Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer

Autores
Lezna, Reynaldo Oscar; Romagnoli, Roberto; De Tacconi, Norma R.; Rajeshwar, Krishnan
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The cobalt hexacyanoferrate system, MhCokA[FeB(CN)6]l , (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex sim X-ray photoelectron spectroscopy.
Fil: Lezna, Reynaldo Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Romagnoli, Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: De Tacconi, Norma R.. University of Texas; Estados Unidos
Fil: Rajeshwar, Krishnan. University of Texas; Estados Unidos
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/152053
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transferLezna, Reynaldo OscarRomagnoli, RobertoDe Tacconi, Norma R.Rajeshwar, Krishnanhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The cobalt hexacyanoferrate system, MhCokA[FeB(CN)6]l , (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex sim X-ray photoelectron spectroscopy.Fil: Lezna, Reynaldo Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Romagnoli, Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: De Tacconi, Norma R.. University of Texas; Estados UnidosFil: Rajeshwar, Krishnan. University of Texas; Estados UnidosAmerican Chemical Society2002-03-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/mswordapplication/pdfhttp://hdl.handle.net/11336/152053Lezna, Reynaldo Oscar; Romagnoli, Roberto; De Tacconi, Norma R.; Rajeshwar, Krishnan; Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer; American Chemical Society; Journal of Physical Chemistry B; 106; 14; 12-3-2002; 3612-36211089-5647CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jp013991rinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T10:00:22Zoai:ri.conicet.gov.ar:11336/152053instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 10:00:22.445CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer
title Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer
spellingShingle Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer
Lezna, Reynaldo Oscar
title_short Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer
title_full Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer
title_fullStr Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer
title_full_unstemmed Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer
title_sort Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer
dc.creator.none.fl_str_mv Lezna, Reynaldo Oscar
Romagnoli, Roberto
De Tacconi, Norma R.
Rajeshwar, Krishnan
author Lezna, Reynaldo Oscar
author_facet Lezna, Reynaldo Oscar
Romagnoli, Roberto
De Tacconi, Norma R.
Rajeshwar, Krishnan
author_role author
author2 Romagnoli, Roberto
De Tacconi, Norma R.
Rajeshwar, Krishnan
author2_role author
author
author
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The cobalt hexacyanoferrate system, MhCokA[FeB(CN)6]l , (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex sim X-ray photoelectron spectroscopy.
Fil: Lezna, Reynaldo Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Romagnoli, Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: De Tacconi, Norma R.. University of Texas; Estados Unidos
Fil: Rajeshwar, Krishnan. University of Texas; Estados Unidos
description The cobalt hexacyanoferrate system, MhCokA[FeB(CN)6]l , (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex sim X-ray photoelectron spectroscopy.
publishDate 2002
dc.date.none.fl_str_mv 2002-03-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/152053
Lezna, Reynaldo Oscar; Romagnoli, Roberto; De Tacconi, Norma R.; Rajeshwar, Krishnan; Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer; American Chemical Society; Journal of Physical Chemistry B; 106; 14; 12-3-2002; 3612-3621
1089-5647
CONICET Digital
CONICET
url http://hdl.handle.net/11336/152053
identifier_str_mv Lezna, Reynaldo Oscar; Romagnoli, Roberto; De Tacconi, Norma R.; Rajeshwar, Krishnan; Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer; American Chemical Society; Journal of Physical Chemistry B; 106; 14; 12-3-2002; 3612-3621
1089-5647
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/jp013991r
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/msword
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.976206

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