One-electron oxidation of antioxidants: A kinetic-thermodynamic correlation
- Autores
- Villata, Laura Sofía; Berkovic, Andrea; González, Mónica Cristina; Mártire, Daniel Osvaldo
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The values of the bimolecular rate constants for the reactions of 2,2′-azino-bis(3-ethylbenz-thiazoline-6-sulfonic acid) radical cation with epicatechin (((2.4 ± 0.2)) s−1 M−1), and epigallocatechingallate ((29 ± 5) s−1 M−1) were obtained by spectrophotometric measurements. We propose a correlation between the Gibbs energy ΔGº for the one-electron charge-transfer reactions from several antioxidants to radical species and the rate constants of the corresponding bimolecular reactions. This correlation can be used to predict rate constants of reactions of known ΔGº values.
Facultad de Ciencias Exactas
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas - Materia
-
Ciencias Exactas
Física
Química
ABTS
antioxidants
epicatechin
epigallocatechingallate
kinetic-thermodynamic correlation - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/106565
Ver los metadatos del registro completo
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One-electron oxidation of antioxidants: A kinetic-thermodynamic correlationVillata, Laura SofíaBerkovic, AndreaGonzález, Mónica CristinaMártire, Daniel OsvaldoCiencias ExactasFísicaQuímicaABTSantioxidantsepicatechinepigallocatechingallatekinetic-thermodynamic correlationThe values of the bimolecular rate constants for the reactions of 2,2′-azino-bis(3-ethylbenz-thiazoline-6-sulfonic acid) radical cation with epicatechin (((2.4 ± 0.2)) s<sup>−1</sup> M<sup>−1</sup>), and epigallocatechingallate ((29 ± 5) s<sup>−1</sup> M<sup>−1</sup>) were obtained by spectrophotometric measurements. We propose a correlation between the Gibbs energy ΔGº for the one-electron charge-transfer reactions from several antioxidants to radical species and the rate constants of the corresponding bimolecular reactions. This correlation can be used to predict rate constants of reactions of known ΔGº values.Facultad de Ciencias ExactasInstituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2013info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf205-209http://sedici.unlp.edu.ar/handle/10915/106565enginfo:eu-repo/semantics/altIdentifier/url/http://europepmc.org/backend/ptpmcrender.fcgi?accid=PMC6837577&blobtype=pdfinfo:eu-repo/semantics/altIdentifier/issn/1743-2928info:eu-repo/semantics/altIdentifier/pmid/24020720info:eu-repo/semantics/altIdentifier/doi/10.1179/1351000213Y.0000000063info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:23:52Zoai:sedici.unlp.edu.ar:10915/106565Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:23:53.066SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
One-electron oxidation of antioxidants: A kinetic-thermodynamic correlation |
title |
One-electron oxidation of antioxidants: A kinetic-thermodynamic correlation |
spellingShingle |
One-electron oxidation of antioxidants: A kinetic-thermodynamic correlation Villata, Laura Sofía Ciencias Exactas Física Química ABTS antioxidants epicatechin epigallocatechingallate kinetic-thermodynamic correlation |
title_short |
One-electron oxidation of antioxidants: A kinetic-thermodynamic correlation |
title_full |
One-electron oxidation of antioxidants: A kinetic-thermodynamic correlation |
title_fullStr |
One-electron oxidation of antioxidants: A kinetic-thermodynamic correlation |
title_full_unstemmed |
One-electron oxidation of antioxidants: A kinetic-thermodynamic correlation |
title_sort |
One-electron oxidation of antioxidants: A kinetic-thermodynamic correlation |
dc.creator.none.fl_str_mv |
Villata, Laura Sofía Berkovic, Andrea González, Mónica Cristina Mártire, Daniel Osvaldo |
author |
Villata, Laura Sofía |
author_facet |
Villata, Laura Sofía Berkovic, Andrea González, Mónica Cristina Mártire, Daniel Osvaldo |
author_role |
author |
author2 |
Berkovic, Andrea González, Mónica Cristina Mártire, Daniel Osvaldo |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Ciencias Exactas Física Química ABTS antioxidants epicatechin epigallocatechingallate kinetic-thermodynamic correlation |
topic |
Ciencias Exactas Física Química ABTS antioxidants epicatechin epigallocatechingallate kinetic-thermodynamic correlation |
dc.description.none.fl_txt_mv |
The values of the bimolecular rate constants for the reactions of 2,2′-azino-bis(3-ethylbenz-thiazoline-6-sulfonic acid) radical cation with epicatechin (((2.4 ± 0.2)) s<sup>−1</sup> M<sup>−1</sup>), and epigallocatechingallate ((29 ± 5) s<sup>−1</sup> M<sup>−1</sup>) were obtained by spectrophotometric measurements. We propose a correlation between the Gibbs energy ΔGº for the one-electron charge-transfer reactions from several antioxidants to radical species and the rate constants of the corresponding bimolecular reactions. This correlation can be used to predict rate constants of reactions of known ΔGº values. Facultad de Ciencias Exactas Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
description |
The values of the bimolecular rate constants for the reactions of 2,2′-azino-bis(3-ethylbenz-thiazoline-6-sulfonic acid) radical cation with epicatechin (((2.4 ± 0.2)) s<sup>−1</sup> M<sup>−1</sup>), and epigallocatechingallate ((29 ± 5) s<sup>−1</sup> M<sup>−1</sup>) were obtained by spectrophotometric measurements. We propose a correlation between the Gibbs energy ΔGº for the one-electron charge-transfer reactions from several antioxidants to radical species and the rate constants of the corresponding bimolecular reactions. This correlation can be used to predict rate constants of reactions of known ΔGº values. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/106565 |
url |
http://sedici.unlp.edu.ar/handle/10915/106565 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
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dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
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openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
dc.format.none.fl_str_mv |
application/pdf 205-209 |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
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