia Cecilia
Baran, Enrique José
author2_role author
author
author
dc.subject.none.fl_str_mv Química
Nickel
Citrate
Raman spectrum
IR spectrum
Magnetic susceptibility
topic Química
Nickel
Citrate
Raman spectrum
IR spectrum
Magnetic susceptibility
dc.description.none.fl_txt_mv The complex compound K₂[Ni(cit)(H₂O)₂]₂·4H₂O (cit = triionized citrate ion) seems to be a good model for the investigation of Ni(II)/citrate interactions that are of interest in relation to nickel metabolism and bioaccumulation. Its infrared and Raman spectra were recorded and analyzed on the basis of its structural peculiarities. The magnetic susceptibility, investigated in the temperature range between 1.9 and 300 K, shows the absence of magnetic interactions between the two metal centers present in this structure.
Centro de Química Inorgánica
description The complex compound K₂[Ni(cit)(H₂O)₂]₂·4H₂O (cit = triionized citrate ion) seems to be a good model for the investigation of Ni(II)/citrate interactions that are of interest in relation to nickel metabolism and bioaccumulation. Its infrared and Raman spectra were recorded and analyzed on the basis of its structural peculiarities. The magnetic susceptibility, investigated in the temperature range between 1.9 and 300 K, shows the absence of magnetic interactions between the two metal centers present in this structure.
publishDate 2000
dc.date.none.fl_str_mv 2000
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/146411
url http://sedici.unlp.edu.ar/handle/10915/146411
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0163-4984
info:eu-repo/semantics/altIdentifier/issn/1559-0720
info:eu-repo/semantics/altIdentifier/doi/10.1385/bter:76:2:183
info:eu-repo/semantics/altIdentifier/pmid/11049232
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
183-190
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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