Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative

Autores
Sánchez, Laura Mabel; Sathicq, Ángel Gabriel; Baronetti, Graciela Teresita; Thomas, Horacio Jorge; Romanelli, Gustavo Pablo
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
H7P2W17VO62.25H2O Wells-Dawson heteropolyacid was prepared, characterized and evaluated as catalyst in a 1,4-dihydropyridine oxidation reaction. The optimal conditions are the following: 1 mmol% of HWDV, a molar ratio 1,4-DHP:H2O2 (1:10) at reflux of acetonitrile. A conversion of 98.6 % is achieved in only 120 min of reaction.
Centro de Investigación y Desarrollo en Ciencias Aplicadas
Planta Piloto Multipropósito - Laboratorio de Servicios a la Industria y al Sistema Científico
Materia
Química
Ciencias Exactas
Heteropolyacid
Oxidation
1,4-dihydropyridine
Hydrogen peroxide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/138848
Acceder
id SEDICI_5a2a96266523510df3dd9df065ecb24c
oai_identifier_str oai:sedici.unlp.edu.ar:10915/138848
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine DerivativeSánchez, Laura MabelSathicq, Ángel GabrielBaronetti, Graciela TeresitaThomas, Horacio JorgeRomanelli, Gustavo PabloQuímicaCiencias ExactasHeteropolyacidOxidation1,4-dihydropyridineHydrogen peroxideH7P2W17VO62.25H2O Wells-Dawson heteropolyacid was prepared, characterized and evaluated as catalyst in a 1,4-dihydropyridine oxidation reaction. The optimal conditions are the following: 1 mmol% of HWDV, a molar ratio 1,4-DHP:H2O2 (1:10) at reflux of acetonitrile. A conversion of 98.6 % is achieved in only 120 min of reaction.Centro de Investigación y Desarrollo en Ciencias AplicadasPlanta Piloto Multipropósito - Laboratorio de Servicios a la Industria y al Sistema Científico2013-10-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf172-180http://sedici.unlp.edu.ar/handle/10915/138848enginfo:eu-repo/semantics/altIdentifier/issn/1011-372xinfo:eu-repo/semantics/altIdentifier/issn/1572-879xinfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10562-013-1111-6info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-11-05T13:11:10Zoai:sedici.unlp.edu.ar:10915/138848Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-11-05 13:11:11.193SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
title Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
spellingShingle Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
Sánchez, Laura Mabel
Química
Ciencias Exactas
Heteropolyacid
Oxidation
1,4-dihydropyridine
Hydrogen peroxide
title_short Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
title_full Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
title_fullStr Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
title_full_unstemmed Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
title_sort Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
dc.creator.none.fl_str_mv Sánchez, Laura Mabel
Sathicq, Ángel Gabriel
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
Romanelli, Gustavo Pablo
author Sánchez, Laura Mabel
author_facet Sánchez, Laura Mabel
Sathicq, Ángel Gabriel
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
Romanelli, Gustavo Pablo
author_role author
author2 Sathicq, Ángel Gabriel
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
Romanelli, Gustavo Pablo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Química
Ciencias Exactas
Heteropolyacid
Oxidation
1,4-dihydropyridine
Hydrogen peroxide
topic Química
Ciencias Exactas
Heteropolyacid
Oxidation
1,4-dihydropyridine
Hydrogen peroxide
dc.description.none.fl_txt_mv H7P2W17VO62.25H2O Wells-Dawson heteropolyacid was prepared, characterized and evaluated as catalyst in a 1,4-dihydropyridine oxidation reaction. The optimal conditions are the following: 1 mmol% of HWDV, a molar ratio 1,4-DHP:H2O2 (1:10) at reflux of acetonitrile. A conversion of 98.6 % is achieved in only 120 min of reaction.
Centro de Investigación y Desarrollo en Ciencias Aplicadas
Planta Piloto Multipropósito - Laboratorio de Servicios a la Industria y al Sistema Científico
description H7P2W17VO62.25H2O Wells-Dawson heteropolyacid was prepared, characterized and evaluated as catalyst in a 1,4-dihydropyridine oxidation reaction. The optimal conditions are the following: 1 mmol% of HWDV, a molar ratio 1,4-DHP:H2O2 (1:10) at reflux of acetonitrile. A conversion of 98.6 % is achieved in only 120 min of reaction.
publishDate 2013
dc.date.none.fl_str_mv 2013-10-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/138848
url http://sedici.unlp.edu.ar/handle/10915/138848
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1011-372x
info:eu-repo/semantics/altIdentifier/issn/1572-879x
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10562-013-1111-6
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
172-180
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.084122

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