Formation of a reversible cell in the electrolysis of molten silver nitrate
- Autores
- Triaca, Walter Enrique; Arvia, Alejandro Jorge
- Año de publicación
- 1964
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In the electrolysis of pure molten silver nitrate with a silver cathode and a platinum anode at temperatures from 220 to 380°C a reversible cell is formed. When the system is electrolysed for a short time at a steady current density and then the current is interrupted, it tends to reach after a few seconds a reversible emf which is independent of the current density employed in the previous electrolysis. This emf is constant provided that the composition of the system is not altered. short-circuiting the cell repeatedly always leads to the same emf. The emf is related to the residual electrochemical cell formed during the electrolysis. The cell can be represented by the following scheme: Ag/AgNO3(l)/NO2,NO,O2/Pt. The reversible reactions involved in the cell are Ag + NO2 + 12O2 ⇌ AgNO3 and NO + 12O2 ⇌ NO2. The theoretical decomposition voltage of silver nitrate is coincident with the ones found experimentally, taking account of the actual concentrations of species involved in the reactions.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas - Materia
-
Ciencias Exactas
Química
Reversible cell
Molten silver nitrate
Electrolysis - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/121082
Ver los metadatos del registro completo
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Formation of a reversible cell in the electrolysis of molten silver nitrateTriaca, Walter EnriqueArvia, Alejandro JorgeCiencias ExactasQuímicaReversible cellMolten silver nitrateElectrolysisIn the electrolysis of pure molten silver nitrate with a silver cathode and a platinum anode at temperatures from 220 to 380°C a reversible cell is formed. When the system is electrolysed for a short time at a steady current density and then the current is interrupted, it tends to reach after a few seconds a reversible emf which is independent of the current density employed in the previous electrolysis. This emf is constant provided that the composition of the system is not altered. short-circuiting the cell repeatedly always leads to the same emf. The emf is related to the residual electrochemical cell formed during the electrolysis. The cell can be represented by the following scheme: Ag/AgNO<sub>3</sub>(l)/NO<sub>2</sub>,NO,O<sub>2</sub>/Pt. The reversible reactions involved in the cell are Ag + NO<sub>2</sub> + 12O<sub>2</sub> ⇌ AgNO<sub>3</sub> and NO + 12O<sub>2</sub> ⇌ NO<sub>2</sub>. The theoretical decomposition voltage of silver nitrate is coincident with the ones found experimentally, taking account of the actual concentrations of species involved in the reactions.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1964info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf919-924http://sedici.unlp.edu.ar/handle/10915/121082enginfo:eu-repo/semantics/altIdentifier/issn/0013-4686info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(64)85042-8info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-03T11:00:48Zoai:sedici.unlp.edu.ar:10915/121082Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-03 11:00:48.43SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Formation of a reversible cell in the electrolysis of molten silver nitrate |
| title |
Formation of a reversible cell in the electrolysis of molten silver nitrate |
| spellingShingle |
Formation of a reversible cell in the electrolysis of molten silver nitrate Triaca, Walter Enrique Ciencias Exactas Química Reversible cell Molten silver nitrate Electrolysis |
| title_short |
Formation of a reversible cell in the electrolysis of molten silver nitrate |
| title_full |
Formation of a reversible cell in the electrolysis of molten silver nitrate |
| title_fullStr |
Formation of a reversible cell in the electrolysis of molten silver nitrate |
| title_full_unstemmed |
Formation of a reversible cell in the electrolysis of molten silver nitrate |
| title_sort |
Formation of a reversible cell in the electrolysis of molten silver nitrate |
| dc.creator.none.fl_str_mv |
Triaca, Walter Enrique Arvia, Alejandro Jorge |
| author |
Triaca, Walter Enrique |
| author_facet |
Triaca, Walter Enrique Arvia, Alejandro Jorge |
| author_role |
author |
| author2 |
Arvia, Alejandro Jorge |
| author2_role |
author |
| dc.subject.none.fl_str_mv |
Ciencias Exactas Química Reversible cell Molten silver nitrate Electrolysis |
| topic |
Ciencias Exactas Química Reversible cell Molten silver nitrate Electrolysis |
| dc.description.none.fl_txt_mv |
In the electrolysis of pure molten silver nitrate with a silver cathode and a platinum anode at temperatures from 220 to 380°C a reversible cell is formed. When the system is electrolysed for a short time at a steady current density and then the current is interrupted, it tends to reach after a few seconds a reversible emf which is independent of the current density employed in the previous electrolysis. This emf is constant provided that the composition of the system is not altered. short-circuiting the cell repeatedly always leads to the same emf. The emf is related to the residual electrochemical cell formed during the electrolysis. The cell can be represented by the following scheme: Ag/AgNO<sub>3</sub>(l)/NO<sub>2</sub>,NO,O<sub>2</sub>/Pt. The reversible reactions involved in the cell are Ag + NO<sub>2</sub> + 12O<sub>2</sub> ⇌ AgNO<sub>3</sub> and NO + 12O<sub>2</sub> ⇌ NO<sub>2</sub>. The theoretical decomposition voltage of silver nitrate is coincident with the ones found experimentally, taking account of the actual concentrations of species involved in the reactions. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
| description |
In the electrolysis of pure molten silver nitrate with a silver cathode and a platinum anode at temperatures from 220 to 380°C a reversible cell is formed. When the system is electrolysed for a short time at a steady current density and then the current is interrupted, it tends to reach after a few seconds a reversible emf which is independent of the current density employed in the previous electrolysis. This emf is constant provided that the composition of the system is not altered. short-circuiting the cell repeatedly always leads to the same emf. The emf is related to the residual electrochemical cell formed during the electrolysis. The cell can be represented by the following scheme: Ag/AgNO<sub>3</sub>(l)/NO<sub>2</sub>,NO,O<sub>2</sub>/Pt. The reversible reactions involved in the cell are Ag + NO<sub>2</sub> + 12O<sub>2</sub> ⇌ AgNO<sub>3</sub> and NO + 12O<sub>2</sub> ⇌ NO<sub>2</sub>. The theoretical decomposition voltage of silver nitrate is coincident with the ones found experimentally, taking account of the actual concentrations of species involved in the reactions. |
| publishDate |
1964 |
| dc.date.none.fl_str_mv |
1964 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://sedici.unlp.edu.ar/handle/10915/121082 |
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http://sedici.unlp.edu.ar/handle/10915/121082 |
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eng |
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eng |
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info:eu-repo/semantics/altIdentifier/issn/0013-4686 info:eu-repo/semantics/altIdentifier/doi/10.1016/0013-4686(64)85042-8 |
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info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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openAccess |
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http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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application/pdf 919-924 |
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