Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer
- Autores
- Lezna, Reynaldo Oscar; Romagnoli, Roberto; De Tacconi, Norma R.; Rajeshwar, Krishnan
- Año de publicación
- 2002
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The cobalt hexacyanoferrate system, MhCokA[FeB(CN)6]l , (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex sim X-ray photoelectron spectroscopy.
Fil: Lezna, Reynaldo Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Romagnoli, Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: De Tacconi, Norma R.. University of Texas; Estados Unidos
Fil: Rajeshwar, Krishnan. University of Texas; Estados Unidos - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/152053
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Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transferLezna, Reynaldo OscarRomagnoli, RobertoDe Tacconi, Norma R.Rajeshwar, Krishnanhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The cobalt hexacyanoferrate system, MhCokA[FeB(CN)6]l , (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex sim X-ray photoelectron spectroscopy.Fil: Lezna, Reynaldo Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Romagnoli, Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: De Tacconi, Norma R.. University of Texas; Estados UnidosFil: Rajeshwar, Krishnan. University of Texas; Estados UnidosAmerican Chemical Society2002-03-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/mswordapplication/pdfhttp://hdl.handle.net/11336/152053Lezna, Reynaldo Oscar; Romagnoli, Roberto; De Tacconi, Norma R.; Rajeshwar, Krishnan; Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer; American Chemical Society; Journal of Physical Chemistry B; 106; 14; 12-3-2002; 3612-36211089-5647CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jp013991rinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:46:50Zoai:ri.conicet.gov.ar:11336/152053instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:46:50.318CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer |
title |
Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer |
spellingShingle |
Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer Lezna, Reynaldo Oscar |
title_short |
Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer |
title_full |
Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer |
title_fullStr |
Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer |
title_full_unstemmed |
Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer |
title_sort |
Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer |
dc.creator.none.fl_str_mv |
Lezna, Reynaldo Oscar Romagnoli, Roberto De Tacconi, Norma R. Rajeshwar, Krishnan |
author |
Lezna, Reynaldo Oscar |
author_facet |
Lezna, Reynaldo Oscar Romagnoli, Roberto De Tacconi, Norma R. Rajeshwar, Krishnan |
author_role |
author |
author2 |
Romagnoli, Roberto De Tacconi, Norma R. Rajeshwar, Krishnan |
author2_role |
author author author |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The cobalt hexacyanoferrate system, MhCokA[FeB(CN)6]l , (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex sim X-ray photoelectron spectroscopy. Fil: Lezna, Reynaldo Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: Romagnoli, Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: De Tacconi, Norma R.. University of Texas; Estados Unidos Fil: Rajeshwar, Krishnan. University of Texas; Estados Unidos |
description |
The cobalt hexacyanoferrate system, MhCokA[FeB(CN)6]l , (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex sim X-ray photoelectron spectroscopy. |
publishDate |
2002 |
dc.date.none.fl_str_mv |
2002-03-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/152053 Lezna, Reynaldo Oscar; Romagnoli, Roberto; De Tacconi, Norma R.; Rajeshwar, Krishnan; Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer; American Chemical Society; Journal of Physical Chemistry B; 106; 14; 12-3-2002; 3612-3621 1089-5647 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/152053 |
identifier_str_mv |
Lezna, Reynaldo Oscar; Romagnoli, Roberto; De Tacconi, Norma R.; Rajeshwar, Krishnan; Cobalt hexacyanoferrate: Compound stoichiometry, infrared spectroelectrochemistry, and photoinduced electron transfer; American Chemical Society; Journal of Physical Chemistry B; 106; 14; 12-3-2002; 3612-3621 1089-5647 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/jp013991r |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/msword application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614510639316992 |
score |
13.070432 |